Ethynyl(methyl)phosphane | 154416-08-7

• 分子结构分类: 有机化合物 - 碳化物
• 英文名称: Ethynyl(methyl)phosphane
• CAS: 154416-08-7
• 化学式: C₃H₅P
• 分子量: 72.0465
• InChiKey: XRAXLJJAJSVXBT-UHFFFAOYSA-N

计算性质

• 辛醇/水分配系数(LogP)：
  0.3
• 重原子数：
  4
• 可旋转键数：
  0
• 环数：
  0.0
• sp3杂化的碳原子比例：
  0.33
• 拓扑面积：
  0
• 氢给体数：
  0
• 氢受体数：
  0

反应信息

• 作为反应物：
  描述：

  Ethynyl(methyl)phosphane 在 1,8-二氮杂双环[5.4.0]十一碳-7-烯 作用下， 以 四氢呋喃 为溶剂， 以26%的产率得到ethenylidene-methylphosphine
  参考文献：
  名称：

  Unstabilized 1-phosphaallenes : synthesis and characterization

  摘要：

  Unstabilized P-methyl-1-phosphaallenes 1 are prepared by a base-induced dehydrohalogenation of 1-chlorovinyl-methylphosphines or rearrangement of 1-alkynyl-methylphosphines.

  DOI：

  10.1016/s0040-4039(00)76522-1
• 作为产物：
  描述：

  methyl ethynylmethylphosphinate 在 dichloroalane 作用下， 以31%的产率得到Ethynyl(methyl)phosphane
  参考文献：
  名称：

  Unstabilized 1-phosphaallenes : synthesis and characterization

  摘要：

  Unstabilized P-methyl-1-phosphaallenes 1 are prepared by a base-induced dehydrohalogenation of 1-chlorovinyl-methylphosphines or rearrangement of 1-alkynyl-methylphosphines.

  DOI：

  10.1016/s0040-4039(00)76522-1

文献信息

• First synthesis of secondary P-alkenyl and P-alkynyl phosphine oxides
  作者：Gnon Baba、Jean-François Pilard、Khalid Tantaoui、Annie-Claude Gaumont、Jean-Marc Denis

  DOI：10.1016/0040-4039(95)00761-z

  日期：1995.6

  A general method for preparing secondary P-alkenyl and P-alkynyl phosphine oxides, compounds unknown so far, involves the condensation of the vinyl Grignard reagent or lithium acetylide on P-chloroaminophosphines followed by acidic hydrolysis of the corresponding vinyl- or ethynylaminophosphines on a solid acid (Amberlyst 15). The few reported chemical properties are mainly related to the strong PH bond activation. Of special interest is the addition of a secondary vinylphosphine oxyde derivative on methyl acrylate which occurs at room temperature without any catalyst.