bis(perfluorocyclohexanecarbonyl)peroxide | 203255-90-7

• 分子结构分类: 有机化合物 - 有机卤素化合物 - 卤代烷
• 英文名称: bis(perfluorocyclohexanecarbonyl)peroxide
• 英文别名: bis-perfluorocyclohexanoylperoxide；bis(perfluorocyclohexane carbonyl) peroxide；Peroxide, bis[(undecafluorocyclohexyl)carbonyl]；(1,2,2,3,3,4,4,5,5,6,6-undecafluorocyclohexanecarbonyl) 1,2,2,3,3,4,4,5,5,6,6-undecafluorocyclohexane-1-carboperoxoate
• CAS: 203255-90-7
• 化学式: C₁₄F₂₂O₄
• 分子量: 650.116
• InChiKey: XWIGYEOZHFHUEH-UHFFFAOYSA-N

物化性质

• 沸点：
  281.3±50.0 °C(Predicted)
• 密度：
  1.90±0.1 g/cm3(Predicted)

计算性质

• 辛醇/水分配系数(LogP)：
  6.9
• 重原子数：
  40
• 可旋转键数：
  5
• 环数：
  2.0
• sp3杂化的碳原子比例：
  0.86
• 拓扑面积：
  52.6
• 氢给体数：
  0
• 氢受体数：
  26

反应信息

• 作为反应物：
  描述：

  bis(perfluorocyclohexanecarbonyl)peroxide 、 苯 以 various solvent(s) 为溶剂， 反应 10.0h， 以1.58 g的产率得到1,1,2,2,3,3,4,4,5,5,6-Undecafluoro-6-phenylcyclohexane
  参考文献：
  名称：

  双（全氟环己烷羰基）过氧化物的新型全氟环己基化反应

  摘要：

  通过相应的酰氟和过氧化氢反应制备了一种新的双（全氟环己烷羰基）过氧化物。该过氧化物适用于将全氟环己基直接引入丙烯酸低聚物、苯、聚苯乙烯等各种有机分子中；尤其令人感兴趣的是，不仅赤道异构体而且轴向构象异构体都在由此获得的苯基全氟环己烷中分离出来。

  DOI：

  10.1246/cl.1998.153
• 作为产物：
  描述：

  十一氟代环己烷酰氟 在 hydroxide 、 双氧水 作用下， 以 various solvent(s) 为溶剂， 生成 bis(perfluorocyclohexanecarbonyl)peroxide
  参考文献：
  名称：

  双（全氟环己烷羰基）过氧化物的新型全氟环己基化反应

  摘要：

  通过相应的酰氟和过氧化氢反应制备了一种新的双（全氟环己烷羰基）过氧化物。该过氧化物适用于将全氟环己基直接引入丙烯酸低聚物、苯、聚苯乙烯等各种有机分子中；尤其令人感兴趣的是，不仅赤道异构体而且轴向构象异构体都在由此获得的苯基全氟环己烷中分离出来。

  DOI：

  10.1246/cl.1998.153

文献信息

• Novel perfluoroalkyl vinyl ether compound, process for preparing copolymer by using the compound, and optical plastic materials comprising copolymer prepared by the process
  申请人：Hwang Taek Jin

  公开号：US20050148800A1

  公开（公告）日：2005-07-07

  Disclosed herein are a novel perfluoroalkyl vinyl ether compound, a process for preparing a copolymer by using the perfluoroalkyl vinyl ether compound, and an optical plastic material comprising a copolymer prepared by the process. More specifically, the perfluoroalkyl vinyl ether has a particular molecular structure; the process is performed by copolymerizing the perfluoroalkyl vinyl ether compound with a common fluorinated olefin in the presence of a perfluorinated radical initiator; and, the optical plastic material comprises a copolymer prepared by the process and optionally a dopant. The copolymerization of the perfluoroalkyl vinyl ether with a common fluorinated olefin can provide a copolymer having a high molecular weight. In addition, appropriate control of the composition of the monomers can provide a completely amorphous copolymer. Since the polymer prepared by the process exhibits excellent thermal properties and is substantially transparent in the UV and near IR regions, it can be usefully applied to various optical plastic materials. Furthermore, a preform for a GI type plastic optical fiber fabricated by using the copolymer and the dopant has a high T g , thus being stable, and a parabolic refractive index profile due to the presence of the dopant.

