2,3c-diphenyl-acrylic acid amide | 1129304-56-8

• 分子结构分类: 有机化合物 - 苯丙烷和聚酮 - 二苯乙烯类
• 英文名称: 2,3c-diphenyl-acrylic acid amide
• 英文别名: 2,3c-Diphenyl-acrylsaeure-amid；diphenylacrylamide；cis-alpha-Phenylcinnamamide；(Z)-2,3-diphenylprop-2-enamide
• CAS: 1129304-56-8
• 化学式: C₁₅H₁₃NO
• 分子量: 223.274
• InChiKey: VTOAFAPBGXLGME-KAMYIIQDSA-N

物化性质

• 熔点：
  167-168 °C
• 沸点：
  427.1±45.0 °C(Predicted)
• 密度：
  1.155±0.06 g/cm3(Temp: 20 °C; Press: 760 Torr)(Predicted)

计算性质

• 辛醇/水分配系数(LogP)：
  2.9
• 重原子数：
  17
• 可旋转键数：
  3
• 环数：
  2.0
• sp3杂化的碳原子比例：
  0.0
• 拓扑面积：
  43.1
• 氢给体数：
  1
• 氢受体数：
  1

反应信息

• 作为产物：
  描述：

  (R)-4-(叔-丁氧基羰基)吗啉-2-羧酸 在 乙醚 、 五氯化磷 作用下， 生成 2,3c-diphenyl-acrylic acid amide
  参考文献：
  名称：

  Stoermer; Voht, Justus Liebigs Annalen der Chemie, 1915, vol. 409, p. 42

  摘要：

  DOI：

文献信息

• [EN] NOVEL DITHIOKETAL<br/>[FR] NOUVEAU DITHIOCETAL
  申请人：BIOCON LTD

  公开号：WO2004103957A1

  公开（公告）日：2004-12-02

  A novel compound of formula (I) and a process for the preparation of compounds of formula (I): by reacting a compound of formula (II): Formula (III): with a compound of formula (III) where R1 and R2 are any suitable alkyl group, preferably C2H5 or R1 and R2 can join together to form any cyclic structure, preferably -CH2-Ch2-CH2-.

  公式（I）的新化合物和公式（I）化合物的制备方法：通过将公式（II）的化合物与公式（III）的化合物反应，其中R1和R2是任何适当的烷基，优选C2H5或R1和R2可以结合形成任何环状结构，优选-CH2-Ch2- -。
• Use of adhesive quaternary ammonium polymer compositions in bonding flexible covering to rigid substrate, and laminated articles produced therewith
  申请人：ROHM AND HAAS COMPANY

  公开号：EP0072684A1

  公开（公告）日：1983-02-23

  An adhesive composition comprising either (i) a latex polymer having a Tg from -10°C to 25°C or (ii) a mixture of soft latex polymer and hard latex polymer, each polymer being either (1) a copolymer of quaternary monomer prepared by reacting an epihalohydrin of the formula XCH2-CHCH2O with a salt of an amine of the formula RN(R')CH3, or (2) A reaction product of a copolymer of such an amine salt and such an epihalohydrin; wherein R is an ethylenically unsaturated organic group, R' is a linear (C, to C4)-alkyl group, optionally hydroxy-substituted, X is chlorine, bromine or iodine. The compositions are useful in bonding a flexible covering layer, such as fabric covered polyurethane foam, to a rigid substrate such as glass fibre mat to produce laminates including automotive headliners and acoustic panels.

  一种粘合剂组合物，包括(i)Tg 为 -10°C 至 25°C 的乳胶聚合物或(ii)软质乳胶聚合物和硬质乳胶聚合物的混合物，每种聚合物都是 (1) 由式 XCH2-CHCH2O 的表卤代烃与式 RN(R')CH3 的胺盐反应制备的季单体共聚物，或 (2) 此类胺盐与此类表卤代烃的共聚物的反应产物； 其中 R 是乙烯基不饱和有机基团、 R' 是线性（C，至 C4）烷基，可选择羟基取代、 X 是氯、溴或碘。 这些组合物适用于将织物包覆聚氨酯泡沫等柔性覆盖层粘合到玻璃纤维毡等刚性基材上，以生产包括汽车顶篷和隔音板在内的层压板。
• One-package aqueous latices containing alkaline-curable crosslinking polymers
  申请人：National Starch and Chemical Corporation

