2-丙烯酸-2-[[(十七氟代辛基)磺酰基]甲基氨基]乙酯 | 25268-77-3

• 分子结构分类: 有机化合物 - 有机卤素化合物 - 卤代烷
• 中文名称: 2-丙烯酸-2-[[(十七氟代辛基)磺酰基]甲基氨基]乙酯
• 英文名称: 2-(N-methylperfluorooctanesulfonamido)ethyl acrylate
• 英文别名: MeFOSEA；C8F17-SO2(CH3)N-CH2CH2-OCOCH=CH2；2-(N-methylperfluorooctane-sulphonamido)ethyl acrylate；2-(((Heptadecafluorooctyl)sulphonyl)methylamino)ethyl acrylate；2-[1,1,2,2,3,3,4,4,5,5,6,6,7,7,8,8,8-heptadecafluorooctylsulfonyl(methyl)amino]ethyl prop-2-enoate
• CAS: 25268-77-3
• 化学式: C₁₄H₁₀F₁₇NO₄S
• 分子量: 611.277
• InChiKey: RTJZWOGSCLVJLD-UHFFFAOYSA-N

物化性质

• 沸点：
  348.0±52.0 °C(Predicted)
• 密度：
  1.610±0.06 g/cm3(Predicted)

计算性质

• 辛醇/水分配系数(LogP)：
  5.9
• 重原子数：
  37
• 可旋转键数：
  13
• 环数：
  0.0
• sp3杂化的碳原子比例：
  0.79
• 拓扑面积：
  72.1
• 氢给体数：
  0
• 氢受体数：
  22

反应信息

• 作为反应物：
  描述：

  2-丙烯酸-2-[[(十七氟代辛基)磺酰基]甲基氨基]乙酯 、 1-硫代甘油 在 偶氮二异丁腈 作用下， 以 乙酸乙酯 为溶剂， 反应 15.0h， 生成
  参考文献：
  名称：

  Alkylated fluorochemical oligomers and use thereof in the treatment of fibrous substrates

  摘要：

  这项发明提供了一种处理纤维基质（如皮革）的方法，包括将基质与含有氟化合物接触，该氟化合物包括：含有脂肪族骨架和多个挂链氟脂肪基团的氟化合物寡聚物部分，每个氟脂肪基团具有全氟化的末端基团，并且每个通过有机连接基团独立连接到脂肪族骨架的碳原子上；脂肪基团；以及将氟化合物寡聚物部分连接到脂肪基团的连接基团。这些氟化合物为纤维基质提供了理想的油、水和污渍防护性能。

  公开号：

  US20040024262A1

文献信息

• [EN] COMPOSITION COMPRISING A DISPERSION OF PARTICLES OF A GRAFTED ETHYLENIC POLYMER AND A FILM-FORMING AGENT<br/>[FR] COMPOSITION COMPORTANT UNE DISPERSION DE PARTICULES A BASE D'UN POLYMERE ETHYLENIQUE GREFFE ET D'UN AGENT FILMOGENE
  申请人：OREAL

  公开号：WO2005058274A1

  公开（公告）日：2005-06-30

  The present invention relates to a cosmetic composition comprising a dispersion of particles of a grafted ethylenic polymer in a liquid fatty phase, and a film-forming agent. The film-forming agent may be soluble or dispersible in the said liquid fatty phase. The composition may contain an aqueous phase, in which case the film-forming agent may be soluble or dispersible in the aqueous phase. A subject of the invention is also the use of a combination of such a grafted ethylenic polymer and of a film-forming agent to improve the staying power and/or the transfer resistance of the said composition on keratin materials.

  本发明涉及一种化妆品组合物，包括一种嵌接乙烯基聚合物颗粒分散于液态脂肪相中，并且含有一种成膜剂。该成膜剂可以溶解或分散于所述液态脂肪相中。该组合物可以包含水相，在这种情况下，成膜剂可以溶解或分散于水相中。本发明的一个对象还是使用这种嵌接乙烯基聚合物和成膜剂的组合物来提高该组合物在角质素材料上的持久性和/或转移抵抗力。
• Photosensitive material
  申请人：Daikin Kogyo Co., Ltd.

