1,2-bis(2-ethoxy-5-phenyl-3-thienyl)perfluorocyclopentene | 443890-91-3

• 分子结构分类: 有机化合物 - 有机杂环化合物 - 噻吩类
• 英文名称: 1,2-bis(2-ethoxy-5-phenyl-3-thienyl)perfluorocyclopentene
• 英文别名: 1,2-bis[2-ethoxy-5-phenyl-3-thienyl]perfluorocyclopentene；1,2-Bis(2-ethoxy-5-phenyl-3-thienyl)-3,3,4,4,5,5-hexafluoro-1-cyclopentene；2-ethoxy-3-[2-(2-ethoxy-5-phenylthiophen-3-yl)-3,3,4,4,5,5-hexafluorocyclopenten-1-yl]-5-phenylthiophene
• CAS: 443890-91-3
• 化学式: C₂₉H₂₂F₆O₂S₂
• 分子量: 580.615
• InChiKey: POKZSGZUQYDRFN-UHFFFAOYSA-N

计算性质

• 辛醇/水分配系数(LogP)：
  8.8
• 重原子数：
  39
• 可旋转键数：
  8
• 环数：
  5.0
• sp3杂化的碳原子比例：
  0.24
• 拓扑面积：
  74.9
• 氢给体数：
  0
• 氢受体数：
  10

反应信息

• 作为反应物：
  描述：

  1,2-bis(2-ethoxy-5-phenyl-3-thienyl)perfluorocyclopentene 以 正己烷 为溶剂， 生成 9a,9b-Diethoxy-4,4,5,5,6,6-hexafluoro-2,8-diphenyl-5,6,9a,9b-tetrahydro-4H-1,9-dithia-trindene
  参考文献：
  名称：

  Dithienylethenes with a Novel Photochromic Performance

  摘要：

  Dithienylethenes with low decoloration quantum yields and thermal reversibility at high temperature above 100degreesC were prepared. Introduction of bulky alkoxy substituents at 2- and 2'-positions of the thiophene rings strongly suppressed the cycloreversion quantum yields. The quantum yields were lower than 10(-3), and the photogenerated color remained stable enough under room light. On the other hand, the bulky alkoxy substituent decreased the thermal stability of the colored closed-ring isomers at high temperature. The color of the dithienylethene with cyclohexyloxy substituents faded out in less than 1 min at 160degreesC.

  DOI：

  10.1021/jo020114o
• 作为产物：
  描述：

  3,5-dibromo-2-ethoxythiophene 在 正丁基锂 作用下， 以 四氢呋喃 、 正己烷 为溶剂， 反应 7.0h， 生成 1,2-bis(2-ethoxy-5-phenyl-3-thienyl)perfluorocyclopentene
  参考文献：
  名称：

  Dithienylethenes with a Novel Photochromic Performance

  摘要：

  Dithienylethenes with low decoloration quantum yields and thermal reversibility at high temperature above 100degreesC were prepared. Introduction of bulky alkoxy substituents at 2- and 2'-positions of the thiophene rings strongly suppressed the cycloreversion quantum yields. The quantum yields were lower than 10(-3), and the photogenerated color remained stable enough under room light. On the other hand, the bulky alkoxy substituent decreased the thermal stability of the colored closed-ring isomers at high temperature. The color of the dithienylethene with cyclohexyloxy substituents faded out in less than 1 min at 160degreesC.

  DOI：

  10.1021/jo020114o

文献信息

• Pohtochromic material
  申请人：JAPAN SCIENCE AND TECHNOLOGY CORPORATION

  公开号：US20040049040A1

  公开（公告）日：2004-03-11

  A photochromic material having a ring opening quantum yield of 10 −3 or lower which does not fade under ambient light is provided. The material comprises a compound belonging to the diheteroarylethene class. The compound has alkoxy group and aryl group on the heteroaryl group.

  提供一种具有环开放量子产率为10^-3或更低且不会在常温光线下褪色的光致变色材料。该材料包括属于二杂环乙烯类的化合物。该化合物在杂环基上具有烷氧基和芳基。
• PHOTOCHROMIC MATERIAL
  申请人：Japan Science and Technology Agency

  公开号：EP1367111B1

  公开（公告）日：2009-07-22
• DEVELOPERS AND METHOD OF COLORING LITHOGRAPHIC PRINTING MEMBERS
  申请人：Figov Murray

  公开号：US20120045720A1

  公开（公告）日：2012-02-23

  A color contrast image in imaged lithographic printing precursors can be obtained by contacting the imaged precursor with a coloration solution containing a colorless form of a photochromic compound. Residual amounts of this compound attached to the oleophilic surface of the imaged precursor can be changed to its colored form when exposed to UV light. The coloration solution can be an alkaline or acidic developer or an alkaline or acidic solution used separately after development. The coloration solution can also be a gum solution.
• US7057054B2
  申请人：——

  公开号：US7057054B2

  公开（公告）日：2006-06-06
• US8420297B2
  申请人：——

  公开号：US8420297B2

  公开（公告）日：2013-04-16