isopropyldimethyl(n-tetradecyl)silane

• 分子结构分类: 有机化合物 - 有机金属化合物 - 有机类金属化合物
• 英文名称: isopropyldimethyl(n-tetradecyl)silane
• 英文别名: dimethyl-propan-2-yl-tetradecylsilane
• 化学式: C₁₉H₄₂Si
• 分子量: 298.628
• InChiKey: YYFHPKLAWSNSMC-UHFFFAOYSA-N

计算性质

• 辛醇/水分配系数(LogP)：
  7.81
• 重原子数：
  20.0
• 可旋转键数：
  14.0
• 环数：
  0.0
• sp3杂化的碳原子比例：
  1.0
• 拓扑面积：
  0.0
• 氢给体数：
  0.0
• 氢受体数：
  0.0

反应信息

• 作为产物：
  描述：

  二甲基异丙基氯硅烷 在 dihydrogen hexachloroplatinate 、 lithium aluminium tetrahydride 作用下， 生成 isopropyldimethyl(n-tetradecyl)silane
  参考文献：
  名称：

  Mass spectra of some high molecular weight tetra(alkyl)silanes

  摘要：

  AbstractThe mass spectra of tetra(alkyl)silanes having one short and three long alkyl groups were recorded (C20C32). These silanes did not give molecular ions, and the dominant course of fragmentation involved the loss of alkyl groups, followed by elimination of alkenes. The loss of alkyl groups, followed by elimination of alkenes. The loss of alkyl groups followed the sequence iso‐Pr>Et, Pr,… C14H29» Me. With alkyl groups longer than hexyl, a rearrangement was observed in which n‐alkanes were eliminated from the base ion. When the alkyl group was hexyl, the alkane eliminated was methane; when the alkyl group was heptyl, ethane was expelled; with octyl, it was propane; and with decyl, n‐pentane was expelled. Deuterium labeling showed that at least two modes of rearrangement were occurring.

  DOI：

  10.1002/oms.1210200805

文献信息

• Mass spectra of some high molecular weight tetra(alkyl)silanes
  作者：Anatoli Onopchenko、Edward T. Sabourin、David A. Danner

  DOI：10.1002/oms.1210200805

  日期：1985.8

  AbstractThe mass spectra of tetra(alkyl)silanes having one short and three long alkyl groups were recorded (C20C32). These silanes did not give molecular ions, and the dominant course of fragmentation involved the loss of alkyl groups, followed by elimination of alkenes. The loss of alkyl groups, followed by elimination of alkenes. The loss of alkyl groups followed the sequence iso‐Pr>Et, Pr,… C14H29» Me. With alkyl groups longer than hexyl, a rearrangement was observed in which n‐alkanes were eliminated from the base ion. When the alkyl group was hexyl, the alkane eliminated was methane; when the alkyl group was heptyl, ethane was expelled; with octyl, it was propane; and with decyl, n‐pentane was expelled. Deuterium labeling showed that at least two modes of rearrangement were occurring.