(6-Oxy-naphthyl-(2))-mercaptan | 6088-50-2

• 分子结构分类: 有机化合物 - 苯类化合物 - 萘
• 英文名称: (6-Oxy-naphthyl-(2))-mercaptan
• 英文别名: 6-Oxy-2-mercapto-naphthalin；6-Mercapto-[2]naphthol；6-hydroxynaphthalene-2-thiol；6-sulfanylnaphthalen-2-ol
• CAS: 6088-50-2
• 化学式: C₁₀H₈OS
• 分子量: 176.239
• InChiKey: KLHFHLRQBFMVHG-UHFFFAOYSA-N

物化性质

• 沸点：
  362.4±15.0 °C(Predicted)
• 密度：
  1.309±0.06 g/cm3(Predicted)

计算性质

• 辛醇/水分配系数(LogP)：
  2.9
• 重原子数：
  12
• 可旋转键数：
  0
• 环数：
  2.0
• sp3杂化的碳原子比例：
  0.0
• 拓扑面积：
  21.2
• 氢给体数：
  2
• 氢受体数：
  2

反应信息

• 作为反应物：
  描述：

  (6-Oxy-naphthyl-(2))-mercaptan 在 碘 作用下， 以 甲醇 、 水 为溶剂， 生成 双(6-羟基-2-萘)二硫
  参考文献：
  名称：

  Effects of oxygen–sulfur substitution on glycosaminoglycan-priming naphthoxylosides

  摘要：

  Three series of sulfur-containing analogs to the selectively antiproliferative 2-(6-hydroxynaphthyl) beta-D-xylopyranoside were synthesized and their biological properties investigated. A short, general route to hydroxynaphthyl disulfides from dihydroxy-naphthalenes was developed to utilize the disulfide bond as a sulfur-selective protecting group to enable the orthogonal protection of hydroxyls and thiols. The results indicate that hydrophobic, uncharged oxygen-sulfur substituted naphthoxylosides are taken up by calls and initiate priming of GAG chains to a greater extent compared to the oxygen analogs. No correlation between priming ability and antiproliferative activity was observed. (c) 2007 Elsevier Ltd. All rights reserved.

  DOI：

  10.1016/j.bmc.2007.05.008
• 作为产物：
  描述：

  6-[(乙氧羰基)氧基]-2-巯基萘 在 乙醇 作用下， 生成 (6-Oxy-naphthyl-(2))-mercaptan
  参考文献：
  名称：

  Zincke; Dereser, Chemische Berichte, 1918, vol. 51, p. 359

  摘要：

  DOI：

文献信息

• Naphthalene derivatives
  申请人：Teijin Limited

  公开号：US05149859A1

  公开（公告）日：1992-09-22

  A naphthalene derivative having the formula (I): ##STR1## wherein R.sup.1 represents a hydrogen atom, a C.sub.1 -C.sub.5 alkyl group or a non-toxic salt moiety; R.sup.2 and R.sup.3 independently represent a hydrogen atom or --OR.sup.4 where R.sup.4 represents a hydrogen atom or a C.sub.1 -C.sub.3 alkyl group; A represents a group: ##STR2## [where X.sup.1 and X.sup.2 represents an oxygen atom or N--OR.sup.5 (where R.sup.5 represents a hydrogen atom or a C.sub.1 -C.sub.3 alkyl group)], a group: ##STR3## [where Y.sup.1 and Y.sup.2 independently an oxygen atom or a group N--OR.sup.6 (where R.sup.6 represents a hydrogen atom or a C.sub.1 -C.sub.3 alkyl group)], or a group: ##STR4## (where n is 0 or 1); and B represents --(CH.sub.2).sub.m -- wherein m is an integer of 1, to 8, --(CH.sub.2).sub.m.sbsb.1 --O--(CH.sub.2).sub.m.sbsb.2 -- wherein m.sub.1 and m.sub.2 are independently 1 or 2, or ##STR5## wherein m.sub.3 is 0 or 1.

  一种具有以下式（I）的萘衍生物：其中R.sup.1代表氢原子、C.sub.1 -C.sub.5烷基或无毒盐基；R.sup.2和R.sup.3独立地代表氢原子或--OR.sup.4，其中R.sup.4代表氢原子或C.sub.1 -C.sub.3烷基；A代表以下基团之一：[式中X.sup.1和X.sup.2代表氧原子或N--OR.sup.5（其中R.sup.5代表氢原子或C.sub.1 -C.sub.3烷基）]，[式中Y.sup.1和Y.sup.2独立地代表氧原子或基团N--OR.sup.6（其中R.sup.6代表氢原子或C.sub.1 -C.sub.3烷基）]，或[式中n为0或1]；B代表--(CH.sub.2).sub.m--，其中m是1到8的整数，--(CH.sub.2).sub.m.sbsb.1--O--(CH.sub.2).sub.m.sbsb.2--，其中m.sub.1和m.sub.2独立地为1或2，或[式中m.sub.3为0或1]。
• SILICONE RUBBER
  申请人：EMPIRE TECHNOLOGY DEVELOPMENT LLC

