biphenyl-4-yl-(4-naphthalen-1-yl-phenyl)-(4-(9-phenyl-9H-carbazol-3-yl)-phenyl)-amine | 1160294-68-7

• 分子结构分类: 有机化合物 - 有机氮化合物
• 英文名称: biphenyl-4-yl-(4-naphthalen-1-yl-phenyl)-(4-(9-phenyl-9H-carbazol-3-yl)-phenyl)-amine
• 英文别名: N-(4-naphthalen-1-ylphenyl)-4-phenyl-N-[4-(9-phenylcarbazol-3-yl)phenyl]aniline
• CAS: 1160294-68-7
• 化学式: C₅₂H₃₆N₂
• 分子量: 688.871
• InChiKey: YJISGTKAUZHMRF-UHFFFAOYSA-N

计算性质

• 辛醇/水分配系数(LogP)：
  14.4
• 重原子数：
  54
• 可旋转键数：
  7
• 环数：
  10.0
• sp3杂化的碳原子比例：
  0.0
• 拓扑面积：
  8.2
• 氢给体数：
  0
• 氢受体数：
  1

反应信息

• 作为产物：
  描述：

  N-苯基-3-咔唑硼酸 、 (4-bromo-phenyl)-(4-naphthalen-1-yl-phenyl)-biphenyl-4-yl-amine 在 palladium diacetate 、 三(邻甲基苯基)磷 potassium carbonate 作用下， 以 乙醇 、 水 、 甲苯 为溶剂， 反应 2.0h， 以44%的产率得到biphenyl-4-yl-(4-naphthalen-1-yl-phenyl)-(4-(9-phenyl-9H-carbazol-3-yl)-phenyl)-amine
  参考文献：
  名称：

  [EN] CARBAZOLE DERIVATIVE, AND LIGHT-EMITTING ELEMENT, LIGHT-EMITTING DEVICE, AND ELECTRONIC DEVICE USING CARBAZOLE DERIVATIVE
  [FR] DÉRIVÉ CARBAZOLE, ET ÉLÉMENT ÉMETTANT DE LA LUMIÈRE, DISPOSITIF ÉMETTANT DE LA LUMIÈRE, ET DISPOSITIF ÉLECTRONIQUE UTILISANT LE DÉRIVÉ CARBAZOLE

  摘要：

  为提供具有高发光效率的发光元件，并提供一种低功耗、低电压驱动的发光装置和电子设备，提供了由通式（1）表示的咔唑衍生物。在该式中，α1、α2、α3 和 α4 分别表示具有小于或等于 13 个碳原子的芳基基团；Ar1 和 Ar2 分别表示具有小于或等于 13 个碳原子的芳基基团；R1 表示氢原子、具有 1 到 6 个碳原子的烷基基团、取代或未取代的苯基团，以及取代或未取代的联苯基团中的任意一种；R2 表示具有 1 到 6 个碳原子的烷基基团、取代或未取代的苯基团，以及取代或未取代的联苯基团中的任意一种。此外，l、m 和 n 分别独立地为 0 或 1。

  公开号：

  WO2009072587A1

文献信息

• ORGANIC LIGHT EMITTING DEVICE
  申请人：SAMSUNG DISPLAY CO., LTD.

  公开号：US20170288147A1

  公开（公告）日：2017-10-05

  An organic light emitting device including an anode; a hole transport region on the anode; an emission layer on the hole transport region; an electron transport region on the emission layer; and a cathode on the electron transport region, wherein the hole transport region includes: a first hole transport layer including a first hole transport material represented by the following Formula 1 or a second hole transport material represented by the following Formula 2; and a second hole transport layer on the first hole transport layer, the second hole transport layer including a third hole transport material represented by the following Formula 3 or a fourth hole transport material represented by the following Formula 4:

  一种有机发光器件，包括：阳极；位于阳极上的空穴传输区域；位于空穴传输区域上的发射层；位于发射层上的电子传输区域；以及位于电子传输区域上的阴极，其中空穴传输区域包括：第一空穴传输层，包括由以下化学式1表示的第一空穴传输材料或由以下化学式2表示的第二空穴传输材料；以及位于第一空穴传输层上的第二空穴传输层，第二空穴传输层包括由以下化学式3表示的第三空穴传输材料或由以下化学式4表示的第四空穴传输材料：
• Compound, organic electric element using the same, and an electronic device thereof
  申请人：DUK SAN NEOLUX CO., LTD.

