| 202071-20-3

• 分子结构分类: 无机化合物
• CAS: 202071-20-3
• 化学式: H₆O₆Pu
• 分子量: 341.044
• InChiKey: VVHOBQOLJBEJHB-ZFNFDAPRSA-H

计算性质

• 辛醇/水分配系数(LogP)：
  -3.34
• 重原子数：
  7.0
• 可旋转键数：
  0.0
• 环数：
  0.0
• sp3杂化的碳原子比例：
  0.0
• 拓扑面积：
  121.38
• 氢给体数：
  6.0
• 氢受体数：
  6.0

反应信息

• 作为产物：
  描述：

  钚 、 sodium hydroxide 、 lithium hydroxide 、 水 以 水 为溶剂， 生成 、 tetrasodium dihydroxidotetraoxidoplutonate(VII) hydroxidedihydrate
  参考文献：
  名称：

  Novel heptavalent actinide compounds: tetrasodium dihydroxidotetraoxidoneptunate(VII) hydroxide dihydrate and its plutonium analogue

  摘要：

  The title compounds, Na-4[NpO4(OH)(2)]OH center dot 2H(2)O and Na-4[PuO4(OH)(2)]OH center dot 2H(2)O, are isostructural and isomorphous, and contain complex [AnO(4)(OH)(2)](3-) anions (Ac is an actinide)in the form of distorted tetragonal bipyramids, Na+ cations, crystallization water molecules and outer-sphere OH groups. The complex [AnO(4)(OH)(2)](3-) anions occupy general positions and the coordinated OH groups deviate significantly from a centrosymmetric relative orientation. The [AnO(4)(OH)(2)](3-) anions exhibit anisotropic actinide contraction; the shortening of the An-O(hydroxide)bonds on going from Np to Pu is greater than that of the AnO(4) groups.

  DOI：

  10.1107/s0108270109044394