1,2-acenaphthylene dicarboxylic acid | 69352-10-9

• 分子结构分类: 有机化合物 - 苯类化合物 - 吖萘类
• 英文名称: 1,2-acenaphthylene dicarboxylic acid
• 英文别名: acenaphthylene-1,2-dicarboxylic acid；1,2-Acenaphthylen-dicarbonsaeure
• CAS: 69352-10-9
• 化学式: C₁₄H₈O₄
• 分子量: 240.215
• InChiKey: XKGLPSIQUWMMGU-UHFFFAOYSA-N

物化性质

• 沸点：
  372.4±30.0 °C(Predicted)
• 密度：
  1.615±0.06 g/cm3(Predicted)

计算性质

• 辛醇/水分配系数(LogP)：
  2.2
• 重原子数：
  18
• 可旋转键数：
  2
• 环数：
  3.0
• sp3杂化的碳原子比例：
  0.0
• 拓扑面积：
  74.6
• 氢给体数：
  2
• 氢受体数：
  4

反应信息

• 作为反应物：
  描述：

  甲醇 、 1,2-acenaphthylene dicarboxylic acid 在 硫酸 作用下， 生成 1,2-acenaphthylenedicarboxylic acid dimethyl ester
  参考文献：
  名称：

  Synthesis of 1,2-disubstituted acenaphthylenes

  摘要：

  DOI：

  10.1021/jo01322a043
• 作为产物：
  描述：

  1,2-dibromoacenaphthylene 在 N-甲基吡咯烷酮 、 硫酸 、 溶剂黄146 作用下， 生成 1,2-acenaphthylene dicarboxylic acid
  参考文献：
  名称：

  Synthesis of 1,2-disubstituted acenaphthylenes

  摘要：

  DOI：

  10.1021/jo01322a043

文献信息

• A potential photochemically driven information storage system
  作者：Reuben D. Rieke、Gary O. Page、Phillip M. Hudnall、Roger W. Arhart、Thomas W. Bouldin

  DOI：10.1039/c39900000038

  日期：——

  Orange acenaphthylene-1,2-dicarboxylic anhydride undergoes a solid state photochemical [2 + 2] cycloaddition upon irradiation at 390 nm to yield a white photodimer which can be cleaved back to two monomers by irradiation at 300 nm; this process can be repeated numerous times.

  橙色烯1,2-二羧酸酐在390 nm照射后经历固态光化学[2 + 2]环加成反应，生成白色光二聚体，可通过在300 nm照射裂解成两个单体；此过程可以重复很多次。
• HEROLD D. A.; RIEKE R. D., J. ORG. CHEM., 1979, 44, NO 8, 1359-1361
  作者：HEROLD D. A.、 RIEKE R. D.

  DOI：——

  日期：——
• COATING COMPOSITIONS
  申请人：Dow Global Technologies LLC

  公开号：EP2621998A1

  公开（公告）日：2013-08-07
• [EN] COATING COMPOSITIONS<br/>[FR] COMPOSITIONS DE REVÊTEMENT
  申请人：DOW GLOBAL TECHNOLOGIES LLC

  公开号：WO2012044490A1

  公开（公告）日：2012-04-05

  A coating composition comprising an advanced poly epoxy ester resin polymeric composition having the following chemical structure: where n is a number from 1 to about 3000; each m independently has a value of 0 or 1; each R0 is independently -H or -CH3; each R1 is independently -H or a C1 to C6 alkylene radical (saturated divalent aliphatic hydrocarbon radical); Ar is a divalent aromatic fused -ring moiety, which is most preferably a divalent naphthalene group, substituted divalent naphthalene group, where the substitute groups include an alkyl, cycloalkyl, an aryl or an aralkyl group or other substituent; and X is cycloalkylene group, including substituted cycloalkylene group, where the substitute group include an alkyl, cycloalkyl, an aryl or an aralkyl group or other substitute group, for example, a halogen, a nitro, a blocked isocyanate, or an alkyloxy group; the combination of cycloalkylene and alkylene groups and the combination of alkylene and cycloalkylene group with a bridging moiety in between.
• Synthesis of 1,2-disubstituted acenaphthylenes
  作者：David A. Herold、Reuben D. Rieke

  DOI：10.1021/jo01322a043

  日期：1979.4