浸移磷 | 13265-60-6

• 分子结构分类: 有机化合物 - 有机酸及其衍生物 - 有机二硫代磷酸及其衍生物
• 中文名称: 浸移磷
• 中文别名: S-2-乙酰胺基乙基O，O-二甲基二硫代磷酸酯
• 英文名称: S-(2-acetylaminoethyl) dimethyl phosphorodithioate
• 英文别名: O,O-dimethyl-S-2-(acetylamino)-ethyl dithiophosphate；S-(2-acetamidoethyl)-O,O-dimethyldithiophosphate；O,O-Dimethyl-S-(2-acetamidoethyl)-phosphordithioat；Amiphos；N-(2-dimethoxyphosphinothioylsulfanylethyl)acetamide
• CAS: 13265-60-6
• 化学式: C₆H₁₄NO₃PS₂
• 分子量: 243.288
• InChiKey: BETVNUCOOCCCIO-UHFFFAOYSA-N

物化性质

• 密度：
  1.265±0.06 g/cm3(Predicted)

计算性质

• 辛醇/水分配系数(LogP)：
  1
• 重原子数：
  13
• 可旋转键数：
  6
• 环数：
  0.0
• sp3杂化的碳原子比例：
  0.83
• 拓扑面积：
  105
• 氢给体数：
  1
• 氢受体数：
  5

安全信息

• 海关编码：
  2931900090

制备方法与用途

类别：农药

• 毒性分级：高毒
• 急性毒性：口服-大鼠 LD₅₀：220毫克/公斤；口服-小鼠 LD₅₀：146毫克/公斤
• 可燃性危险特性：燃烧时产生有毒氮氧化物、磷氧化物和硫氧化物气体
• 储运特性：库房需通风低温干燥，并与食品原料分开储存运输
• 灭火剂：干粉、泡沫、砂土
• 职业标准：STEL 0.5 毫克/立方米

反应信息

• 作为反应物：
  描述：

  浸移磷 在 乙硫醇钠 作用下， 以 四氢呋喃 、 乙醇 为溶剂， 反应 0.75h， 生成 S-(2-acetylaminoethyl) S-methyl methyl phosphorodithiolate
  参考文献：
  名称：

  Miyamoto, Toru; Yamamoto, Izuru, Agricultural and Biological Chemistry, 1981, vol. 45, # 9, p. 1991 - 1998

  摘要：

  DOI：

文献信息

• Process for preparing peroxides
  申请人：E. I. du Pont de Nemours and Company

  公开号：US05831131A1

  公开（公告）日：1998-11-03

  A process for the faster manufacturing of hydrocarbon, fluorocarbon and chlorocarbon acyl peroxides is disclosed wherein a hydroxide, a peroxide and an acyl halide are reacted under continuous vigorous agitation conditions so as to bring the reaction to substantial completion is less than one minute.

  公开了一种更快速制造碳氢化合物、氟碳化合物和氯碳化合物酰基过氧化物的方法，其中在连续剧烈搅拌条件下反应氢氧化物、过氧化物和酰卤化物，以使反应在不到一分钟内基本完成。
• NON-TIN-BASED, LOW TOXICITY ANTI-FOULING AGENTS
  申请人：BATTELLE MEMORIAL INSTITUTE

  公开号：EP0449975B1

  公开（公告）日：1997-04-23
• HERPES VIRUS-BASED COMPOSITIONS AND METHODS OF USE IN THE PRENATAL AND PERINATAL PERIODS
  申请人：THE UNIVERSITY OF ROCHESTER

  公开号：EP1903873A2

  公开（公告）日：2008-04-02
• Methods to accelerate the isolation of novel cell strains from pluripotent stem cells and cells obtained thereby
  申请人：West D. Michael

  公开号：US20080070303A1

  公开（公告）日：2008-03-20

  This invention generally relates to methods to differentiate pluripotent stem cells, such as embryonic stem, embryonic germ, or embryo-derived cells, to obtain subpopulations of cells from heterogeneous mixtures of cells wherein the subpopulation of cells possess reduced differentiation potential compared to the original pluripotent stem cells and where the subpopulation is capable of being propagated.
• Herpes Virus-Based Compositions and Methods of Use in the Prenatal and Perinatal Periods
  申请人：Federoff Howard J.

  公开号：US20080226601A1

  公开（公告）日：2008-09-18

  Disclosed are compositions and methods for reducing the severity of a birth defect in a mammal by exposing the mammal (e.g., in utero) to a herpes virus amplicon particle comprising a cis element-flanked transgene and a sequence encoding a transposase. Upon expression, the transposase inserts the transgene into the genome of a cell (e.g., a neuron) within the mammal and the transgene expresses a polypeptide or RNA that compensates for a protein or gene defect that is causally associated with the birth defect.