1,4,7-tri-n-octyl-1,4,7-triazacyclononane | 1021873-99-3

• 分子结构分类: 有机化合物 - 有机氮化合物
• 英文名称: 1,4,7-tri-n-octyl-1,4,7-triazacyclononane
• 英文别名: 1,4,7-trioctyl-1,4,7-triazonane
• CAS: 1021873-99-3
• 化学式: C₃₀H₆₃N₃
• 分子量: 465.85
• InChiKey: SOFAOVZOIMGEPN-UHFFFAOYSA-N

计算性质

• 辛醇/水分配系数(LogP)：
  10.4
• 重原子数：
  33
• 可旋转键数：
  21
• 环数：
  1.0
• sp3杂化的碳原子比例：
  1.0
• 拓扑面积：
  9.7
• 氢给体数：
  0
• 氢受体数：
  3

反应信息

• 作为产物：
  描述：

  1,4,7-tri(n-heptylcarbonyl)-1,4,7-triazacyclononane 在 硼烷四氢呋喃络合物 作用下， 以 甲醇 为溶剂， 以85%的产率得到1,4,7-tri-n-octyl-1,4,7-triazacyclononane
  参考文献：
  名称：

  PROCESS FOR PRODUCTION OF POLYMERS WITH IRON COMPLEX CATALYST

  摘要：

  公开号：

  EP2269995B1

文献信息

• Process for production of polymers with iron complex catalyst
  申请人：DIC Corporation

  公开号：US08017706B2

  公开（公告）日：2011-09-13

  The present invention relates to a novel iron complex having a cyclic amine compound as a ligand and a method for producing polymers by polymerizing a radical polymerizable monomer in the presence of the iron complex and a radical generator. The problem for the present invention is providing a method capable of producing a polymer or block copolymer having a chemically convertible functional group at the end from a radical polymerizable monomer and providing a method for recovering the iron complex in a solvent with a high recovery rate after the polymerization reaction. This problem is solved by providing a novel iron complex, a method for producing a polymer in the presence of a radical polymerization initiator that uses the iron complex as a polymerization catalyst and a method for simply and easily recovering the iron complex. The present invention can provide an iron complex useful for the method for producing a polymer by polymerizing a radical polymerizable monomer and a method for producing the polymer using that iron complex.

  本发明涉及一种以环状胺化合物为配体的新型铁配合物，以及在铁配合物和自由基发生剂的存在下聚合自由基聚合单体以产生聚合物的方法。本发明的问题在于提供一种能够从自由基聚合单体中产生具有可化学转化的末端官能团的聚合物或嵌段聚合物的方法，并提供一种在聚合反应后以高回收率的溶剂回收铁配合物的方法。通过提供一种新型铁配合物、一种使用铁配合物作为聚合催化剂的自由基聚合引发剂的聚合物生产方法以及一种简单易行的回收铁配合物的方法来解决这个问题。本发明可提供一种铁配合物，该配合物对于通过聚合自由基聚合单体来生产聚合物的方法和使用该铁配合物来生产聚合物的方法非常有用。
• US8017706B2
  申请人：——

  公开号：US8017706B2

  公开（公告）日：2011-09-13
• PROCESS FOR PRODUCTION OF POLYMERS WITH IRON COMPLEX CATALYST
  申请人：Kai Hidetomo

  公开号：US20110105703A1

  公开（公告）日：2011-05-05

  The invention relates to a novel iron complex bearing a cyclic amine as ligand; and a process for the production of polymers by polymerizing a radical-polymerizable monomer in the presence of the iron complex and a radical generator. The invention aims at providing a process by which a polymer having a chemically convertible functional group at the end can be produced from a radical-polymerizable monomer and which permits the production of a block copolymer and a process for recovering, after polymerization, an iron complex into a solvent at a high recovery ratio. The aim can be solved by providing a novel iron complex, a process for producing a polymer in the presence of a radical polymerization initiator by using the iron complex as the polymerization catalyst, a process for the production of a block copolymer which is subsequent to the polymerization for producing the above polymer, and a process for recovering the iron complex easily and simply. The invention provides an iron complex useful in producing a polymer by polymerizing a radical-polymerizable monomer; and a process for the production of polymers with the iron catalyst.

  该发明涉及一种具有环胺作为配体的新型铁配合物；以及通过在铁配合物和自由基发生剂的存在下聚合自由基可聚合单体来生产聚合物的方法。该发明旨在提供一种通过在自由基可聚合单体中生产具有化学可转化官能团末端的聚合物的方法，并且允许生产嵌段共聚物以及在聚合后将铁配合物以高回收率回收到溶剂中的方法。该目的可以通过提供一种新型铁配合物、在自由基聚合引发剂的存在下使用铁配合物作为聚合催化剂生产聚合物的方法、在上述聚合物生产后用于生产嵌段共聚物的方法以及轻松简便地回收铁配合物的方法来实现。该发明提供了一种有用的铁配合物，用于通过聚合自由基可聚合单体来生产聚合物；以及使用铁催化剂生产聚合物的方法。