  公开号：US20150203635A1

  公开（公告）日：2015-07-23

  Copolymers, as well as compounds, compositions, articles of manufacture, and methods of making thereof, are disclosed. The copolymers may generally exhibit flexibility properties and may generally have a high refractive index. The copolymers may generally be made by providing a dihydrodisiloxane and an aliphatic vinyl alcohol and combining the dihydrodisiloxane and the aliphatic vinyl alcohol under conditions that allow for hydrogenation of the aliphatic vinyl alcohol and result in coupling of the aliphatic vinyl alcohol to the dihydrodisiloxane to produce a hydroxyl substituted siloxane.

  本文介绍了共聚物、化合物、组合物、制造品以及制造方法。这些共聚物通常具有柔性特性和高折射率。通常可以通过提供二氢二硅氧烷和脂肪族乙烯醇，并在允许脂肪族乙烯醇氢化的条件下将二氢二硅氧烷和脂肪族乙烯醇结合起来，从而使脂肪族乙烯醇与二氢二硅氧烷偶联，产生羟基取代的硅氧烷来制备这些共聚物。
• Liquid-crystal polyester resin
  申请人：Ueno Ryuzo

  公开号：US20050054811A1

  公开（公告）日：2005-03-10

  The present invention provides a liquid-crystalline polyester resin which comprises monomer units derived from 2-hydroxy-3-naphthoic acid and/or 2-hydroxynaphthalene-3,6-dicarboxylic acid in an amount of 1-5000 mmol % based on the total monomer components of the resin and an alkaline metal compound in an amount of 10-3000 ppm as alkaline metal based on the total monomer components of the resin. The liquid-crystalline polyester resin of the present invention has good colorability, improved heat resistance and good mechanical properties.

  本发明提供了一种液晶聚酯树脂，其包含从2-羟基-3-萘甲酸和/或2-羟基萘并[3,6-二羧酸]衍生的单体单位，其数量为树脂总单体组分的1-5000 mmol％，以及一种碱性金属化合物，其数量为树脂总单体组分的10-3000 ppm作为碱性金属。本发明的液晶聚酯树脂具有良好的着色性，改善的耐热性和良好的机械性能。
• LITHOGRAPHIC PRINTING PLATE PRECURSOR AND LITHOGRAPHIC PRINTING METHOD
  申请人：IWAI Yu

  公开号：US20080087183A1

  公开（公告）日：2008-04-17

  A lithographic printing plate precursor includes an image-recording layer which is capable of being removed with at least one of printing ink and dampening water and contains a compound represented by the following formula (I), a sensitizing dye and a compound having at least one addition-polymerizable ethylenically unsaturated bond: wherein R 1 represents a monovalent substituent, R 2 , R 3 , R 4 , R 5 and R 6 each independently represents a hydrogen atom, a halogen atom or a monovalent substituent, and X − represents an anion.

  一种光刻印刷版前体包括一个图像记录层，该层能够被印刷油墨和润湿水中的至少一种去除，并含有以下式（I）所代表的化合物，一种敏化染料和至少一种含有至少一个加成聚合乙烯基不饱和键的化合物：其中R1代表一个单价取代基，R2、R3、R4、R5和R6各自独立地代表氢原子、卤素原子或单价取代基，X⁻代表一个阴离子。
• THERMOPLASTIC RESIN WITH HIGH THERMAL CONDUCTIVITY
  申请人：Yoshihara Shusuke

  公开号：US20130035468A1

  公开（公告）日：2013-02-07

  Provided is a thermoplastic resin having excellent thermal conductivity, in which thermoplastic resin a change in number average molecular mass caused by progress of polymerization occurring when the thermoplastic resin material is melted and a change in thermal conductivity caused by the change in number average molecular mass are low. The thermoplastic resin has (A) a specific structure and (B) ends of molecular chains sealed by a monofunctional low molecular weight compound. The resin itself has excellent thermal conductivity. The change in number average molecular mass becomes small during melting of the thermoplastic resin material, so that the change in thermal conductivity of the resin itself becomes small.

  提供的是一种具有优异热导率的热塑性树脂，其中该热塑性树脂具有（A）特定结构和（B）由单官能低分子量化合物密封的分子链末端。当热塑性树脂材料熔化时，由聚合进展引起的数量平均分子量变化以及由数量平均分子量变化引起的热导率变化都很小。该树脂本身具有优异的热导率。在热塑性树脂材料熔化过程中，数量平均分子量的变化变得很小，因此树脂本身的热导率变化也很小。