(o-phenanthroline)bis(2,2,6,6-tetramethylheptan-3,5-dionato)copper(II) | 188638-92-8

• 分子结构分类: 有机化合物 - 有机杂环化合物 - 菲咯啉
• 英文名称: (o-phenanthroline)bis(2,2,6,6-tetramethylheptan-3,5-dionato)copper(II)
• CAS: 188638-92-8
• 化学式: C₃₄H₄₆CuN₂O₄
• 分子量: 610.296
• InChiKey: OWCSVVAANFPKOL-UHFFFAOYSA-N

计算性质

• 辛醇/水分配系数(LogP)：
  None
• 重原子数：
  None
• 可旋转键数：
  None
• 环数：
  None
• sp3杂化的碳原子比例：
  None
• 拓扑面积：
  None
• 氢给体数：
  None
• 氢受体数：
  None

反应信息

• 作为产物：
  描述：

  2,2,6,6-四甲基-3,5-庚二酮 以 水 、 苯 为溶剂， 生成 (o-phenanthroline)bis(2,2,6,6-tetramethylheptan-3,5-dionato)copper(II)
  参考文献：
  名称：

  Crystal structure of copper(II) pivaloyltrifluoracetonate adducts with o-phenanthroline and 2,2′-dipyridyl

  摘要：

  The crystal structure of Cu(pta)(2) . Phen has been determined. The phenanthroline ligand occupies a position in the equatorial plane of the tetragonally distorted octahedron with equal Cu-N distances and equivalent beta-diketonate-anions. Cu(pta)(2) . 2,2'-Dipy is isostructural to Cu(pta)(2) . Phen. The volatility of adducts decreases in the sequence Cu(thd)(2) . Phen, Cu(pta(2)). Phen and Cu(hfa)(2) . Phen changing inversely to that of the beta-diketonates. The variation of packing mode caused by the difference of the molecular structure is considered to be responsible for the effect. The changes of the electronic spectra of copper(II) beta-diketonates caused by adduct formation are discussed. (C) 1997 Elsevier Science Ltd.

  DOI：

  10.1016/s0277-5387(96)00519-0

文献信息

• Synthesis and crystal structure of copper(II) 2, 2, 6, 6-tetramethylheptan-3, 5-dionate adduct with o-phenanthroline
  作者：S.I. Troyanov、O.Yu. Gorbenko、A.A. Bosak

  DOI：10.1016/s0277-5387(96)00476-7

  日期：1997.3

  The X-ray crystal structure of Cu(thd)(2) . Phen, which is the first adduct of Cu(thd)(2) reported to be stable in the vapor phase, was determined. A cis-octahedral arrangement of chelate ligands around copper is of low symmetry due to Jahn-Teller distortion and the rigidity of the ligands. Peculiarities of the Cu(thd)(2) . Phen synthesis are discussed. (C) 1997 Elsevier Science Ltd.