1,10-phenanthroline-2,9-dicarbonyl-p-nitrophenylhydrazine | 1312792-29-2

• 分子结构分类: 有机化合物 - 有机杂环化合物 - 菲咯啉
• 英文名称: 1,10-phenanthroline-2,9-dicarbonyl-p-nitrophenylhydrazine
• 英文别名: 2-N',9-N'-bis(4-nitrophenyl)-1,10-phenanthroline-2,9-dicarbohydrazide
• CAS: 1312792-29-2
• 化学式: C₂₆H₁₈N₈O₆
• 分子量: 538.479
• InChiKey: DJWLNYTVTUIZHO-UHFFFAOYSA-N

计算性质

• 辛醇/水分配系数(LogP)：
  5.1
• 重原子数：
  40
• 可旋转键数：
  6
• 环数：
  5.0
• sp3杂化的碳原子比例：
  0.0
• 拓扑面积：
  200
• 氢给体数：
  4
• 氢受体数：
  10

反应信息

• 作为产物：
  描述：

  2,9-二甲酰氯-1,10-菲咯啉 、 4-硝基苯肼 在 三乙胺 作用下， 以 二氯甲烷 为溶剂， 反应 72.0h， 以0.33 g的产率得到1,10-phenanthroline-2,9-dicarbonyl-p-nitrophenylhydrazine
  参考文献：
  名称：

  A novel acetate selective chromogenic chemosensor based on phenanthroline

  摘要：

  A novel colorimetric anion-chemosensor based on 1,10-phenanthroline-2,9-dicarbonyl-p-nitrophenylhydrazine has been synthesized. Among the different anions tested, it shows the best selectivity towards AcO-. The addition of acetate causes the color to change from yellow to red, which could be detected with naked eyes. The binding ability of chemosensor 1 with anions has been investigated through UV-vis spectral titrations. In addition, H-1 NMR experiment was carried out to explore the nature of interaction between chemosensor 1 and acetate. (C) 2011 Elsevier B.V. All rights reserved.

  DOI：

  10.1016/j.saa.2011.03.013

文献信息

• A novel acetate selective chromogenic chemosensor based on phenanthroline
  作者：Weiwei Huang、Yaping Li、Zhongyue Yang、Hai Lin、Huakuan Lin

  DOI：10.1016/j.saa.2011.03.013

  日期：2011.8

  A novel colorimetric anion-chemosensor based on 1,10-phenanthroline-2,9-dicarbonyl-p-nitrophenylhydrazine has been synthesized. Among the different anions tested, it shows the best selectivity towards AcO-. The addition of acetate causes the color to change from yellow to red, which could be detected with naked eyes. The binding ability of chemosensor 1 with anions has been investigated through UV-vis spectral titrations. In addition, H-1 NMR experiment was carried out to explore the nature of interaction between chemosensor 1 and acetate. (C) 2011 Elsevier B.V. All rights reserved.