[1,1'-联萘]-8,8'-二甲酸 | 29878-91-9

• 分子结构分类: 有机化合物 - 苯类化合物 - 萘
• 中文名称: [1,1'-联萘]-8,8'-二甲酸
• 中文别名: 1,1'-联萘-8,8'-二甲酸
• 英文名称: [1,1']binaphthyl-8,8'-dicarboxylic acid
• 英文别名: [1,1'-Binaphthalene]-8,8'-dicarboxylic acid；8-(8-carboxynaphthalen-1-yl)naphthalene-1-carboxylic acid
• CAS: 29878-91-9
• 化学式: C₂₂H₁₄O₄
• mdl: MFCD00027401
• 分子量: 342.351
• InChiKey: XGDAODQNSVFBGM-UHFFFAOYSA-N

物化性质

• 熔点：
  306-307℃
• 密度：
  1.380±0.06 g/cm3 (20 ºC 760 Torr)
• 沸点：
  615.7±40.0 °C(Predicted)

计算性质

• 辛醇/水分配系数(LogP)：
  5.1
• 重原子数：
  26
• 可旋转键数：
  3
• 环数：
  4.0
• sp3杂化的碳原子比例：
  0.0
• 拓扑面积：
  74.6
• 氢给体数：
  2
• 氢受体数：
  4

SDS

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Section 1. IDENTIFICATION OF THE SUBSTANCE/MIXTURE
Product identifiers
Product name : 1,1'-Binaphthyl-8,8'-dicarboxylic acid
CAS-No. : 29878-91-9

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Section 2. HAZARDS IDENTIFICATION
Classification of the substance or mixture
Classification according to Regulation (EC) No 1272/2008 [EU-GHS/CLP]
Acute toxicity, Oral (Category 4)
Chronic aquatic toxicity (Category 4)
Classification according to EU Directives 67/548/EEC or 1999/45/EC
Harmful if swallowed.
Label elements
Labelling according Regulation (EC) No 1272/2008 [CLP]
Pictogram
Signal word Warning
Hazard statement(s)
Harmful if swallowed.
May cause long lasting harmful effects to aquatic life.
Precautionary statement(s) none
Supplemental Hazard none
Statements
According to European Directive 67/548/EEC as amended.
Hazard symbol(s)
R-phrase(s)
R22 Harmful if swallowed.
S-phrase(s) none
Other hazards - none

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Section 3. COMPOSITION/INFORMATION ON INGREDIENTS
Substances
Formula : C22H14O4
Molecular Weight : 342,34 g/mol
Component Concentration
1,1'-Binaphthyl-8,8'-dicarboxylic acid
CAS-No. 29878-91-9 -
EC-No. 249-922-7

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Section 4. FIRST AID MEASURES
Description of first aid measures
General advice
Consult a physician. Show this safety data sheet to the doctor in attendance.
If inhaled
If breathed in, move person into fresh air. If not breathing, give artificial respiration. Consult a physician.
In case of skin contact
Wash off with soap and plenty of water. Consult a physician.
In case of eye contact
Flush eyes with water as a precaution.
If swallowed
Never give anything by mouth to an unconscious person. Rinse mouth with water. Consult a physician.
Most important symptoms and effects, both acute and delayed
To the best of our knowledge, the chemical, physical, and toxicological properties have not been
thoroughly investigated.
Indication of any immediate medical attention and special treatment needed
no data available

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Section 5. FIREFIGHTING MEASURES
Extinguishing media
Suitable extinguishing media
Use water spray, alcohol-resistant foam, dry chemical or carbon dioxide.
Special hazards arising from the substance or mixture
Carbon oxides
Advice for firefighters
Wear self contained breathing apparatus for fire fighting if necessary.
Further information
no data available

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Section 6. ACCIDENTAL RELEASE MEASURES
Personal precautions, protective equipment and emergency procedures
Use personal protective equipment. Avoid dust formation. Avoid breathing vapors, mist or gas. Ensure
adequate ventilation. Avoid breathing dust.
Environmental precautions
Prevent further leakage or spillage if safe to do so. Do not let product enter drains. Discharge into the
environment must be avoided.
Methods and materials for containment and cleaning up
Pick up and arrange disposal without creating dust. Sweep up and shovel. Keep in suitable, closed
containers for disposal.
Reference to other sections
For disposal see section 13.

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Section 7. HANDLING AND STORAGE
Precautions for safe handling
Avoid contact with skin and eyes. Avoid formation of dust and aerosols.
Provide appropriate exhaust ventilation at places where dust is formed.Normal measures for preventive fire
protection.
Conditions for safe storage, including any incompatibilities
Store in cool place. Keep container tightly closed in a dry and well-ventilated place.
Specific end uses
no data available

