2,3,4,5-tetra-O-methyl-6-O-triphenylmethyl-D-gluconic acid | 541550-96-3

• 分子结构分类: 有机化合物 - 苯类化合物 - 三苯基化合物
• 英文名称: 2,3,4,5-tetra-O-methyl-6-O-triphenylmethyl-D-gluconic acid
• 英文别名: (2R,3S,4R,5R)-2,3,4,5-tetramethoxy-6-trityloxyhexanoic acid
• CAS: 541550-96-3
• 化学式: C₂₉H₃₄O₇
• 分子量: 494.585
• InChiKey: BBYJRMWCHAEZLC-JVYGEBFASA-N

计算性质

• 辛醇/水分配系数(LogP)：
  4
• 重原子数：
  36
• 可旋转键数：
  14
• 环数：
  3.0
• sp3杂化的碳原子比例：
  0.34
• 拓扑面积：
  83.4
• 氢给体数：
  1
• 氢受体数：
  7

反应信息

• 作为反应物：
  描述：

  2,3,4,5-tetra-O-methyl-6-O-triphenylmethyl-D-gluconic acid 以 水 、 溶剂黄146 为溶剂， 反应 7.0h， 以90%的产率得到2,3,4,5-tetra-O-methyl-D-gluconic acid
  参考文献：
  名称：

  Synthesis of 2,3,4,5-tetra-O-methyl-d-glucono-1,6-lactone as a monomer for the preparation of copolyesters

  摘要：

  2,3,4,5-Tetra-O-methyl-D-glucono-1,6-lactone has been prepared as a crystalline compound in acceptable yield by two different routes. An initial assay of copolymerization with L-lactide by ring-opening polymerization was carried out. The incorporation of the carbohydrate monomer into the polymer chain was about 2%. (C) 2003 Elsevier Science Ltd. All rights reserved.

  DOI：

  10.1016/s0008-6215(02)00528-1
• 作为产物：
  描述：

  2,3,4,5-tetra-O-methyl-6-O-triphenylmethyl-D-glucose 在 重铬酸吡啶 作用下， 以 N,N-二甲基甲酰胺 为溶剂， 反应 20.0h， 以77%的产率得到2,3,4,5-tetra-O-methyl-6-O-triphenylmethyl-D-gluconic acid
  参考文献：
  名称：

  Synthesis of 2,3,4,5-tetra-O-methyl-d-glucono-1,6-lactone as a monomer for the preparation of copolyesters

  摘要：

  2,3,4,5-Tetra-O-methyl-D-glucono-1,6-lactone has been prepared as a crystalline compound in acceptable yield by two different routes. An initial assay of copolymerization with L-lactide by ring-opening polymerization was carried out. The incorporation of the carbohydrate monomer into the polymer chain was about 2%. (C) 2003 Elsevier Science Ltd. All rights reserved.

  DOI：

  10.1016/s0008-6215(02)00528-1

文献信息

• Synthesis of 2,3,4,5-tetra-O-methyl-d-glucono-1,6-lactone as a monomer for the preparation of copolyesters
  作者：Inmaculada Molina Pinilla、Manuel Bueno Martı́nez、Juan A Galbis

  DOI：10.1016/s0008-6215(02)00528-1

  日期：2003.3

  2,3,4,5-Tetra-O-methyl-D-glucono-1,6-lactone has been prepared as a crystalline compound in acceptable yield by two different routes. An initial assay of copolymerization with L-lactide by ring-opening polymerization was carried out. The incorporation of the carbohydrate monomer into the polymer chain was about 2%. (C) 2003 Elsevier Science Ltd. All rights reserved.