  本文披露了一种新型的全氟烷基乙烯醚化合物，一种利用该全氟烷基乙烯醚化合物制备共聚物的方法，以及一种包括通过该方法制备的共聚物的光学塑料材料。具体而言，该全氟烷基乙烯醚具有特定的分子结构；该方法是在全氟基自由基引发剂的存在下，通过共聚合该全氟烷基乙烯醚化合物和常见的氟化烯烃来进行的；而且，该光学塑料材料包括通过该方法制备的共聚物和可选的掺杂剂。 全氟烷基乙烯醚与常见的氟化烯烃的共聚可以提供高分子量的共聚物。此外，适当控制单体的组成可以提供完全无定形的共聚物。由于该方法制备的聚合物具有优异的热性能，并且在紫外线和近红外区域具有较高的透明度，因此可以应用于各种光学塑料材料中。此外，使用该共聚物和掺杂剂制备的GI型塑料光纤预制件具有高Tg，因此稳定，并且由于存在掺杂剂而具有抛物线折射率剖面。
• 全氟酰基过氧化物的制备
  申请人：中国科学院上海有机化学研究所

  公开号：CN108794367A

  公开（公告）日：2018-11-13

  本发明涉及全氟酰基过氧化物的制备方法。具体地，所述方法包括步骤：在惰性溶剂中，用全氟酰卤，弱碱和过氧化氢的加合物进行反应，得到全氟酰基过氧化物。本发明的全氟酰基过氧化物在自由基聚合反应中作为引发剂广泛使用。该发明方法安全性能好，操作简单，过氧化物纯度高，收率高。
• METHOD OF OBTAINING PERFLUOROSULPHONATE POLYMERS CONTAINING SULPHONYL FUNCTIONAL GROUPS
  申请人：DAVID FUEL CELL COMPONENTS, S.L.

  公开号：EP1538168A1

  公开（公告）日：2005-06-08

  The present invention refers to a method of obtaining perfluorocarbonate polymers containing functional fluorosulphonyl groups and that have structural formula (I) that consists in carrying out copolymerization between tetrafluoroethylene and a perfluorovinylic ether in a fluorated organic solvent medium, in the presence of a radical type starter with additional input of tetrafluoroethylene during the copolymerization process, characterized because before starting the copolymerization reaction a, previously synthesized, dispersion is introduced of a copolymer of tetrafluoroethylene and perfluorovinylic ether, in an organic solvent. The present invention also refers to the perfluorocarbonate polymer obtainable by the method of the invention and the use of this polymer to prepare ion-exchange membranes.

  本发明涉及一种获得含有功能性氟磺酰基且结构式为(I)的全氟碳酸酯聚合物的方 法，该方法包括在含氟有机溶剂介质中进行四氟乙烯和全氟乙烯基醚的共聚、在共聚过程中，在有自由基起始剂存在的情况下，额外加入四氟乙烯，其特征是在开始共聚反应之前，在有机溶剂中加入事先合成的四氟乙烯和全氟乙烯基醚的共聚物分散体。本发明还涉及可通过本发明方法获得的全氟碳酸酯聚合物，以及使用这种聚合物制备离子交换膜。
• α-Branched-perfluorodiacyl peroxides: preparation and characterization
  作者：Marco Galimberti、Emma Barchiesi、Walter Navarrini

  DOI：10.1016/j.jfluchem.2005.01.003

  日期：2005.4

  New perfluorodiacyl peroxides substituted at the a position have been synthesized and characterized. This class of peroxides shows good hydrolytic stability. (c) 2005 Elsevier B.V. All rights reserved.
• POLYMER, GAS SEPARATION MEMBRANE, AND PROCESS FOR PRODUCTION OF POLYMER
  申请人：Aoki Toshiki

  公开号：US20120214949A1

  公开（公告）日：2012-08-23

  A polymer having a repeating unit represented by formula (1). [R 1 represents a hydrogen atom, a halogeno group, a substituted or unsubstituted alkyl group, a substituted or unsubstituted aromatic hydrocarbon group, a substituted or unsubstituted aromatic heterocyclic group, a trialkylsilyl group, or a trialkylgermyl group, each R 2 is independently represented by the following formula (2), m is an integer of from 1 to 5, and when a plurality of R 2 s are present, the R 2 s may be the same as or different from each other.] [Each X is independently a monovalent group, and the plurality of Xs may be the same as or different from each other, at least one X is a monovalent group containing a halogen atom, and p is an integer of from 0 to 10.]