The synthesis, structure, vibrational analysis and a comparative vibrational study in function of the structure and the metal-ligand bond strength are discussed for a series of Mn(II)-urea-halogenide complexes. Complex [MnCl2U] has been prepared and studied fur the first time. The single-crystal X-ray structure of the 1:6-bromide complex reveals the presence of octahedral [MnU6](2+) ions and bromide counterions. (C) 2000 Elsevier Science Ltd. All rights reserved.
Pavlenko, A. I.; Redchenko, G. A., Russian Journal of Inorganic Chemistry, 1975, vol. 20, p. 1381 - 1383
作者:Pavlenko, A. I.、Redchenko, G. A.
DOI:——
日期:——
Coordination of manganese(II): High spin complexes with urea