{Ni(salicylidene-o-aminophenol(2-))(H2O)} | 781642-00-0

• 分子结构分类: 有机化合物 - 苯丙烷和聚酮 - 二苯乙烯类
• 英文名称: {Ni(salicylidene-o-aminophenol(2-))(H2O)}
• 英文别名: aquo[N-(2-hydroxyphenyl)salicylaldiminato]nickel(II)；Ni(salicylidene 2-aminophenol(-2H))(H2O)；[Ni(N-salicylidene-o-aminophenol)(H2O)]
• CAS: 781642-00-0；65106-67-4
• 化学式: C₁₃H₁₁NNiO₃
• 分子量: 287.925
• InChiKey: SEJUZPMZSVZSRM-CAJRCRMVSA-L

计算性质

• 辛醇/水分配系数(LogP)：
  0.76
• 重原子数：
  18.0
• 可旋转键数：
  2.0
• 环数：
  2.0
• sp3杂化的碳原子比例：
  0.0
• 拓扑面积：
  89.98
• 氢给体数：
  0.0
• 氢受体数：
  3.0

反应信息

• 作为反应物：
  描述：

  {Ni(salicylidene-o-aminophenol(2-))(H2O)} 以 neat (no solvent, solid phase) 为溶剂， 生成 nickel(II) oxide
  参考文献：
  名称：

  Synthesis, structural characterization, thermal studies, catalytic efficiency and antimicrobial activity of some M(II) complexes with ONO tridentate Schiff base N-salicylidene-o-aminophenol (saphH2)

  摘要：

  The reactions of acetate salts of M(II) (M = Mn, Co, Ni, Cu and Zn) with N-salicylidene-o-aminophenol (saphH(2)) in ethyl alcohol afforded new four coordinated complexes with the general formula [M-(II)(saph)(H2O)]. The complexes have been fully characterized by microanalysis, molar conductance, magnetic susceptibility, H-1 NMR, IR, UV-Vis, ESR, mass spectra and thermogravimetric analysis (TGA). The experimental data have been shown that all complexes are mononuclear with the M(II) being coordinated by a dianionic tridentate Schiff base ligand, through the deprotonated two enolic oxygen and the azomethine nitrogen atoms. UV-Vis spectra and magnetic moments have been suggested square planar stereochemistry for Co(II) and Cu(II) complexes, and tetrahedral geometry has been suggested for Mn(II), Ni(II) and Zn(II) complexes. The new complexes have been tested for their abilities to catalyze aerial oxidation of benzaldehyde to benzoic acid. Finally, in view of the biological activity, antibacterial and antifungal tests of the ligand and its complexes have been carried out and the results were compared with some known antibiotics. (C) 2011 Elsevier B.V. All rights reserved.

  DOI：

  10.1016/j.molstruc.2011.11.043
• 作为产物：
  描述：

  nickel(II) chloride hexahydrate 、 2-羟基缩苯胺 在 KOH 作用下， 以 甲醇 为溶剂， 以80%的产率得到{Ni(salicylidene-o-aminophenol(2-))(H2O)}
  参考文献：
  名称：

  Chatterjee, Debabrata; Mukherjee, Sanghamitra, Indian Journal of Chemistry, Section A: Inorganic, Physical, Theoretical and Analytical, 2002, vol. 41, # 7, p. 1406 - 1409

  摘要：

  DOI：

文献信息

• Electrochemical synthesis and structural characterization of nickel(II) and copper(II) complexes of tridentate schiff bases: Molecular structure of the five-coordinated copper(II) complex: 1,10-phenanthroline {2-[(2-oxyphenyl)iminomethyl]phenolato}copper(II)
  作者：Elena Labisbal、Jose A. Garcia-Vazquez、Jaime Romero、Sofia Picos、Antonio Sousa、Alfonso Castiñeiras、Cäcilia Maichle-Mössmer

  DOI：10.1016/0277-5387(94)00292-m

  日期：1995.3

  of metal anodes (copper and nickel) in acetonitrile solutions of Schiff bases (H2L) (synthesized from salicylaldehydes and 2-aminophenols) gave CuL and NiL complexes. When 1,10-phenanthroline (phen) or 2,2′-bipyridine (bipy) was added to the electrolytic cell, the mixed complexes CuLL′ and NiLL′ (L′ = phen or bipy) were obtained. The crystal structure of 1,10-phenanthroline 2-[(2-oxyphenyl)iminomet

  摘要在由水杨醛和2-氨基苯酚合成的席夫碱（H2L）的乙腈溶液中，金属阳极（铜和镍）的电化学氧化产生了CuL和NiL配合物。当将1，10-菲咯啉（phen）或2，2′-联吡啶（bipy）添加到电解池中时，获得混合的配合物CuLL′和NiLL′（L′＝ phen或bipy）。通过X射线衍射测定1，10-菲咯啉2-[（（2-氧苯基）亚氨基甲基]苯酚基}铜（II）的晶体结构。该结构由单体分子组成，其中铜原子具有扭曲的方金字塔形CuN3O2核。
• Synthesis, spectroscopy and thermal study of some nickel(II) complexes containing tridentate Schiff bases and substituted amine ligands, X-ray crystal structure of nickel(II) complex
  作者：Ali Hossein Kianfar、Masomeh Bahramian、Hamid Reza Khavasi

  DOI：10.1016/j.saa.2012.03.039

  日期：2012.8

  and has four coordinate in the solid state. The thermogravimmetry (TG) and differential thermoanalysis (DTA) of the synthesized complexes were carried out in the range of 20–700 °C, leading to decomposition of ONO type in two stages and of ONS type in three stages. The ONO and ONS complexes were decomposed to NiO and NiS respectively. Thermal decomposition of the complexes is closely the depends upon

  合成了一些新的[NiL（胺）]的三齿ONO和ONS Schiff碱配合物（L =水杨基2-氨基苯酚和水杨基2-氨基硫代苯酚，胺=苄胺，吗啉，吡咯烷和哌啶），并用红外光谱，紫外可见光谱，1 H NMR光谱和元素分析。[NiL 2的几何通过X射线晶体学测定的[bzlan]表明该络合物具有平面结构并且在固态具有四个坐标。合成配合物的热重分析（TG）和差示热分析（DTA）在20–700°C的范围内进行，导致ONO型分解为两个阶段，ONS型分解为三个阶段。将ONO和ONS配合物分别分解为NiO和NiS。配合物的热分解与席夫碱配体的性质密切相关，并通过一级动力学进行。
• Shukla, P. R.; Singh, V. K.; Jaiswal, A. M., Journal of the Indian Chemical Society, 1983, vol. 60, p. 321 - 324
  作者：Shukla, P. R.、Singh, V. K.、Jaiswal, A. M.、Narain, Gopal

  DOI：——

  日期：——
• Stability studies in relation to IR data of some schiff base complexes of transition metals and their biological and pharmacological studies
  作者：R.K. Parashar、R.C. Sharma、Anil Kumar、Govind Mohan

  DOI：10.1016/s0020-1693(00)83468-4

  日期：1988.3
• Chatterjee, Debabrata; Mukherjee, Sanghamitra; Mitra, Anannya, Indian Journal of Chemistry, Section A: Inorganic, Physical, Theoretical and Analytical, 1999, vol. 38, # 11, p. 1177 - 1180
  作者：Chatterjee, Debabrata、Mukherjee, Sanghamitra、Mitra, Anannya

  DOI：——

  日期：——