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Section 8. EXPOSURE CONTROLS/PERSONAL PROTECTION
Control parameters
Components with workplace control parameters
Exposure controls
Appropriate engineering controls
Handle in accordance with good industrial hygiene and safety practice. Wash hands before breaks and
at the end of workday.
Personal protective equipment
Eye/face protection
Safety glasses with side-shields conforming to EN166 Use equipment for eye protection tested
and approved under appropriate government standards such as NIOSH (US) or EN 166(EU).
Skin protection
Handle with gloves. Gloves must be inspected prior to use. Use proper glove removal technique
(without touching glove's outer surface) to avoid skin contact with this product. Dispose of
contaminated gloves after use in accordance with applicable laws and good laboratory practices.
Wash and dry hands.
The selected protective gloves have to satisfy the specifications of EU Directive 89/686/EEC and
the standard EN 374 derived from it.
Body Protection
Complete suit protecting against chemicals, The type of protective equipment must be selected
according to the concentration and amount of the dangerous substance at the specific workplace.
Respiratory protection
For nuisance exposures use type P95 (US) or type P1 (EU EN 143) particle respirator.For higher
level protection use type OV/AG/P99 (US) or type ABEK-P2 (EU EN 143) respirator cartridges.
Use respirators and components tested and approved under appropriate government standards
such as NIOSH (US) or CEN (EU).

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Section 9. PHYSICAL AND CHEMICAL PROPERTIES
Information on basic physical and chemical properties
a) Appearance Form: solid
b) Odour no data available
c) Odour Threshold no data available
d) pH no data available
e) Melting point/freezing no data available
point
f) Initial boiling point and no data available
boiling range
g) Flash point no data available
h) Evaporation rate no data available
i) Flammability (solid, gas) no data available
j) Upper/lower no data available
flammability or
explosive limits
k) Vapour pressure no data available
l) Vapour density no data available
m) Relative density no data available
n) Water solubility no data available
o) Partition coefficient: n- log Pow: 4,877
octanol/water
p) Autoignition no data available
temperature
q) Decomposition no data available
temperature
r) Viscosity no data available
s) Explosive properties no data available
t) Oxidizing properties no data available
Other safety information
no data available

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Section 10. STABILITY AND REACTIVITY
Reactivity
no data available
Chemical stability
no data available
Possibility of hazardous reactions
no data available
Conditions to avoid
no data available
Incompatible materials
Strong oxidizing agents
Hazardous decomposition products
Other decomposition products - no data available

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Section 11. TOXICOLOGICAL INFORMATION
Information on toxicological effects
Acute toxicity
no data available
Skin corrosion/irritation
no data available
Serious eye damage/eye irritation
no data available
Respiratory or skin sensitization
no data available
Germ cell mutagenicity
no data available
Carcinogenicity
IARC: No component of this product present at levels greater than or equal to 0.1% is identified as
probable, possible or confirmed human carcinogen by IARC.
Reproductive toxicity
no data available
Specific target organ toxicity - single exposure
no data available
Specific target organ toxicity - repeated exposure
no data available
Aspiration hazard
no data available
Potential health effects
Inhalation
May be harmful if inhaled. May cause respiratory tract irritation.
Ingestion Harmful if swallowed.
Skin May be harmful if absorbed through skin. May cause skin irritation.
Eyes May cause eye irritation.
Signs and Symptoms of Exposure
To the best of our knowledge, the chemical, physical, and toxicological properties have not been
thoroughly investigated.
Additional Information
RTECS: Not available

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Section 12. ECOLOGICAL INFORMATION
Toxicity
no data available
Persistence and degradability
no data available
Bioaccumulative potential
no data available
Mobility in soil
no data available
Results of PBT and vPvB assessment
no data available
Other adverse effects
no data available

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Section 13. DISPOSAL CONSIDERATIONS
Waste treatment methods
Product
Offer surplus and non-recyclable solutions to a licensed disposal company. Contact a licensed
professional waste disposal service to dispose of this material. Dissolve or mix the material with a
combustible solvent and burn in a chemical incinerator equipped with an afterburner and scrubber.
Contaminated packaging
Dispose of as unused product.

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Section 14. TRANSPORT INFORMATION
UN number
ADR/RID: - IMDG: - IATA: -
UN proper shipping name
ADR/RID: Not dangerous goods
IMDG: Not dangerous goods
IATA: Not dangerous goods
Transport hazard class(es)
ADR/RID: - IMDG: - IATA: -
Packaging group
ADR/RID: - IMDG: - IATA: -
Environmental hazards
ADR/RID: no IMDG Marine pollutant: no IATA: no
Special precautions for user
no data available

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Section 15. REGULATORY INFORMATION
This safety datasheet complies with the requirements of Regulation (EC) No. 1907/2006.
Safety, health and environmental regulations/legislation specific for the substance or mixture
no data available
Chemical Safety Assessment

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SECTION 16 - ADDITIONAL INFORMATION
N/A

反应信息

• 作为反应物：
  描述：

  [1,1'-联萘]-8,8'-二甲酸 在 硫酸 、 铜 作用下， 以 喹啉 为溶剂， 生成 7H-dibenz[a,kl]anthracen-7-one
  参考文献：
  名称：

  690.一些多环酮的亲电子反应性。第三部分 Dibenz [ a，kl ]蒽酮

  摘要：

  DOI：

  10.1039/jr9620003516
• 作为产物：
  描述：

  alkaline earth salt of/the/ methylsulfuric acid 在 copper(I) oxide 作用下， 生成 [1,1'-联萘]-8,8'-二甲酸
  参考文献：
  名称：

