4-hydroxynapthylazo-4-fluorobenzene | 36853-47-1

• 分子结构分类: 有机化合物 - 苯类化合物 - 萘
• 英文名称: 4-hydroxynapthylazo-4-fluorobenzene
• 英文别名: 1-Naphthol, 4-(4-fluorophenyl)azo-；4-[(4-fluorophenyl)diazenyl]naphthalen-1-ol
• CAS: 36853-47-1
• 化学式: C₁₆H₁₁FN₂O
• 分子量: 266.275
• InChiKey: CYOANEQWZHWBHD-UHFFFAOYSA-N

计算性质

• 辛醇/水分配系数(LogP)：
  4.7
• 重原子数：
  20
• 可旋转键数：
  2
• 环数：
  3.0
• sp3杂化的碳原子比例：
  0.0
• 拓扑面积：
  45
• 氢给体数：
  1
• 氢受体数：
  4

反应信息

• 作为反应物：
  描述：

  4-hydroxynapthylazo-4-fluorobenzene 、 4-正戊氧基苯甲酰氯 在 吡啶 作用下， 生成
  参考文献：
  名称：

  Mesomorphism Dependence on Molecular Flexibility in an Azoester Series

  摘要：

  A novel azoester homologous series with a flouro terminal end group was synthesized and evaluated for mesomorphic properties. The novel homologous series consists of 12 members. The first two-third members of the series are nonmesogenic. The butyloxy to decyloxy homologues are enantiotropic nematogenic and the rest of the mesogenic homologoues are enantiotropic smectogenic only. Transition temperatures and textures of the mesophases were observed through an optical polarizing microscope equipped with a heating stage. The textures of the nematic phase are threaded or Schlieren as judged by a miscibility method and those of the smectic phase are of the type A or C. A phase diagram is used to illustrate the mesomorphic behavior across the series. Analytical and spectral data confirm the molecular structures of the homologues. Thermal stabilities of smectic and nematic mesophases are 114.3 degrees C and 137.0 degrees C respectively. The mesogenic phase lengths for smectic and nematic are vary from 8 degrees C to 26 degrees C and 26 degrees C to 43 degrees C respectively.

  DOI：

  10.1080/15421406.2014.953740
• 作为产物：
  描述：

  萘酚 、 4-氟苯胺 在 盐酸 、 sodium nitrite 、 sodium hydroxide 作用下， 生成 4-hydroxynapthylazo-4-fluorobenzene
  参考文献：
  名称：

  Mesomorphism Dependence on Molecular Flexibility in an Azoester Series

  摘要：

  A novel azoester homologous series with a flouro terminal end group was synthesized and evaluated for mesomorphic properties. The novel homologous series consists of 12 members. The first two-third members of the series are nonmesogenic. The butyloxy to decyloxy homologues are enantiotropic nematogenic and the rest of the mesogenic homologoues are enantiotropic smectogenic only. Transition temperatures and textures of the mesophases were observed through an optical polarizing microscope equipped with a heating stage. The textures of the nematic phase are threaded or Schlieren as judged by a miscibility method and those of the smectic phase are of the type A or C. A phase diagram is used to illustrate the mesomorphic behavior across the series. Analytical and spectral data confirm the molecular structures of the homologues. Thermal stabilities of smectic and nematic mesophases are 114.3 degrees C and 137.0 degrees C respectively. The mesogenic phase lengths for smectic and nematic are vary from 8 degrees C to 26 degrees C and 26 degrees C to 43 degrees C respectively.

  DOI：

  10.1080/15421406.2014.953740

文献信息

• Liquid Crystalline Behavior of Binary Mixtures of Structurally Dissimilar Mesogens and Nonmesogens
  作者：Jayrang S. Dave、Purvang D. Patel、Himanshu S. Bhatt

  DOI：10.1080/15421406.2013.766920

  日期：2013.6.1

  We have studied eight binary systems comprising three enantiotropic nematogens, namely 4-(4-n-butyloxybenzoyloxy)phenylazo-4-fluorobenzene, 4-(4-n-butyloxybenzo yloxy)benzylidene-4-fluoro aniline, and 4-(4-n-heptyloxybenzoyloxy)phenylazo-4-fl uorobenzene; a monotropic nematogen, viz. 4-(4-n-dodecyloxybenzoyloxy)napthylazo-4-fluorobenzene; and three nonmesogens, viz. 4-(4-n-butyloxy benzoyloxy)benzalde hyde, 4-methoxybenzylidene-4-chloroaniline, and 4-methoxybenzylidene-4-toluidine. The central linkage, terminal group, and central ring system of the components have been varied systematically and the effect of these variations has been evaluated on the liquid crystalline properties of the binary mixtures. The mixed mesomorphic properties of these systems are discussed on the basis of their phase diagrams.