N,N'-bis(salicylidene)-1,1-dimethylethane-1,2-diamine

• 分子结构分类: 有机化合物 - 苯类化合物 - 酚类
• 英文名称: N,N'-bis(salicylidene)-1,1-dimethylethane-1,2-diamine
• 英文别名: 2,2'-((Butane-2,3-diylbis(azanylylidene))bis(methanylylidene))diphenol；2-[3-[(2-hydroxyphenyl)methylideneamino]butan-2-yliminomethyl]phenol
• 化学式: C₁₈H₂₀N₂O₂
• 分子量: 296.369
• InChiKey: CUBYBPBDWDVROB-UHFFFAOYSA-N

计算性质

• 辛醇/水分配系数(LogP)：
  2.9
• 重原子数：
  22
• 可旋转键数：
  5
• 环数：
  2.0
• sp3杂化的碳原子比例：
  0.22
• 拓扑面积：
  65.2
• 氢给体数：
  2
• 氢受体数：
  4

反应信息

• 作为反应物：
  描述：

  bis(acetylacetonate)oxovanadium 、 N,N'-bis(salicylidene)-1,1-dimethylethane-1,2-diamine 以 甲醇 为溶剂， 以81%的产率得到
  参考文献：
  名称：

  New compounds of tetradentate Schiff bases with vanadium(IV) and vanadium(V) †

  摘要：

  一系列潜在的四齿配体H2L已由芳香醛、酮以及脂肪族二胺制备而成。它们的钒(IV)和钒(V)配合物[VO(L)]和[VO(L)]+，以及一些加合物[VO(L)→VO(L)]+也已合成。对四个选定配合物的结构进行了确定，结果显示这些结构必须是由于立体和电子因素的共同作用，使得对构象和堆叠的预测变得困难。加合物[VO(L)→VO(L)]+在二氯甲烷溶液中具有持久的结构，在该环境中它们可以进行氧化还原反应，但在供体溶剂乙腈中，它们显然会解离成各自的组成配合物。

  DOI：

  10.1039/a908337e

文献信息

• Structural effect of cobalt Schiff base complex catalyst on its catalytic activity in dioxygenolysis of 3-methylindole
  作者：Akira Nishinaga、Toshihiko Tsutsui、Hideki Moriyama、Takahiro Wazaki、Takahiro Mashino、Yuki Fujii

  DOI：10.1016/0304-5102(93)87012-w

  日期：1993.7

  Dioxygenolysis of 3-methylindole catalyzed by a series of cobalt(II) Schiff base complexes electronically and sterically designed gives 2-(N-formylamino) acetophenone as the sole product, but the reaction rate depended largely on the structure of the complex:the more positive SIGMA-degrees (Co(II)/Co(III)) brings about the more catalytic activity. Steric hindrance of coordination of the substrate to the catalyst retards the reaction.
• New compounds of tetradentate Schiff bases with vanadium(IV) and vanadium(V) †
  作者：Nosheen F. Choudhary、Neil G. Connelly、Peter B. Hitchcock、G. Jeffery Leigh

  DOI：10.1039/a908337e

  日期：——

  A new range of potentially tetradentate proligands, H2L, derived from aromatic aldehydes and ketones and aliphatic diamines has been prepared. Their vanadyl(IV) and vanadyl(V) complexes [VO(L)] and [VO(L)]+, and also some adducts [VO(L)→VO(L)]+, have been synthesized. The structures of four selected complexes have been determined and it is shown that these must be a result of both steric and electronic factors that make prediction of conformation and stacking difficult. The adducts [VO(L)→VO(L)]+ have structures that persist in solution in dichloromethane, where they can undergo redox chemistry, but they apparently dissociate into their component complexes in the donor solvent acetonitrile.

  一系列潜在的四齿配体H2L已由芳香醛、酮以及脂肪族二胺制备而成。它们的钒(IV)和钒(V)配合物[VO(L)]和[VO(L)]+，以及一些加合物[VO(L)→VO(L)]+也已合成。对四个选定配合物的结构进行了确定，结果显示这些结构必须是由于立体和电子因素的共同作用，使得对构象和堆叠的预测变得困难。加合物[VO(L)→VO(L)]+在二氯甲烷溶液中具有持久的结构，在该环境中它们可以进行氧化还原反应，但在供体溶剂乙腈中，它们显然会解离成各自的组成配合物。