4-(4'-hexyloxybenzoyloxy)benzoyl chloride | 52899-52-2

• 分子结构分类: 有机化合物 - 苯丙烷和聚酮 - 缩酚酸和缩酚酸环醚类
• 英文名称: 4-(4'-hexyloxybenzoyloxy)benzoyl chloride
• 英文别名: p-(p-hexyloxybenzoyloxy)benzoic acid chloride；(4-Carbonochloridoylphenyl) 4-hexoxybenzoate
• CAS: 52899-52-2
• 化学式: C₂₀H₂₁ClO₄
• 分子量: 360.837
• InChiKey: GWDOZAAOSZYTFT-UHFFFAOYSA-N

物化性质

• 沸点：
  491.8±30.0 °C(Predicted)
• 密度：
  1.179±0.06 g/cm3(Predicted)

计算性质

• 辛醇/水分配系数(LogP)：
  6.1
• 重原子数：
  25
• 可旋转键数：
  10
• 环数：
  2.0
• sp3杂化的碳原子比例：
  0.3
• 拓扑面积：
  52.6
• 氢给体数：
  0
• 氢受体数：
  4

反应信息

• 作为反应物：
  描述：

  4-(4'-hexyloxybenzoyloxy)benzoyl chloride 在 水 、 四丁基硫酸氢铵 、 potassium carbonate 、 溶剂黄146 作用下， 以 乙醇 、 二氯甲烷 为溶剂， 生成 [4-[4-[[3-[3-[[4-[4-(4-Hexoxybenzoyl)oxybenzoyl]oxyphenyl]methylideneamino]benzoyl]phenyl]iminomethyl]phenoxy]carbonylphenyl] 4-hexoxybenzoate
  参考文献：
  名称：

  Synthesis and Characterization of Symmetrical Eight Aromatic Ring Containing Bent-Shaped Material Derived from Benzophenone

  摘要：

  A new family of symmetrical eight aromatic ring-containing bent-shaped mesogens in which the central elbow is a ketone has been synthesized and characterized. The effect of the side chain on the mesomorphism has been studied. All the bent derivatives were found to exhibit mesomorphism. The higher homologues of the series exhibit the B1 phase and the lower homologues of the series show the B6 phase.

  DOI：

  10.1080/15421406.2010.526450
• 作为产物：
  描述：

  4-formylphenyl 4-hexyloxybenzoate 在 Jones reagent 、 氯化亚砜 作用下， 以 丙酮 为溶剂， 反应 3.0h， 生成 4-(4'-hexyloxybenzoyloxy)benzoyl chloride
  参考文献：
  名称：

  Synthesis and Characterization of Symmetrical Eight Aromatic Ring Containing Bent-Shaped Material Derived from Benzophenone

  摘要：

  A new family of symmetrical eight aromatic ring-containing bent-shaped mesogens in which the central elbow is a ketone has been synthesized and characterized. The effect of the side chain on the mesomorphism has been studied. All the bent derivatives were found to exhibit mesomorphism. The higher homologues of the series exhibit the B1 phase and the lower homologues of the series show the B6 phase.

  DOI：

  10.1080/15421406.2010.526450

文献信息

• Core-to-core dimers forming switchable mesophase
  作者：M. Horčic、J. Svoboda、V. Novotná、D. Pociecha、E. Gorecka

  DOI：10.1039/c6cc09983a

  日期：——

  We report structurally new type of dimers composed of bent-core molecules connected through their central cores by an alkylene spacer.

  我们报告了由弯曲核心分子通过烷基间隔连接它们的中心核心而组成的新型二聚体。
• Synthesis and liquid crystal properties of substituted 5-(arylcarbonyloxy)-2(p-cyanophenyl)pyrimidines
  作者：M. A. Mikhaleva、G. A. Igonina、V. A. Savel'ev

  DOI：10.1007/bf01373550

  日期：1995.3
• New Liquid Crystalline Material Exhibiting a Reentrant Nematic Phase
  作者：Shunsuke Takenaka、Hideyuki Nakai、Shigekazu Kusabayashi

  DOI：10.1080/00268948308075359

  日期：1983.10
• Synthesis and liquid crystalline properties of 2-substituted (5-pyrimidinyl) benzoates and benzoyloxybenzoates
  作者：T. A. Kizner、M. A. Mikhaleva、E. S. Serebryakova

  DOI：10.1007/bf00474238

  日期：1991.3
• Deutscher, H.-J.; Krieg, R.; Frach, R., Journal fur praktische Chemie (Leipzig 1954), 1987, vol. 329, # 6, p. 963 - 974
  作者：Deutscher, H.-J.、Krieg, R.、Frach, R.、Kresse, H.、Zaschke, H.

  DOI：——

  日期：——