Tert-butyl-(4-but-2-ynoxyhex-5-enoxy)-dimethylsilane | 859857-58-2

• 分子结构分类: 有机化合物 - 有机金属化合物 - 有机类金属化合物
• 英文名称: Tert-butyl-(4-but-2-ynoxyhex-5-enoxy)-dimethylsilane
• CAS: 859857-58-2
• 化学式: C₁₆H₃₀O₂Si
• 分子量: 282.498
• InChiKey: KLXWTZPGIANCIK-UHFFFAOYSA-N

计算性质

• 辛醇/水分配系数(LogP)：
  4.38
• 重原子数：
  19
• 可旋转键数：
  9
• 环数：
  0.0
• sp3杂化的碳原子比例：
  0.75
• 拓扑面积：
  18.5
• 氢给体数：
  0
• 氢受体数：
  2

反应信息

• 作为反应物：
  描述：

  Tert-butyl-(4-but-2-ynoxyhex-5-enoxy)-dimethylsilane 在 四丁基氟化铵 作用下， 生成
  参考文献：
  名称：

  Unexpected Dehydrogenation Products in the Furan Series Arising from Ruthenium‐Catalyzed 4‐Oxo‐1,6‐enyne Metathesis

  摘要：

  Metathesis of 4-oxo-1,6-enynes afforded the usual dihydrofuran products accompanied for the first time by unexpected side products identified as the corresponding furans. It probably arose from ruthenium-catalyzed dehydrogenation of dihydrofurans in the metathesis reaction mixture.

  DOI：

  10.1081/scc-200058011
• 作为产物：
  描述：

  6-((tert-butyldimethylsilyl)oxy)hex-1-en-3-ol 在 sodium hydroxide 、 正丁基锂 、 四丁基硫酸氢铵 作用下， 以 四氢呋喃 、 水 、 甲苯 为溶剂， 生成 Tert-butyl-(4-but-2-ynoxyhex-5-enoxy)-dimethylsilane
  参考文献：
  名称：

  Unexpected Dehydrogenation Products in the Furan Series Arising from Ruthenium‐Catalyzed 4‐Oxo‐1,6‐enyne Metathesis

  摘要：

  Metathesis of 4-oxo-1,6-enynes afforded the usual dihydrofuran products accompanied for the first time by unexpected side products identified as the corresponding furans. It probably arose from ruthenium-catalyzed dehydrogenation of dihydrofurans in the metathesis reaction mixture.

  DOI：

  10.1081/scc-200058011

文献信息

• Unexpected Dehydrogenation Products in the Furan Series Arising from Ruthenium‐Catalyzed 4‐Oxo‐1,6‐enyne Metathesis
  作者：Laurent Evanno、Bastien Nay、Bernard Bodo

  DOI：10.1081/scc-200058011

  日期：2005.6

  Metathesis of 4-oxo-1,6-enynes afforded the usual dihydrofuran products accompanied for the first time by unexpected side products identified as the corresponding furans. It probably arose from ruthenium-catalyzed dehydrogenation of dihydrofurans in the metathesis reaction mixture.