3-tert-butyl-1,10-phenanthroline | 1218756-05-8

• 分子结构分类: 有机化合物 - 有机杂环化合物 - 菲咯啉
• 英文名称: 3-tert-butyl-1,10-phenanthroline
• CAS: 1218756-05-8
• 化学式: C₁₆H₁₆N₂
• 分子量: 236.316
• InChiKey: GGZGRTQBEVHVEP-UHFFFAOYSA-N

计算性质

• 辛醇/水分配系数(LogP)：
  3.5
• 重原子数：
  18
• 可旋转键数：
  1
• 环数：
  3.0
• sp3杂化的碳原子比例：
  0.25
• 拓扑面积：
  25.8
• 氢给体数：
  0
• 氢受体数：
  2

反应信息

• 作为产物：
  描述：

  8-氨基喹啉 、 3,3-二甲基-2-亚甲基丁醛 在 硫酸 、 sodium iodide 作用下， 以 水 为溶剂， 生成 3-tert-butyl-1,10-phenanthroline
  参考文献：
  名称：

  New Nonsymmetric Phenanthrolines as Very Effective Ligands in the Palladium-Catalyzed Carbonylation of Nitrobenzene

  摘要：

  Inspired by the results of a previous mechanistic Study, a series of mostly new nonsymmetric phenanthrolines were synthesized and tested as ligands in the palladium-catalyzed reductive carbonylation reaction of nitrobenzene to methyl phenylcarbamate. Very good results were obtained when the asymmetry was of an electronic nature (a donating substituent in the para position of one of the two pyridinic rings and an electron-withdrawing or no substituent on the para position of the other pyridinic ring), but steric hindrance in the ortho or meta position retarded the reaction. The TOF for the modified system is the highest ever reported for any carbonylation reaction of nitroarenes.

  DOI：

  10.1021/om100023x

文献信息

• Nitrogen-containing compound, electronic element and electronic device
  申请人：Shaanxi Lighte Optoelectronics Material Co., Ltd.

  公开号：US11203584B2

  公开（公告）日：2021-12-21

  The present disclosure provides a nitrogen-containing compound, an electronic element and an electronic device, which belongs to the technical field of organic materials. The nitrogen-containing compound has a structure of Chemical Formula 1, wherein R1 and R2 are each independently selected from hydrogen or a group represented by Chemical Formula 1-1, and one and only one of R1 and R2 has the group of Chemical Formula 1-1; when R1 or R2 is selected from hydrogen, said R1 and R2 may be replaced by R4. The nitrogen-containing compound can improve the performance of electronic elements.

  本公开提供了一种含氮化合物、电子元件和电子器件，属于有机材料技术领域。 该含氮化合物具有化学式1的结构，其中R1和R2各自独立地选自氢或化学式1-1所代表的基团，且R1和R2中仅有一个具有化学式1-1的基团；当R1或R2选自氢时，所述R1和R2可被R4取代。 含氮化合物可以改善电子元件的性能。
• Nitrogen-containing compound, electronic element, and electronic device
  申请人：SHAANXI LIGHTE OPTOELECTRONICS MATERIAL CO., LTD.

  公开号：US11524970B2

  公开（公告）日：2022-12-13

  Provided are a nitrogen-containing compound, an electronic element, and an electronic device, and relates to the technical field of organic materials. The nitrogen-containing compound is shown as formula I, and can reduce the working voltage of an electronic element, improve the efficiency of an OLED, and prolong the service life of an OLED.

  本发明提供了一种含氮化合物、一种电子元件和一种电子器件，涉及有机材料技术领域。该含氮化合物如式 I 所示，可降低电子元件的工作电压，提高 OLED 的效率，延长 OLED 的使用寿命。
• MULTICYCLIC COMPOUND AND ORGANIC ELECTRONIC DEVICE USING THE SAME
  申请人：LG CHEM, LTD.

  公开号：US20160126473A1

  公开（公告）日：2016-05-05

  The present specification describes a novel polycyclic compound and an organic electroluminescent device using the same.
• NITROGEN-CONTAINING COMPOUND, ELECTRONIC COMPONENT AND ELECTRONIC DEVICE
  申请人：Shaanxi Lighte Optoelectronics Material Co., Ltd.

  公开号：US20210130313A1

  公开（公告）日：2021-05-06

  The present disclosure provides a nitrogen-containing compound as shown in Formula I, an electronic component, and an electronic device, which belongs to the technical field of the organic materials. The nitrogen-containing compound can improve the performance of electronic components.
• SUBSTITUTED 2,2'-BIPYRIMIDINYL COMPOUNDS, ANALOGUES THEREOF, AND METHODS USING SAME
  申请人：ARBUTUS BIOPHARMA CORPORATION

  公开号：US20210251991A1

  公开（公告）日：2021-08-19

  The present disclosure includes substituted 2,2′-bipyrimidinyl compounds, analogues thereof, and compositions comprising the same, which can be used to treat and/or prevent hepatitis B virus (HBV) and/or hepatitis B virus (HBV)-hepatitis D virus (HDV) infection in a patient.