3,3'-(piperazine-1,4-diyl)bis(1-chloropropan-2-ol) | 15336-88-6

• 分子结构分类: 有机化合物 - 有机杂环化合物 - 二嗪烷类
• 英文名称: 3,3'-(piperazine-1,4-diyl)bis(1-chloropropan-2-ol)
• 英文别名: N,N'-bis-(3-chloro-2-hydroxypropyl)piperazine；3,3'-dichloro-1,1'-piperazine-1,4-diyl-bis-propan-2-ol；1,4-bis-(3-chloro-2-hydroxy-propyl)-piperazine；1,4-Bis-(3-chlor-2-hydroxy-propyl)-piperazin；N,N'-bis(3-Chlor-2-oxypropyl)-piperazin；1-Chloro-3-[4-(3-chloro-2-hydroxypropyl)piperazin-1-yl]propan-2-ol
• CAS: 15336-88-6
• 化学式: C₁₀H₂₀Cl₂N₂O₂
• mdl: MFCD27945289
• 分子量: 271.187
• InChiKey: LQOMYIZRPNPJDB-UHFFFAOYSA-N

计算性质

• 辛醇/水分配系数(LogP)：
  0
• 重原子数：
  16
• 可旋转键数：
  6
• 环数：
  1.0
• sp3杂化的碳原子比例：
  1.0
• 拓扑面积：
  46.9
• 氢给体数：
  2
• 氢受体数：
  4

反应信息

• 作为反应物：
  描述：

  3,3'-(piperazine-1,4-diyl)bis(1-chloropropan-2-ol) 以 甲醇 为溶剂， 反应 5.0h， 以42%的产率得到N-(3-chloro-2-hydroxypropyl)-N'-(2-hydroxy-1,3-trimethylene)-piperazinium chloride
  参考文献：
  名称：

  Marton-Meresz, M.; Kuszmann, J., Acta Chimica Hungarica, 1983, vol. 112, # 1, p. 31 - 42

  摘要：

  DOI：
• 作为产物：
  描述：

  哌嗪 、 环氧氯丙烷 以 甲醇 为溶剂， 反应 12.0h， 生成 3,3'-(piperazine-1,4-diyl)bis(1-chloropropan-2-ol)
  参考文献：
  名称：

  CO2 fixation by dicopper(ii) complexes in hypodentate framework of N8O2

  摘要：

  合成了一种新的配体，其 N8O2 供体含有三个潜在的金属结合位点 (H2L) 及其三铜 (II) 配合物 1。发现三铜物质是由次齿二铜(II)络合物2在碱性溶液中形成的。络合物2可以从H2L与铜源在酸性条件下的反应中分离出来。配合物 2 可以进行 CO2 萃取，生成八铜 (II) 配合物 3。配合物 2 和 3 的单晶结构通过 X 射线晶体学进行了表征。

  DOI：

  10.1039/c3dt53497a

文献信息

• CO2 fixation by dicopper(ii) complexes in hypodentate framework of N8O2
  作者：Yi-Hsueh Ho、Mu-Chieh Chang、Kuo-Hsuan Yu、Yi-Hung Liu、Yu Wang、Yuan-Chung Cheng、Jwu-Ting Chen

  DOI：10.1039/c3dt53497a

  日期：——

  A new ligand with N8O2 donors containing three potential metal-binding sites (H2L) and its tricopper(II) complex 1 are synthesized. The tricopper species is found to be formed from a hypodentate dicopper(II) complex 2 in basic solutions. Complex 2 may be isolated from the reaction of H2L with a copper source under acidic conditions. Complex 2 can undergo CO2-abstraction to yield an octacopper(II) complex 3. The single crystal structures of complexes 2 and 3 are characterized by X-ray crystallography.

  合成了一种新的配体，其 N8O2 供体含有三个潜在的金属结合位点 (H2L) 及其三铜 (II) 配合物 1。发现三铜物质是由次齿二铜(II)络合物2在碱性溶液中形成的。络合物2可以从H2L与铜源在酸性条件下的反应中分离出来。配合物 2 可以进行 CO2 萃取，生成八铜 (II) 配合物 3。配合物 2 和 3 的单晶结构通过 X 射线晶体学进行了表征。
• Polyamines, synthesis method thereof and use thereof for the selective elimination of H2S from a gaseous effluent comprising CO2
  申请人：IFP Energies Nouvelles

  公开号：US11136434B2

  公开（公告）日：2021-10-05

  Polyamines of formula (I), their preparation method and their use in an absorbing solution based on amines in order to selectively eliminate H2S from a gaseous effluent containing H2S and CO2, which polyamines are obtained by a reaction between piperazine and an epihalohydrin or a 1,3-dihalo-2-propanol

  式(I)的多胺、其制备方法及其在基于胺的吸收液中的用途，以选择性地消除含有H2S和CO2的气态流出物中的H2S，这些多胺是通过哌嗪与表卤代醇或1,3-二卤-2-丙醇反应得到的
• Structure-Activity Relationship of Some Diamine Bis-epoxides in Mouse Leukaemia
  作者：Koert Gerzon、James E. Cochran、Lawrence A. White、Rosmarie Monahan、Eriks V. Krumkalns、Robert E. Scroggs、Jack Mills

  DOI：10.1021/jm50004a003

  日期：1959.6
• MARTON-MERESZ, M.;KUSZMANN, J., ACTA CHIM. HUNG., 1983, 112, N 1, 31-41
  作者：MARTON-MERESZ, M.、KUSZMANN, J.

  DOI：——

  日期：——
• NOVEL POLYAMINES, SYNTHESIS METHOD THEREOF AND USE THEREOF FOR THE SELECTIVE ELIMINATION OF H2S FROM A GASEOUS EFFLUENT COMPRISING CO2
  申请人：IFP Energies Nouvelles

  公开号：US20200148824A1

  公开（公告）日：2020-05-14

  The invention concerns novel polyamines with formula (I), obtained by the reaction between piperazine and an epihalohydrin or a 1,3-dihalo-2-propanol, n being in the range 2 to 100, R 1 being equally either an H or an alkyl radical containing between 1 and 8 carbon atoms or a hydroxyalkyl radical having the following general formula (II): R 2 being equally either an H or an alkyl radical containing between 1 and 6 carbon atoms; two R 2 may be connected together via a covalent bond in order to form a cycle if they are alkyl radicals. The invention also concerns their preparation method and their use in an absorbing solution based on amines in order to selectively eliminate H 2 S from a gaseous effluent containing H 2 S and CO 2 .