1,3,5-tri(prop-2-yn-1-yl)-1,3,5-triazinane-2,4,6-trione | 13185-65-4

• 分子结构分类: 有机化合物 - 有机杂环化合物 - 三嗪类
• 英文名称: 1,3,5-tri(prop-2-yn-1-yl)-1,3,5-triazinane-2,4,6-trione
• 英文别名: TPYTATO；1,3,5-triprop-2-ynyl-[1,3,5]triazinane-2,4,6-trione；Tripropargylisocyanurat；1,3,5-Tri-prop-2-ynyl-[1,3,5]triazinane-2,4,6-trione；1,3,5-tris(prop-2-ynyl)-1,3,5-triazinane-2,4,6-trione
• CAS: 13185-65-4
• 化学式: C₁₂H₉N₃O₃
• 分子量: 243.222
• InChiKey: ZZNPHULACRQIKD-UHFFFAOYSA-N

计算性质

• 辛醇/水分配系数(LogP)：
  -0.3
• 重原子数：
  18
• 可旋转键数：
  3
• 环数：
  1.0
• sp3杂化的碳原子比例：
  0.25
• 拓扑面积：
  60.9
• 氢给体数：
  0
• 氢受体数：
  3

反应信息

• 作为反应物：
  描述：

  1,3,5-tri(prop-2-yn-1-yl)-1,3,5-triazinane-2,4,6-trione 在 N-溴代丁二酰亚胺(NBS) 、 silver nitrate 作用下， 以 丙酮 为溶剂， 以45%的产率得到1,3,5-tris(3-bromoprop-2-ynyl)-1,3,5-triazinane-2,4,6-trione
  参考文献：
  名称：

  Synthesis of Podands with Cyanurate or Isocyanurate Cores and Terminal Triple Bonds

  摘要：

  报告了以氰尿酸或异氰尿酸核为核心、带有末端三键或溴化三键的聚氧乙烯侧臂的穴状配体合成。氰尿酸衍生穴状配体的起始原料为市售氰尿酸，而异氰尿酸衍生物则通过相应氰尿酸盐的热异构化获得。

  DOI：

  10.1055/s-0029-1218724
• 作为产物：
  描述：

  3-溴丙炔 、 氰尿酸 在 potassium carbonate 作用下， 以 N,N-二甲基甲酰胺 为溶剂， 反应 24.0h， 以48%的产率得到1,3,5-tri(prop-2-yn-1-yl)-1,3,5-triazinane-2,4,6-trione
  参考文献：
  名称：

  Participation of compact planar 1,3,5-tri(buta-2,3-dien-1-yl)-1,3,5-triazinane-2,4,6-trione in Pd(0) catalysed seven component cascade reactions delivers novel tunable molecular architecture

  摘要：

  We report the spatially controlled, protecting group free, catalytic assembly of a library of nineteen 7-component cascade products generated from a novel planar trisallenyl 1,3,5-triazinane-2,4,6-trione core in combination with aryl iodides and amines with excellent regio and good stereoaselectivity for Z,Z,Z-isomers. (C) 2014 Elsevier Ltd. All rights reserved.

  DOI：

  10.1016/j.tet.2014.05.025

文献信息

• NON-AQUEOUS ELECTROLYTE SOLUTION, AND NON-AQUEOUS-ELECTROLYTE SECONDARY CELL USING SAME
  申请人：Mitsubishi Chemical Corporation

  公开号：EP3252861A1

  公开（公告）日：2017-12-06

  There is provided a non-aqueous electrolyte solution enabling fabrication of a non-aqueous electrolyte solution secondary battery which achieves suppressed gas generation when used under high temperature environment and the improved residual capacity of the battery, and the improved cycle characteristic thereof, and further, is excellent in discharge load characteristic (dischargeable at high rate), and a non-aqueous electrolyte solution secondary battery using the non-aqueous electrolyte solution. There is provided a non-aqueous electrolyte solution for use in a non-aqueous electrolyte solution secondary battery including a positive electrode having a positive electrode active material capable of absorbing and releasing a metal ion and a negative electrode having a negative electrode active material capable of absorbing and releasing a metal ion, which solution contains a bismaleimide compound having a specific structure, and a non-aqueous electrolyte solution secondary battery using the solution.

