1,2-Dichlorotetraneopentyldisilane | 100636-64-4

• 分子结构分类: 有机化合物 - 有机金属化合物 - 有机类金属化合物
• 英文名称: 1,2-Dichlorotetraneopentyldisilane
• 英文别名: chloro-[chloro-bis(2,2-dimethylpropyl)silyl]-bis(2,2-dimethylpropyl)silane
• CAS: 100636-64-4
• 化学式: C₂₀H₄₄Cl₂Si₂
• 分子量: 411.646
• InChiKey: GFFPARJFNPNPLN-UHFFFAOYSA-N

物化性质

• 沸点：
  403.6±14.0 °C(Predicted)
• 密度：
  0.908±0.06 g/cm3(Predicted)

计算性质

• 辛醇/水分配系数(LogP)：
  8.62
• 重原子数：
  24.0
• 可旋转键数：
  5.0
• 环数：
  0.0
• sp3杂化的碳原子比例：
  1.0
• 拓扑面积：
  0.0
• 氢给体数：
  0.0
• 氢受体数：
  0.0

反应信息

• 作为反应物：
  描述：

  1,2-Dichlorotetraneopentyldisilane 在 lithium 作用下， 以 乙二醇二甲醚 为溶剂， 反应 7.0h， 以43%的产率得到Octaneopentylcyclotetrasilane
  参考文献：
  名称：

  OCTANEOPENTYLCYCLOTETRASILANE. SYNTHESIS AND UNUSUAL PROPERTIES

  摘要：

  我们合成了该化合物，并通过 X 射线晶体学确定了其分子结构。该化合物的特殊性质包括：环四硅烷的 CT 带能量最低，且在电子撞击破碎和热解过程中 Si4 框架易于分解。

  DOI：

  10.1246/cl.1985.1005
• 作为产物：
  描述：

  (2,2-二甲基丙基)锂 在 盐酸 、 三氯化铝 、 lithium 作用下， 以 四氢呋喃 、 乙醚 、 Petroleum ether 、 苯 为溶剂， 反应 14.25h， 生成 1,2-Dichlorotetraneopentyldisilane
  参考文献：
  名称：

  Dibenzo[b, e]-7,7,8,8-tetraneopentyl- and dibenzo[b, e]-7,7,8,8-tetraisopropyl-7,8-disilabicyclo[2.2.2]octa-2,5-dienes: interaction with tetracyanoethylene and transition metal chlorides

  摘要：

  Dibenzo[b,e]-7,7,8,8-tetraalkyl-7,8-disilabicyclo[2.2.2]octa-2, 5-dienes (1: R = (t)BuCH(2); 2: R = Pr-i) were prepared by the reaction of CIR(2)SiSiR(2)Cl with lithium anthracenide in 1,2-dimethoxyethane (DME) at room temperature. The structure of 1 was determined by X-ray crystallography, Crystal data for 1: monoclinic, C2/c, a = 12.941(2), b = 14.601(1), c = 35.109(6) Angstrom, beta = 94.957(7)degrees, V = 6609(2) Angstrom(3), Z = 8, R = 0.045, R(w) = 0.053 for 4037 reflections. Compounds 1 and 2 show the bachochromic shift of (1)L(a) and (1)L(b) bands in UV spectra and exhibit considerably low oxidation potentials due to effective sigma-pi conjugation. Compounds 1 and 2 form charge-transfer complexes with tetracyanoethylene (TCNE). In the case of 1, the charge-transfer complex (1: TCNE = 2: 1) could be isolated as crystals and the structure was determined by X-ray crystallography. Crystal data for the 1-TCNE complex: monoclinic, C2/c, a = 10.267(2), b = 36.077(4), c = 20.022(4) Angstrom, beta = 100.680(8)degrees, V = 7288(2) Angstrom(3), Z = 4, R = 0.045, R(w) = 0.077 for 4120 reflections. The action of transition metal chlorides on 2 resulted in [4 + 2] cycloreversion to form (ClPr2SiSiPr2Cl)-Pr-i-Pr-i and anthracene.

  DOI：

  10.1016/0022-328x(95)05907-7

文献信息

• Novel peralkylcyclotetrasilanes of the type (R1R2Si)2(R3R4Si)2
  作者：Hideyuki Matsumoto、Kazutoshi Takatsuna、Masahiko Minemura、Yoichiro Nagai、Midori Goto

  DOI：10.1039/c39850001366

  日期：——

  Novel peralkylcyclotetrasilanes of the type (R1R2Si)2(R1= R2= ButCH2, R3= R4= Pri; R1= R2= ButCH2, R3= But, R4= Me) were obtained by co-condensation of two 1,2-dichlorotetra-alkyldisilanes with Li; the structure of the tetraisopropyltetraneopentylcyclotetrasilane (1), determined by X-ray crystallography, is folded with a large dihedral angle.

  所述类型的新颖peralkylcyclotetrasilanes（R 1 - [R 2 Si）的2（R 1 = R 2 =卜吨CH 2，R 3 = R 4 = PR我; R 1 = R 2 =卜吨CH 2，R 3 =卜吨，通过将两个1,2-二氯四烷基二硅烷与Li共缩合得到R 4 = Me）；通过X射线晶体学测定的四异丙基四戊基戊基环四硅烷（1）的结构以大的二面角折叠。
• MATSUMOTO, HIDEYUKI;MINEMURA, MASAHIKO;TAKATSUNA, KAZUTOSHI;NAGAI, YOICHI+, CHEM. LETT., 1985, N 7, 1005-1006
  作者：MATSUMOTO, HIDEYUKI、MINEMURA, MASAHIKO、TAKATSUNA, KAZUTOSHI、NAGAI, YOICHI+

  DOI：——

  日期：——