(1',3',3'-Trimethylspiro[benzo[f][1,4]benzoxazine-3,2'-indole]-9-yl) 2-bromo-2-methylpropanoate | 869119-24-4

• 分子结构分类: 有机化合物 - 有机杂环化合物 - 苯并恶嗪类
• 英文名称: (1',3',3'-Trimethylspiro[benzo[f][1,4]benzoxazine-3,2'-indole]-9-yl) 2-bromo-2-methylpropanoate
• CAS: 869119-24-4
• 化学式: C₂₆H₂₅BrN₂O₃
• 分子量: 493.4
• InChiKey: XBALBURKEWBDJN-UHFFFAOYSA-N

计算性质

• 辛醇/水分配系数(LogP)：
  6.2
• 重原子数：
  32
• 可旋转键数：
  3
• 环数：
  5.0
• sp3杂化的碳原子比例：
  0.31
• 拓扑面积：
  51.1
• 氢给体数：
  0
• 氢受体数：
  5

反应信息

• 作为产物：
  描述：

  2-溴-2-甲基丙酰溴 、 1,3,3-trimethyl-9'-hydroxyspiro[indoline-2,3'-[3H]naphtho[2,1-b](1,4)oxazine] 在 三乙胺 作用下， 以 二氯甲烷 为溶剂， 以85%的产率得到(1',3',3'-Trimethylspiro[benzo[f][1,4]benzoxazine-3,2'-indole]-9-yl) 2-bromo-2-methylpropanoate
  参考文献：
  名称：

  Tailoring Photochromic Performance of Polymer-Dye Conjugates Using Living Radical Polymerization (ATRP)

  摘要：

  The photochromic performance of polymer-dye conjugates was successfully tailored using the living radical polymerization technique ATRP. ATRP allowed the synthesis of photochromic dye-polymer conjugates consisting of polymer of defined chain length and polydispersity with a single photochromic dye attached at one end. Control over the photochromic switching speed was achieved solely thorough choice of the chain length of the polymer conjugate.

  DOI：

  10.1080/15421400590946505

文献信息

• Photochromic compositions and articles comprising siloxane, alkylene or substituted alkylene oligomers
  申请人：Evans Alexander Richard

  公开号：US20070187656A1

  公开（公告）日：2007-08-16

  This invention relations to a polymerizable composition for forming a photochromic article of glass transition temperature of at least 50 ° C. on curing, the composition comprising: (a) a polymerizable composition comprising a monomer component or resin formed therefrom; and (b) a photochromic dye monomer comprising a photochromic moiety and at least one oligomeric group having at least one group reactive with the monomer component during or following curing wherein the oligomer group comprises a multiplicity of monomer units selected from siloxane, alkylene and substituted alkylene.

  本发明涉及一种可聚合组合物，用于形成玻璃化转变温度至少为50℃的光致变色物品，所述组合物包括：(a)一种聚合物组合物，包括单体组分或由其形成的树脂；以及(b)一种光致变色染料单体，包括一个光致变色基团和至少一个具有至少一个与单体组分在固化期间或固化后反应的寡聚物基团，其中寡聚物基团包括从硅氧烷、烷基和取代烷基中选择的多种单体单元。
• Photochromic Compounds Comprising Polymeric Substituents And Methods For Preparation And Use Thereof
  申请人：Evans Richard Alexander

  公开号：US20090093601A1

  公开（公告）日：2009-04-09

  The present invention relates to a compound comprising a photochromic moiety and at least one substituent comprising a polymer chain having a carbon backbone and a plurality of functional moieties appended to the carbon backbone.

  本发明涉及一种化合物，该化合物包括一个光致变色基团和至少一个取代基，该取代基包括具有碳骨架的聚合物链和附加到碳骨架上的多个功能基团。
• PHOTOCHROMIC COMPOSITIONS AND ARTICLES COMPRISING SILOXANE, ALKYLENE OR SUBSTITUTED ALKYLENE OLIGOMERS
  申请人：Advanced Polymerik Pty Ltd

  公开号：EP1740629B1

  公开（公告）日：2011-03-30
• Tailoring Photochromic Performance of Polymer-Dye Conjugates Using Living Radical Polymerization (ATRP)
  作者：Georgina K. Such、Richard A. Evans、Thomas P. Davis

  DOI：10.1080/15421400590946505

  日期：2005.5.1

  The photochromic performance of polymer-dye conjugates was successfully tailored using the living radical polymerization technique ATRP. ATRP allowed the synthesis of photochromic dye-polymer conjugates consisting of polymer of defined chain length and polydispersity with a single photochromic dye attached at one end. Control over the photochromic switching speed was achieved solely thorough choice of the chain length of the polymer conjugate.