  公开号：EP0170095A2

  公开（公告）日：1986-02-05

  Shelf-stable, one-package aqueous latices, which are curable with or without the application of heat, consist essentially of an alkalinecurable, self-crosslinking emulsion polymer, selected organic metal salts, and water. The alkali, alkaline earth, or heavy metal salts of C1-C6 organic acids (e.g., sodium acetate) are post-added to the polymer emulsion or present during the polymerization. The polymer typically comprises about 90-99.9% by weight of one or more vinyl polymerizable monomers (e.g., acrylates, vinyl esters, and ethylene) and 0.1-10% by weight of a polymerizable non-ionic or cationic self-crosslinking monomer containing halohydrin groups (e.g., 3-chloro-2-hydroxypropyl (meth) acrylate or the reaction product of epichlorohydrin and N,N-dimethylaminopropyl methacrylamide or methacrylate).

  货架稳定的单组分水性乳胶漆可加热或不加热固化，主要由可碱化的自交联乳液聚合 物、选定的有机金属盐和水组成。C1-C6 有机酸的碱、碱土或重金属盐（如醋酸钠）可在聚合物乳液中添加或在聚合过程中存在。聚合物通常包括约 90-99.9% （按重量计）的一种或多种乙烯基可聚合单体（如丙烯酸酯、乙烯酯和乙烯）和 0.1-10% （按重量计）的含有卤代水杨酸基团的可聚合非离子或阳离子自交联单体（如 3-氯-2-羟丙基（甲基）丙烯酸酯或环氧氯丙烷与 N,N-二甲基氨基丙基甲基丙烯酰胺或甲基丙烯酸酯的反应产物）。
• Colloid stabilized latex adhesives
  申请人：National Starch and Chemical Investment Holding Corporation

  公开号：EP0212358A2

  公开（公告）日：1987-03-04

  Latex adhesives having a Tg of -60 to 0°C characterized by superior rheological properties, are prepared without the use of additional thickeners from a colloid stabilized latex comprising: 65-90% by weight of the latex polymer solids of an acrylate or methacrylate ester monomer polymerized in 10-35% by weight of the latex solids of a polymeric colloid, the polymeric colloid having a Tg of -40 to 0°C, a number average molecular weight of 2,000 to 10,000 and comprising a) 50 to 85% by weight of a monomer of the formula: where R' is hydrogen or methyl and R" is a C1-C12 straight or branched chain alkyl group; b) 10 to 50% by weight of an ethylenically unsaturated mono-or dicarboxylic acid; c) 5 to 30% by weight of an acrylic or methacrylic ester of a polyalkylene oxide, and d) 0 to 30% by weight of another ethylenically unsaturated copolymerizable monomer.

  胶乳粘合剂的 Tg 值为 -60 至 0°C，具有优异的流变性能，无需使用额外的增稠剂，由胶体稳定胶乳制备而成：按重量计，65-90%的胶乳聚合物固体是丙烯酸酯或甲基丙烯酸酯单体与按重量计，10-35%的胶乳固体是聚合物胶体聚合而成，聚合物胶体的 Tg 为 -40 至 0°C，平均分子量为 2,000 至 10,000，并包括 a) 50-85%（重量）的式中单体： 其中 R' 为氢或甲基，R" 为 C1-C12 直链或支链烷基； b) 10-50%（重量百分比）乙烯基不饱和单羧酸或二羧酸； c) 5%至 30%（按重量计）的聚环氧烷的丙烯酸酯或甲基丙烯酸酯，以及 d) 0-30% （重量百分比）的另一种乙烯基不饱和可共聚单体。
• water-resistant alkaline adhesive composition
  申请人：National Starch and Chemical Investment Holding Corporation

  公开号：EP0247579A2

  公开（公告）日：1987-12-02

  A starch-based alkaline curing adhesive is disclosed. The adhesive, when employed in the preparation of corrugated paperboard provides the paperboard with superior water resistant bonds. The adhesive contains from about 6 to 35%, based on total weight of the adhesive, solids basis, of a latex polymer of a halohydrin quaternary ammonium monomer.

  本发明公开了一种淀粉基碱性固化粘合剂。这种粘合剂用于制备瓦楞纸板时，可为纸板提供优异的防水粘合性能。该粘合剂含有约 6% 至 35% 的卤代水合季铵盐单体胶乳聚合物（以粘合剂总重量和固含量为基准）。

表征谱图