  公开号：US10026905B2

  公开（公告）日：2018-07-17

  A compound represented by Formula 1. An organic electric element includes a first electrode, a second electrode, and an organic material layer including the compound of Formula 1. The organic material layer include a light emitting layer, a hole transport layer including a compound represented by Formula 2, and an emission-auxiliary layer including the compound represented by Formula 1. When the organic electric element includes the compound in the organic material layer, luminous efficiency, color purity, and life span can be improved.

  由公式1表示的化合物。一种有机电元件包括第一电极、第二电极和包括公式1所表示的化合物的有机材料层。有机材料层包括发光层、包括公式2所表示的化合物的空穴传输层，以及包括公式1所表示的化合物的发射辅助层。当有机电元件包括有机材料层中的该化合物时，可以改善发光效率、色彩纯度和寿命。
• Carbazole Derivative, and Light-Emitting Element, Light-Emitting Device, and Electronic Device Using Carbazole Derivative
  申请人：Nomura Hiroko

  公开号：US20090160323A1

  公开（公告）日：2009-06-25

  To provide a light-emitting element having high luminous efficiency and to provide a light-emitting device and an electronic device which consumes low power and is driven at low voltage, a carbazole derivative represented by the general formula (1) is provided. In the formula, α 1 , α 2 , α 3 , and α 4 each represent an arylene group having less than or equal to 13 carbon atoms; Ar 1 and Ar 2 each represent an aryl group having less than or equal to 13 carbon atoms; R 1 represents any of a hydrogen atom, an alkyl group having 1 to 6 carbon atoms, a substituted or unsubstituted phenyl group, and a substituted or unsubstituted biphenyl group; and R 2 represents any of an alkyl group having 1 to 6 carbon atoms, a substituted or unsubstituted phenyl group, and a substituted or unsubstituted biphenyl group. In addition, l, m, and n are each independently 0 or 1.

  为了提供具有高发光效率的发光元件，并提供低功耗、低电压驱动的发光装置和电子装置，提供了由通式（1）表示的咔唑衍生物。在该式中，α1、α2、α3和α4各代表具有小于或等于13个碳原子的芳烃基；Ar1和Ar2各代表具有小于或等于13个碳原子的芳基；R1代表氢原子、具有1至6个碳原子的烷基、取代或未取代的苯基和取代或未取代的联苯基中的任意一种；R2代表具有1至6个碳原子的烷基、取代或未取代的苯基和取代或未取代的联苯基中的任意一种。此外，l、m和n各自独立地为0或1。
• Carbazole derivative, and light-emitting element, light-emitting device, and electronic device uing carbazole derivative
  申请人：Semiconductor Energy Laboratory Co., Ltd.

  公开号：EP2757094A1

  公开（公告）日：2014-07-23

  The present invention provides a novel carbazole derivative which may be used for the production of a light-emitting element having high luminous efficiency, and for the manufacture of light-emitting devices and electronic devices which consume low power and are driven at low voltage.

  本发明提供了一种新型咔唑衍生物，可用于生产具有高发光效率的发光元件，以及制造低功耗、低电压驱动的发光器件和电子设备。
• Light-emitting element, light-emitting device, electronic device, and lighting device
  申请人：Semiconductor Energy Laboratory Co., Ltd.

  公开号：US10249837B2

  公开（公告）日：2019-04-02

  Provided is a light-emitting element having a light-emitting layer which contains at least a host material and a plurality of guest materials, where the host material has a lower T1 level than that of at least one of the plurality of guest materials. The emission of the one of the plurality of guest materials exhibits a multicomponent decay curve, and the lifetime thereof is less than or equal to 15 μsec, preferably less than or equal to 10 μsec, more preferably less than or equal to 5 μsec, where the lifetime is defined as a time for the emission to decrease in intensity to 1/100 of its initial intensity.

  本发明提供了一种具有发光层的发光元件，该发光层至少包含一种主材料和多种客体材料，其中主材料的 T1 水平低于多种客体材料中至少一种材料的 T1 水平。多种客体材料之一的发射呈现多分量衰减曲线，其寿命小于或等于 15 微秒，优选小于或等于 10 微秒，更优选小于或等于 5 微秒，其中寿命定义为发射强度下降到初始强度的 1/100 的时间。