| 230972-40-4

• 分子结构分类: 有机化合物 - 有机杂环化合物 - 苯并二恶烷
• CAS: 230972-40-4
• 化学式: C₂H₃N*C₂₆H₁₇MnN₂O₄
• 分子量: 517.423
• InChiKey: IAWCVDDQATYYDV-JIHFSCHTSA-K

计算性质

• 辛醇/水分配系数(LogP)：
  None
• 重原子数：
  None
• 可旋转键数：
  None
• 环数：
  None
• sp3杂化的碳原子比例：
  None
• 拓扑面积：
  None
• 氢给体数：
  None
• 氢受体数：
  None

反应信息

• 作为产物：
  描述：

  potassium permanganate 、 2-羟基缩苯胺 、 乙腈 以 乙腈 为溶剂， 生成
  参考文献：
  名称：

  Structures of four types of novel high-valent manganese complexes obtained by the reactions of KMnO4 with tridentate Schiff base ligands

  摘要：

  X-ray structure analysis revealed that four types of novel manganese complexes, Mn-IV(N-EtO-sal)(2), Mn-III(N-PhO-sal)(L), [Mn-IV(5,6-Benzo-L)(2)(mu-O)](2) and Mn-III(L-4-Me)(3) have been found to be obtained by the reactions of KMnO4 with various tridentate Schiff base ligands (N-EtOH-salH, N-PhOH-salH and its derivatives) in dry MeCN, where N-EtOH-salH, N-PhOH-sales, LH, 5,6-Benzo-LH and L-4-MeH denote N-2-hydroxyethyl-salicylideneamine, N-2-hydroxyphenyl-salicylideneamine, 2-(2-hydroxyphenyl)benzoxazole 2-(2-hydroxynaphthyl)-benzoxazole and 2-(2-hydroxyphenyl)-5-methylbenzoxazole, respectively. The reactions of KMnO4 and N-PhOH-sales and its derivatives have especially been found to afford benzoxazole derivatives which may be formed by intramolecular oxidative coupling between the phenolic oxygen atom of aminophenol moiety and the carbon atom of imine moiety. (C) 2002 Elsevier Science Ltd. All rights reserved.

  DOI：

  10.1016/s0277-5387(02)00936-1