| 628688-35-7

• 分子结构分类: 有机化合物 - 苯类化合物 - 萘
• CAS: 628688-35-7
• 化学式: C₆₈H₇₀N₄O₂Zn
• 分子量: 1040.72
• InChiKey: OWEJDTXZNCPGNO-UNPBYVTBSA-N

计算性质

• 辛醇/水分配系数(LogP)：
  None
• 重原子数：
  None
• 可旋转键数：
  None
• 环数：
  None
• sp3杂化的碳原子比例：
  None
• 拓扑面积：
  None
• 氢给体数：
  None
• 氢受体数：
  None

反应信息

• 作为产物：
  描述：

  在 zinc diacetate 作用下， 以 苯 为溶剂， 生成
  参考文献：
  名称：

  Influence of electronic and geometric factors on the redox properties of the blocked zinc porphyrinates in the reaction with organic peroxides

  摘要：

  By an example of the reaction of intermolecular interaction of organic peroxides with blocked zinc porphyrinates we studied the effect of the macrocycle electronic and conformational features on the redox properties. Kinetics and mechanism of the reaction were studied. Using the calculated geometric characteristics of the isolated molecules of reactants and reaction intermediates, we evaluated a degree of their deformation. An increase in the steric strain in the macrocycle is shown to increase the rate of redox process.

  DOI：

  10.1134/s1070363210120182