  本发明提供了一种非水电解质溶液，该溶液可用于制造非水电解质溶液二次电池，在高温环境下使用时可抑制气体生成，提高电池的剩余容量，改善循环特性，而且放电负载特性优异（可高速放电），还提供了一种使用该非水电解质溶液的非水电解质溶液二次电池。提供了一种用于非水电解质溶液二次电池的非水电解质溶液，该二次电池包括正极和负极，正极具有能够吸收和释放金属离子的正极活性材料，负极具有能够吸收和释放金属离子的负极活性材料，该溶液含有具有特定结构的双马来酰亚胺化合物，还提供了一种使用该溶液的非水电解质溶液二次电池。
• NONAQUEOUS ELECTROLYTE SOLUTION AND NONAQUEOUS ELECTROLYTE BATTERY
  申请人：Mitsubishi Chemical Corporation

  公开号：EP3780226A1

  公开（公告）日：2021-02-17

  Provided is a nonaqueous electrolyte battery in which not only the generation of a gas during high-temperature storage but also an increase in the battery resistance are inhibited. Also provided is a nonaqueous electrolyte solution containing: a compound represented by the following Formula (A); a cyclic carbonate having an unsaturated carbon-carbon bond; and at least one compound selected from the group consisting of compounds represented by the following Formula (B) or (C). In this nonaqueous electrolyte solution, the content of the cyclic carbonate having an unsaturated carbon-carbon bond with respect to a total amount of the nonaqueous electrolyte solution is in a specific range, and the content of the at least one compound selected from the group consisting of compounds represented by Formula (B) or (C) is in a specific range.         OCN-Q-NCO     (C)

  本发明提供了一种非水电解质电池，它不仅能抑制高温储存期间气体的产生，还能抑制电池电阻的增加。本发明还提供了一种非水电解质溶液，其中含有：由下式（A）代表的化合物；具有不饱和碳碳键的环状碳酸盐；以及至少一种选自由下式（B）或（C）代表的化合物组成的化合物组。在该非水电解质溶液中，具有不饱和碳-碳键的环状碳酸盐的含量占该非水电解质溶液总量的比例在特定范围内，至少一种选自由式（B）或（C）代表的化合物组成的组的化合物的含量在特定范围内。 OCN-Q-NCO (C)
• UV curable inkjet inks
  申请人：AGFA NV

  公开号：US10513620B2

  公开（公告）日：2019-12-24

  An aqueous UV free radical curable inkjet ink contains a liquid phase A dispersed in a continuous liquid phase B by a polymeric dispersant; wherein the liquid phase A contains at least a photoinitiator, a colour pigment, and one or more polymerizable compounds, and the continuous liquid phase B contains water and optionally one or more organic solvents.

  一种水性紫外线自由基固化喷墨墨水含有通过聚合物分散剂分散在连续液相 B 中的液相 A；其中液相 A 至少含有光引发剂、彩色颜料和一种或多种可聚合化合物，连续液相 B 含有水和可选的一种或多种有机溶剂。
• Cryptands and bismacrocycles with cyanuric and isocyanuric units: synthesis and structural investigations
  作者：Flavia Pop、Crina Socaci、Anamaria Terec、Eric Condamine、Richard Attila Varga、Ciprian I. Raţ、Jean Roncali、Ion Grosu

  DOI：10.1016/j.tet.2012.07.100

  日期：2012.10

  Hay synthesis of cryptands and bismacrocycles starting from tripodands with cyanuric and isocyanuric cores is reported. The structure of the compounds is revealed by X-ray diffraction, NMR spectrometry and MS investigations. DNMR experiments carried out with bismacrocycles indicated the flipping of the rings and the free-energy barrier for the conformational process could be determined in one case. (C) 2012 Elsevier Ltd. All rights reserved.
• UV CURABLE INKJET INKS
  申请人：AGFA NV

  公开号：EP3156461B1

  公开（公告）日：2020-04-01