Tert-butyl(diethoxyphosphoryl)phosphane;carbon monoxide;molybdenum | 124992-16-1

• 分子结构分类: 有机化合物 - 有机盐 - 有机金属盐
• 英文名称: Tert-butyl(diethoxyphosphoryl)phosphane;carbon monoxide;molybdenum
• CAS: 124992-16-1
• 化学式: C₁₃H₂₀MoO₈P₂
• 分子量: 462.185
• InChiKey: ROHIRLJAXWKRHP-UHFFFAOYSA-N

计算性质

• 辛醇/水分配系数(LogP)：
  3.45
• 重原子数：
  24
• 可旋转键数：
  6
• 环数：
  0.0
• sp3杂化的碳原子比例：
  0.62
• 拓扑面积：
  40.5
• 氢给体数：
  0
• 氢受体数：
  8

反应信息

• 作为反应物：
  描述：

  Tert-butyl(diethoxyphosphoryl)phosphane;carbon monoxide;molybdenum 、 丁酮 在 n-BuLi 、 MeOH 、 H₂O 作用下， 以 四氢呋喃 、 正己烷 为溶剂， 以83%的产率得到{methyl isobutyl-t-butylphosphinite}pentacarbonylmolybdenum
  参考文献：
  名称：

  Marinetti, Angela; Bauer, Siegfried; Ricard, Louis, Organometallics, 1990, vol. 9, # 3, p. 793 - 798

  摘要：

  DOI：
• 作为产物：
  描述：

  molybdenum hexacarbonyl 在 C₂H₅ONa 、 C₂H₅OH 作用下， 以 四氢呋喃 、 乙醇 、 甲苯 为溶剂， 生成 Tert-butyl(diethoxyphosphoryl)phosphane;carbon monoxide;molybdenum
  参考文献：
  名称：

  Synthesis of optically active phosphiranes and their use as ligands in rhodium(I) complexes

  摘要：

  Optically active (phosphirane)Mo(CO)5 complexes have been obtained by starting from chiral styrene oxide. The corresponding tervalent phosphiranes are easily recovered through a stereoselective decomplexation reaction and used as ligands for cationic rhodium complexes. Some preliminary results on the catalytic hydrogenation of olefins show that different diastereoisomers of a phosphirane give a completely different catalytic behavior to their rhodium complexes. Unusually for a monodentate phosphine, significant optical yields are obtained with one of the four diastereoisomers of the P-menthylphosphirane. The actual involvement of phosphirane itself in the catalytic cycle is not fully established.

  DOI：

  10.1021/om00028a040

文献信息

• Marinetti, Angela; Bauer, Siegfried; Ricard, Louis, Organometallics, 1990, vol. 9, # 3, p. 793 - 798
  作者：Marinetti, Angela、Bauer, Siegfried、Ricard, Louis、Mathey, François

  DOI：——

  日期：——
• Synthesis of optically active phosphiranes and their use as ligands in rhodium(I) complexes
  作者：Angela Marinetti、Francois Mathey、Louis Ricard

  DOI：10.1021/om00028a040

  日期：1993.4

  Optically active (phosphirane)Mo(CO)5 complexes have been obtained by starting from chiral styrene oxide. The corresponding tervalent phosphiranes are easily recovered through a stereoselective decomplexation reaction and used as ligands for cationic rhodium complexes. Some preliminary results on the catalytic hydrogenation of olefins show that different diastereoisomers of a phosphirane give a completely different catalytic behavior to their rhodium complexes. Unusually for a monodentate phosphine, significant optical yields are obtained with one of the four diastereoisomers of the P-menthylphosphirane. The actual involvement of phosphirane itself in the catalytic cycle is not fully established.