  公开号：EP0040841A1

  公开（公告）日：1981-12-02

  A copolymer comprising (a) a monomer having a C7 to C21 perfluoralkyl or perfluoralkenyl group at one end of the molecule and an ethylenically unsaturated group at the other end of the molecule, and (b( a monomer having a photosensitive group, e.g. an azidobenzoyloxy group, cinnamoyloxy group, benzoylphenyl group or a,#- unsaturated ketone group. The copolymer has an excellent photosensitivity and excellent water and oil repellent properties, and is useful for various purposes, e.g. as a photosensitive material for dry offset printing plate or resist and as a photo-curable, water and oil repelling coating material.

  一种共聚物，包括(a)分子一端为 C7 至 C21 全氟烷基或全氟烯基，分子另一端为乙烯基不饱和基团的单体，以及(b)具有感光基团（如叠氮苯甲酰氧基、肉桂酰氧基、苯甲酰苯基或 a,#-不饱和酮基）的单体。这种共聚物具有极佳的感光性和优异的防水防油性能，可用于多种用途，例如用作干胶印印版或抗蚀剂的感光材料，以及用作光固化防水防油涂层材料。
• Interpenetrating networks from unsaturated monomers and thermosetting resins
  申请人：SUMITOMO CHEMICAL COMPANY, LIMITED

  公开号：EP0632059A2

  公开（公告）日：1995-01-04

  A cured resin product obtained by mixing (A) a compound having an addition-polymerizable group and capable of yielding a thermoplastic resin by its polymerization and (B) a thermosetting resin to form a uniform solution or dispersion and then curing the component (B) while simultaneously polymerizing the component (A), a process for producing the same, a resin composition, and the use of the same. As compound A olefinically unsaturated monomers like styrene, acrylonitrile or (meth)acrylates, particularly perfluoroalkyl(meth)acrylates, are preferred. The thermosetting resin is for example a cyanate, maleimide, phenolic or preferably epoxy resin in combination with a suitable curing agent. The compositions are used for water repellent coatings or for sealing semiconductor elements.

  将(A)具有可加成聚合基团并能通过聚合生成热塑性树脂的化合物与(B)热固性树脂混合形成均匀溶液或分散液，然后在使组分(A)聚合的同时固化组分(B)而得到的固化树脂产品、生产该产品的工艺、树脂组合物以及该产品的用途。 化合物 A 首选烯烃不饱和单体，如苯乙烯、丙烯腈或（甲基）丙烯酸酯，特别是全氟烷基（甲基）丙烯酸酯。 热固性树脂可以是氰酸酯树脂、马来酰亚胺树脂、酚醛树脂，最好是环氧树脂，再加上适当的固化剂。这种组合物可用于防水涂层或密封半导体元件。
• Method of making fluoropolymers
  申请人：UNIVERSITY OF NORTH CAROLINA AT CHAPEL HILL

  公开号：EP1172383A2

  公开（公告）日：2002-01-16

  A process for making a fluoropolymer is disclosed. The process comprises solubilizing a fluoromonomer in solvent comprising a carbon dioxide fluid, and then polymerizing the fluoromonomer to produce a the fluoropolymer. A preferred solvent for carrying out the process is supercritical carbon dioxide; preferred fluoromonomers for carrying out the process are fluoroacrylate monomers such as 1,1-dihydroperfluorooctyl acrylate. The polymerization step is preferably carried out in the presence of an initiator such as azobisisobutyronitrile.

  本发明公开了一种制造含氟聚合物的工艺。该工艺包括在含有二氧化碳流体的溶剂中溶解含氟单体，然后聚合含氟单体以生产含氟聚合物。用于实施该工艺的优选溶剂是超临界二氧化碳；用于实施该工艺的优选含氟单体是丙烯酸氟酯单体，如丙烯酸 1,1-二氢全氟辛酯。聚合步骤最好在偶氮二异丁腈等引发剂存在下进行。
• Method of separating fluoropolymer from a solution therof and carbon dioxide
  申请人：The University of North Carolina at Chapel Hill

  公开号：EP1416002A2

  公开（公告）日：2004-05-06

  There is disclosed a method of making fluoropolymers by separating a solution of fluoropolymer and carbon dioxide, said method comprising: providing a solution consisting essentially of carbon dioxide and a fluoropolymer; and passing the solution through an orifice to separate the fluoropolymer from the solution and form a fluoropolymer layer on a substrate.

  本发明公开了一种通过分离含氟聚合物和二氧化碳溶液来制造含氟聚合物的方法，所述方法包括 提供主要由二氧化碳和含氟聚合物组成的溶液；以及 使溶液通过孔口，将含氟聚合物从溶液中分离出来，并在基底上形成含氟聚合物层。