1H,2H,4H/5H-Octafluor-cyclohexan | 1526-36-9

• 分子结构分类: 有机化合物 - 有机卤素化合物 - 卤代烷
• 英文名称: 1H,2H,4H/5H-Octafluor-cyclohexan
• 英文别名: 1H,4H/2H,5H-Octafluor-cyclohexan；1H,5H/2H,4H-Octafluor-cyclohexan；1,1,2,3,4,4,5,6-Octafluorocyclohexane
• CAS: 1526-36-9
• 化学式: C₆H₄F₈
• 分子量: 228.085
• InChiKey: KGINMAINGOBGJX-UHFFFAOYSA-N

计算性质

• 辛醇/水分配系数(LogP)：
  3
• 重原子数：
  14
• 可旋转键数：
  0
• 环数：
  1.0
• sp3杂化的碳原子比例：
  1.0
• 拓扑面积：
  0
• 氢给体数：
  0
• 氢受体数：
  8

反应信息

• 作为反应物：
  描述：

  1H,2H,4H/5H-Octafluor-cyclohexan 在 氢氧化钾 、 silicone antifoam agent 作用下， 以 水 为溶剂， 反应 0.25h， 生成 五氟苯 、 (+/-)-1,3,3,4r,5t,6,6-heptafluoro-cyclohexene
  参考文献：
  名称：

  Fluorocyclohexanes part XV [1] dehydrofluorinations of undeca- deca- and nona- fluorocyclohexanes

  摘要：

  DOI：

  10.1016/s0022-1139(00)82205-8

文献信息

• METHOD FOR PRODUCING FLUORINE-CONTAINING POLYMER, FLUORINE-CONTAINING POLYMER HAVING FUNCTIONAL GROUP AND ELECTROLYTE MEMBRANE
  申请人：AGC Inc.

  公开号：EP3643728A1

  公开（公告）日：2020-04-29

  To provide a method for producing a fluorinated polymer which enables stable production of a fluorinated polymer having a high molecular weight at a high polymerization rate with good productivity and reduced environmental burdens, a method for producing a fluorinated polymer having functional groups, and a method for producing an electrolyte membrane. A method for producing a fluorinated polymer, which comprises polymerizing a monomer mixture containing tetrafluoroethylene and a fluorinated monomer having a group convertible to a sulfonic acid group or a carboxylic acid group in a polymerization medium, wherein the polymerization medium contains as the main component a C4-10 cyclic hydrofluorocarbon. Further, a method for producing a fluorinated polymer having functional groups and a method for producing an electrolyte membrane, employing the production method.

  提供一种生产含氟聚合物的方法，该方法能够以较高的聚合速率稳定地生产具有较高分子量的含氟聚合物，同时具有较好的生产率和较低的环境负担；还提供一种生产具有官能团的含氟聚合物的方法，以及一种生产电解质膜的方法。 一种生产含氟聚合物的方法，包括在聚合介质中聚合含有四氟乙烯和具有可转化为磺酸基团或羧酸基团的含氟单体的单体混合物，其中聚合介质的主要成分为 C4-10 环烃。此外，一种生产具有官能团的含氟聚合物的方法，以及一种采用该生产方法生产电解质膜的方法。
• Methods for producing fluorinated polymer, fluorinated polymer having functional group and electrolyte membrane
  申请人：AGC Inc.

  公开号：US10975209B2

  公开（公告）日：2021-04-13

  To provide a method for producing a fluorinated polymer which enables stable production of a fluorinated polymer having a high molecular weight at a high polymerization rate with good productivity and reduced environmental burdens, a method for producing a fluorinated polymer having functional groups, and a method for producing an electrolyte membrane. A method for producing a fluorinated polymer, which comprises polymerizing a monomer mixture containing tetrafluoroethylene and a fluorinated monomer having a group convertible to a sulfonic acid group or a carboxylic acid group in a polymerization medium, wherein the polymerization medium contains as the main component a C4-10 cyclic hydrofluorocarbon. Further, a method for producing a fluorinated polymer having functional groups and a method for producing an electrolyte membrane, employing the production method.

  提供一种生产含氟聚合物的方法，该方法能够以较高的聚合速率稳定地生产具有较高分子量的含氟聚合物，同时具有较好的生产率和较低的环境负担；还提供一种生产具有官能团的含氟聚合物的方法，以及一种生产电解质膜的方法。一种生产含氟聚合物的方法，包括在聚合介质中聚合含有四氟乙烯和具有可转化为磺酸基团或羧酸基团的含氟单体的单体混合物，其中聚合介质的主要成分为 C4-10 环烃。此外，一种生产具有官能团的含氟聚合物的方法，以及一种采用该生产方法生产电解质膜的方法。
• METHODS FOR PRODUCING FLUORINATED POLYMER, FLUORINATED POLYMER HAVING FUNCTIONAL GROUP AND ELECTROLYTE MEMBRANE
  申请人：AGC Inc.

  公开号：US20200123337A1

  公开（公告）日：2020-04-23

  To provide a method for producing a fluorinated polymer which enables stable production of a fluorinated polymer having a high molecular weight at a high polymerization rate with good productivity and reduced environmental burdens, a method for producing a fluorinated polymer having functional groups, and a method for producing an electrolyte membrane. A method for producing a fluorinated polymer, which comprises polymerizing a monomer mixture containing tetrafluoroethylene and a fluorinated monomer having a group convertible to a sulfonic acid group or a carboxylic acid group in a polymerization medium, wherein the polymerization medium contains as the main component a C 4-10 cyclic hydrofluorocarbon. Further, a method for producing a fluorinated polymer having functional groups and a method for producing an electrolyte membrane, employing the production method.
• Fluorocyclohexanes part XV [1] dehydrofluorinations of undeca- deca- and nona- fluorocyclohexanes
  作者：Paul L. Coe、Andrew W. Mott、John Colin Tatlow

  DOI：10.1016/s0022-1139(00)82205-8

  日期：1982.4