  DE445390

  摘要：

  公开号：

文献信息

• 一种1，1ˊ-联萘-8，8ˊ-二甲酸的绿色生产方法
  申请人：鞍山市五色石新材料科技有限公司

  公开号：CN113402379B

  公开（公告）日：2023-04-04

  本发明适用有机染料技术领域，提供一种1，1ˊ‑联萘‑8，8ˊ‑二甲酸的绿色生产方法，本发明设计配制了一个以铜氨溶液为催化剂的还原缓冲反应体系；然后合成1‑氨基‑8‑萘甲酸重氮盐，该重氮盐缓慢加入还原缓冲反应体时，还原缓冲反应体系中的催化剂二氨合铜（Ⅰ）被氧化成四氨合铜（Ⅱ）；随即，生成的四氨合铜（Ⅱ）被反应体系中的羟胺盐还原成二氨合铜（Ⅰ）完成了催化剂的再生，再生后的催化剂立即与随后滴入反应体系的1‑氨基‑8‑萘甲酸重氮盐继续反应；如此反复，直到反应结束；本反应因为催化剂的消耗和再生过程都产生氮气，并及时的溢出反应体系，所以反应很迅速而且很彻底，收率也比文献记录的高约10%。
• 一种固体超强酸催化合成蒽缔蒽酮的生产方法
  申请人：鞍山市五色石新材料科技有限公司

  公开号：CN113292407A

  公开（公告）日：2021-08-24

  本发明适用有机染料技术领域，提供一种固体超强酸催化合成蒽缔蒽酮的生产方法，包括以下步骤：配料：将1，1ˊ‑联萘‑8，8ˊ‑二甲酸加入适量的溶剂中，然后加入固体超强酸类催化剂；主反应：升温至回流，脱水；直到反应完全，降温；产品提纯：主反应结束后，过滤，祛除滤饼中的溶剂，然后将滤饼投入氢氧化钠水溶液中，升温，搅拌溶解未反应完全的1，1ˊ‑联萘‑8，8ˊ‑二甲酸和其中的杂质以及反应生成的杂质；再次过滤,干燥，得到产品；本发明采用固体超强酸为催化剂，在有机溶剂中对1，1ˊ‑联萘‑8，8ˊ‑二甲酸进行催化脱水缩合，得到收率和纯度较高蒽缔蒽酮；解决了传统工艺废硫酸的污染问题。
• Method For Producing Porous Metal-Organic Framework Materials
  申请人：Schubert Markus

  公开号：US20080214806A1

  公开（公告）日：2008-09-04

  The present invention relates to processes for preparing a porous metal-organic framework comprising at least two organic compounds coordinated to at least one metal ion, the porous metal-organic frameworks prepared by the process and their use, in particular for gas storage and gas separation.

  本发明涉及制备多孔金属有机框架的方法，所述多孔金属有机框架包括至少两种有机化合物配位至至少一个金属离子，所述方法制备的多孔金属有机框架及其用途，特别是用于气体储存和气体分离。
• METAL-ORGANIC FRAMEWORKS
  申请人：The University of Nottingham

  公开号：US20150175518A1

  公开（公告）日：2015-06-25

  The present invention relates to metal-organic frameworks and, in particular, a continuous flow process for synthesising a metal-organic framework comprising the steps of: providing a ligand and a metal salt which are suitable for forming a metal-organic framework, mixing the ligand and metal salt with a solvent to form a mixture, and providing the mixture at a temperature sufficient to cause the ligand and the metal salt to react to form a metal-organic framework. The invention also relates to a method for the treatment of a metal-organic framework to extract unreacted ligand from the metal organic framework, a method for synthesising a metal-organic framework using recycled unreacted ligand, and uses for metal-organic frameworks.

  本发明涉及金属有机框架，特别是一种连续流程合成金属有机框架的方法，包括以下步骤：提供适合形成金属有机框架的配体和金属盐，将配体和金属盐与溶剂混合形成混合物，并将混合物提供到足够温度使配体和金属盐反应形成金属有机框架。本发明还涉及一种处理金属有机框架以从金属有机框架中提取未反应的配体的方法，一种使用回收的未反应配体合成金属有机框架的方法以及金属有机框架的用途。
• Process for preparing an organometallic framework material
  申请人：Muller Ulrich

  公开号：US20050154222A1

  公开（公告）日：2005-07-14

  A process for preparing an organometallic framework material comprising reacting at least one metal salt with at least one at least bidentate compound capable of coordination to the metal ion of said metal salt, in the presence of an aqueous solvent system and at least one base wherein at least one bidentate compound comprises at least carboxy group and at least one further group which is not a carboxy group and which is capable of forming a hydrogen bridge linkage.

  一种制备金属有机框架材料的方法，包括在水溶剂体系和至少一种碱的存在下，将至少一种金属盐与至少一种至少具有二齿配位能力的化合物反应，其中至少一种二齿配位化合物包括至少一个羧基和至少另外一种不是羧基但能够形成氢桥键的基团。