1-chloro-1,2,2-tris-(diethylamino)dimethyldisilane | 186352-67-0

• 分子结构分类: 有机化合物 - 有机金属化合物 - 有机类金属化合物
• 英文名称: 1-chloro-1,2,2-tris-(diethylamino)dimethyldisilane
• 英文别名: Cl(NEt2)MeSi-SiMe(NEt2)2；ClNEt2MeSi-SiMe(NEt2)2；chloro-1,2,2-tris(diethylamino)dimethyldisilane；1-Chloro-1,2,2-tris(diethylamino)dimethyldisilane；N-[[chloro-(diethylamino)-methylsilyl]-(diethylamino)-methylsilyl]-N-ethylethanamine
• CAS: 186352-67-0
• 化学式: C₁₄H₃₆ClN₃Si₂
• 分子量: 338.084
• InChiKey: ORMZIFRINPUJFQ-UHFFFAOYSA-N

物化性质

• 沸点：
  140 °C(Press: 5 Torr)
• 密度：
  0.928±0.06 g/cm3(Predicted)

计算性质

• 辛醇/水分配系数(LogP)：
  3.47
• 重原子数：
  20
• 可旋转键数：
  10
• 环数：
  0.0
• sp3杂化的碳原子比例：
  1.0
• 拓扑面积：
  9.7
• 氢给体数：
  0
• 氢受体数：
  3

反应信息

• 作为反应物：
  描述：

  1-chloro-1,2,2-tris-(diethylamino)dimethyldisilane 在 甲基三氯硅烷 、 lithium 作用下， 以 四氢呋喃 、 氘代氯仿 为溶剂， 生成 bis(diethylamino)chloromethylsilane
  参考文献：
  名称：

  Preparation and29Si NMR spectroscopical investigations of (diethylamino)-methylchlorotetra- and pentasilanes

  摘要：

  The treatment of several branched methylchlorooligosilanes (Si-4, Si-5) with diethylamine leads to a partial or complete substitution of the chloro substituents for diethylamino groups under formation of the first known (diethylamino)-methylchlorooligosilanes containing more than two Si atoms. The condensation of (Et2N)(2)MeSi-SiMeCl(NEt2) (1d) with Li in THF yields the linear tetrasilane (Et2N)(2)MeSi-SiMe(NEt2)-SiMe(NEt2)-SiMe(Et2N)(2) (2a).The NMR investigations provided information of the general shift ranges of several Si units in (diethylamino)-methylchlorooligosilane systems as well as the number of stereoisomers of the prepared products.

  DOI：

  10.1002/prac.199733901113
• 作为产物：
  描述：

  1,2-二甲基-1,1,2,2-四氯二硅烷 、 二乙胺 生成 1-chloro-1,2,2-tris-(diethylamino)dimethyldisilane
  参考文献：
  名称：

  Nitsche, Silke; Trommer, Kristin; Palitzsch, Wolfram, Phosphorus, Sulfur and Silicon and the Related Elements, 2001, vol. 169, p. 177 - 184

  摘要：

  DOI：

文献信息

• New olefinic functionalized disilanes. Synthesis and NMR spectroscopical investigations
  作者：K. Trommer、U. Herzog、G. Roewer

  DOI：10.1016/s0022-328x(97)00109-5

  日期：1997.8

  The new olefinic substituted aminodisilanes, which are obtained from the reaction of organometallic reagents with aminochlorodisilanes, are converted into the chlorodisilanes by equilibration reactions or treatment with HCl. The resulting olefinic functionalized disilanes are identified by means of Si-29, C-13, H-1 NMR and GC MS measurements. (C) 1997 Elsevier Science S.A.
• NMR spectroscopic investigation of the Reaction between Tetrachlorodimethyldisilane and Diethylamine for the synthesis of chloro- and amino-functionalized methyldisilanes
  作者：K. Trommer、G. Roewer、E. Brendler

  DOI：10.1002/prac.19973390114

  日期：——
• Trommer, K.; Herzog, U.; Georgi, U., Journal fur Praktische Chemie - Chemiker-Zeitung, 1998, vol. 340, # 6, p. 557 - 561
  作者：Trommer, K.、Herzog, U.、Georgi, U.、Roewer, G.

  DOI：——

  日期：——
• Preparation and29Si NMR spectroscopical investigations of (diethylamino)-methylchlorotetra- and pentasilanes
  作者：Kristin Trommer、Uwe Herzog、Gerhard Roewer

  DOI：10.1002/prac.199733901113

  日期：——

  The treatment of several branched methylchlorooligosilanes (Si-4, Si-5) with diethylamine leads to a partial or complete substitution of the chloro substituents for diethylamino groups under formation of the first known (diethylamino)-methylchlorooligosilanes containing more than two Si atoms. The condensation of (Et2N)(2)MeSi-SiMeCl(NEt2) (1d) with Li in THF yields the linear tetrasilane (Et2N)(2)MeSi-SiMe(NEt2)-SiMe(NEt2)-SiMe(Et2N)(2) (2a).The NMR investigations provided information of the general shift ranges of several Si units in (diethylamino)-methylchlorooligosilane systems as well as the number of stereoisomers of the prepared products.
• Nitsche, Silke; Trommer, Kristin; Palitzsch, Wolfram, Phosphorus, Sulfur and Silicon and the Related Elements, 2001, vol. 169, p. 177 - 184
  作者：Nitsche, Silke、Trommer, Kristin、Palitzsch, Wolfram、Weber, Edwin、Roewer, Gerhard

  DOI：——

  日期：——