烯丙基叔丁基过氧碳酸酯 | 65700-08-5

• 分子结构分类: 有机化合物 - 有机酸及其衍生物 - 有机碳酸及其衍生物
• 中文名称: 烯丙基叔丁基过氧碳酸酯
• 中文别名: 叔丁过氧化烯丙基碳酸酯
• 英文名称: percarbonate de O-allyle et O,O-t-butyle
• 英文别名: Allyl tert-butoxy carbonate；(2-methylpropan-2-yl)oxy prop-2-enyl carbonate
• CAS: 65700-08-5
• 化学式: C₈H₁₄O₄
• 分子量: 174.197
• InChiKey: KZDYQEYSNHDGEX-UHFFFAOYSA-N

物化性质

• 熔点：
  -50 °C
• 沸点：
  171.7±33.0 °C(Predicted)
• 密度：
  1.013±0.06 g/cm3(Predicted)
• 闪点：
  50 °C
• 稳定性/保质期：

  遵照规定使用和储存，则不会分解。

计算性质

• 辛醇/水分配系数(LogP)：
  2.2
• 重原子数：
  12
• 可旋转键数：
  6
• 环数：
  0.0
• sp3杂化的碳原子比例：
  0.62
• 拓扑面积：
  44.8
• 氢给体数：
  0
• 氢受体数：
  4

安全信息

• 危险品标志：
  O,Xi
• 安全说明：
  S14,S26,S36,S37,S39
• 危险类别码：
  R7,R10,R36/38
• 海关编码：
  2918300090

反应信息

• 作为反应物：
  描述：

  丙酸甲酯 、 烯丙基叔丁基过氧碳酸酯 在 过氧化苯甲酰 作用下， 反应 24.0h， 以37%的产率得到(methoxycarbonyl-2) propyl-4 oxo-2 dioxolanne-1,3
  参考文献：
  名称：

  Kharrat, A.; Gardrat, C.; Maillard, B., Bulletin des Societes Chimiques Belges, 1986, vol. 95, # 7, p. 535 - 546

  摘要：

  DOI：
• 作为产物：
  描述：

  叔丁基过氧化氢 、 烯丙醇 、 N,N'-羰基二咪唑 生成 烯丙基叔丁基过氧碳酸酯
  参考文献：
  名称：

  Kharrat, A.; Gardrat, C.; Maillard, B., Bulletin des Societes Chimiques Belges, 1986, vol. 95, # 7, p. 535 - 546

  摘要：

  DOI：

文献信息

• Preparation of expandable styrene polymers
  申请人：Atofina Chemicals, Inc.

  公开号：EP1408056A1

  公开（公告）日：2004-04-14

  Enhanced conversion rates are realized in a suspension polymerization process for styrene through the use of peroxide initiators having one hour half life temperatures from 101° to 111° C are disclosed. Also disclosed are suitable initiator combinations which provide polymeric products with low residual monomer content at reduced process temperatures, polymerizable compositions containing such initiators and products produced by such processes and compositions.

  公开了在苯乙烯悬浮聚合工艺中，通过使用半衰期为一小时、温度为 101°C 至 111°C 的过氧化物引发剂，可提高转化率。此外，还公开了合适的引发剂组合，可在较低的工艺温度下提供残余单体含量较低的聚合产品、含有此类引发剂的可聚合组合物以及通过此类工艺和组合物生产的产品。
• ACRYLIC RESIN COMPOSITION AND LAMINATE FORMED BY LAMINATING SAME
  申请人：Adeka Corporation

  公开号：EP3235866A1

  公开（公告）日：2017-10-25

  The invention provides an acrylic resin composition that has excellent weather resistance and can be stably produced at high temperatures. Specifically, disclosed is an acrylic resin composition including, with respect to 100 parts by mass of an acrylic resin, from 0.1 to 8 parts by mass of a triazine-based UV absorber including 2-(4,6-diphenyl-1,3,5-triazin-2-yl)-5-[2-(2-ethylhexanoyloxy)ethoxy]phenol, wherein the acrylic resin used is an acrylic resin including at least 80 wt% of methyl methacrylate as a monomer component, and having a glass transition temperature of at least 80°C.

  本发明提供了一种丙烯酸树脂组合物，该组合物具有优异的耐候性，可在高温下稳定生产。具体地说，本发明公开了一种丙烯酸树脂组合物，以 100 份丙烯酸树脂的质量份数计，包括 0.1 至 8 份三嗪基紫外线吸收剂，其中三嗪基紫外线吸收剂包括 2-(4,6-二苯基-1,3,5-三嗪-2-基)-5-[2-(2-乙基己酰氧基)乙氧基]苯酚，其中使用的丙烯酸树脂是包括至少 80 wt%的甲基丙烯酸甲酯作为单体成分的丙烯酸树脂，且玻璃化转变温度至少为 80°C。
• JPH09104724A
  申请人：——

  公开号：JPH09104724A

  公开（公告）日：1997-04-22
• MOLDED ARTICLE AND LAMINATE INCORPORATING ACRYLIC RESIN COMPOSITION
  申请人：ADEKA CORPORATION

  公开号：US20180327584A1

  公开（公告）日：2018-11-15

  Disclosed is an acrylic resin composition that has excellent weather resistance and can be stably produced at high temperatures. Specifically, disclosed is an acrylic resin composition including, with respect to 100 parts by mass of an acrylic resin, from 0.1 to 8 parts by mass of a triazine-based UV absorber including 2-(4,6-diphenyl-1,3,5-triazin-2-yl)-5-[2-(2-ethylhexanoyloxy)ethoxy]phenol, wherein the acrylic resin used is an acrylic resin including at least 80 wt % of methyl methacrylate as a monomer component, and having a glass transition temperature of at least 80° C.
• SILICON-BASED ENERGY STORAGE DEVICES WITH ELECTROLYTE ADDITIVE COMPOUNDS
  申请人：Enevate Corporation

  公开号：US20200388880A1

  公开（公告）日：2020-12-10

  Electrolytes and electrolyte additives for energy storage devices are disclosed. The energy storage device comprises a first electrode and a second electrode, where one or both of the first electrode and the second electrode is a Si-based electrode, a separator between the first electrode and the second electrode, an electrolyte, and at least one electrolyte additive compound selected from a carbonate, oxalate, trioxidane, peroxide, peroxoate, dioxetanone, oxepane dione, oxetane dione, anhydride, oxalate or 1,4-dioxane-2,3-dione; each of which may be optionally substituted.