benzoylacetone 1-naphthoylhydrazone | 104201-11-8

• 分子结构分类: 有机化合物 - 苯类化合物 - 萘
• 英文名称: benzoylacetone 1-naphthoylhydrazone
• 英文别名: benzoylacetone-1-naphtoylhydrazone
• CAS: 104201-11-8
• 化学式: C₂₁H₁₈N₂O₂
• 分子量: 330.386
• InChiKey: HHEKBPRSEYPQLD-UHFFFAOYSA-N

计算性质

• 辛醇/水分配系数(LogP)：
  4.22
• 重原子数：
  25.0
• 可旋转键数：
  5.0
• 环数：
  3.0
• sp3杂化的碳原子比例：
  0.1
• 拓扑面积：
  58.53
• 氢给体数：
  1.0
• 氢受体数：
  3.0

反应信息

• 作为反应物：
  描述：

  iron(III) chloride hexahydrate 、 benzoylacetone 1-naphthoylhydrazone 以 乙醇 为溶剂， 生成
  参考文献：
  名称：

  Complexes of iron(III) with benzoylacetone 1-naphthoylhydrazone

  摘要：

  DOI：

  10.1016/s0277-5387(00)80139-4

文献信息

• ——
  作者：K. Andjelković、M. Šumar、I. Ivanović-Burmazović

  DOI：10.1023/a:1013140021386

  日期：——

  Results of our research on synthesis and characterization of complexes with acylhydrazone derivatives are described in this review paper. Structural characterization of newly synthesized complexes by thermal analysis (TG, DTA, DSC) is particularly emphasized in this paper. Thermal analysis enabled us to Study not only structural changes of substances during thermal treatment, but also the mode of coordination and degree of deprotonation of acylhydrazones, as well as geometry of the coordination sphere of complexes, the structure of which had not been determined by X-ray analysis. Topics in this paper are as follows: complexes of dioxomolybdenum(VI) with tridentate hydrazones, usnic acid derivatives and their Cu(II) complexes, as well as transition metal complexes with 2,6-diacetylpyridine bis(hydrazones).