N-(perfluorooctanoyl) hydrazine | 30252-50-7

• 分子结构分类: 有机化合物 - 有机卤素化合物 - 卤代烷
• 英文名称: N-(perfluorooctanoyl) hydrazine
• 英文别名: N-(perfluorooctanoyl)-hydrazine；2,2,3,3,4,4,5,5,6,6,7,7,8,8,8-Pentadecafluorooctanehydrazide
• CAS: 30252-50-7
• 化学式: C₈H₃F₁₅N₂O
• 分子量: 428.101
• InChiKey: NUZIRGBVBCZKRH-UHFFFAOYSA-N

计算性质

• 辛醇/水分配系数(LogP)：
  3.9
• 重原子数：
  26
• 可旋转键数：
  6
• 环数：
  0.0
• sp3杂化的碳原子比例：
  0.88
• 拓扑面积：
  55.1
• 氢给体数：
  2
• 氢受体数：
  17

反应信息

• 作为反应物：
  描述：

  N-(perfluorooctanoyl) hydrazine 在 phosphorus pentoxide 作用下， 生成 5,5'-bis-pentadecafluoroheptyl-2,2'-(1,1,2,2,3,3-hexafluoro-propane-1,3-diyl)-bis-[1,3,4]oxadiazole
  参考文献：
  名称：

  Mazalova,Z.I. et al., Journal of Organic Chemistry USSR (English Translation), 1972, vol. 8, p. 535 - 540

  摘要：

  DOI：
• 作为产物：
  描述：

  十五氟辛酸甲酯 在 肼 作用下， 以 甲醇 为溶剂， 生成 N-(perfluorooctanoyl) hydrazine
  参考文献：
  名称：

  1,3,4-Oxadiazoles with SF5-containing substituents

  摘要：

  1,3,4-Oxadiazoles containing a combination of SF5-perfluoroalkyl, SF5-alkyl, polynitroalkyl and perfluoroalkyl substituents have been synthesized by cyclization (dehydration) of the corresponding diacyl hydrazines. The properties of oxadiazoles with SF5-perfluoroalkyl substituents are compared with those of similar oxadiazoles containing the corresponding perfluoroalkyl substituent (CF3 in place of SF5).

  DOI：

  10.1016/0022-1139(94)03095-h

文献信息

• 2-polynitroalkyl-5-perfluoroalkyl-1,3,4-oxadiazoles
  申请人：The United States of America as represented by the Secretary of the Navy

  公开号：US05241071A1

  公开（公告）日：1993-08-31

  An oxadiazole of the formula ##STR1## wherein n is 0, 1, 2, 3, or 4 when X is --F but n is 0, 1, or 2 when X is -NO.sub.2. These oxidiazoles are useful as energetic plasticizers for explosives.

  一种氧代唑的化学式为##STR1##，其中当X为--F时，n为0、1、2、3或4，但当X为-NO.sub.2时，n为0、1或2。这些氧代唑可用作炸药的高能塑化剂。
• Composition and method for capture and degradation of PFAS
  申请人：Battelle Memorial Institute

  公开号：US11518689B2

  公开（公告）日：2022-12-06

  Materials for binding per- and polyfluoroalkyl substances (PFAS) are disclosed. A fluidic device comprising the materials for detection and quantification of PFAS in a sample is disclosed. The fluidic device may be configured for multiplexed analyses. Also disclosed are methods for sorbing and remediating PFAS in a sample. The sample may be groundwater containing, or suspected of containing, one or more PFAS.

  本发明公开了用于结合全氟和多氟烷基物质（PFAS）的材料。还公开了一种流体装置，其中包含用于检测和定量样品中 PFAS 的材料。该流体装置可用于多重分析。还公开了吸附和修复样品中 PFAS 的方法。样品可以是含有或怀疑含有一种或多种 PFAS 的地下水。
• COMPOSITION AND METHOD FOR CAPTURE AND DEGRADATION OF PFAS
  申请人：Battelle Memorial Institute

  公开号：US20200369536A1

  公开（公告）日：2020-11-26

  Materials for binding per- and polyfluoroalkyl substances (PFAS) are disclosed. A fluidic device comprising the materials for detection and quantification of PFAS in a sample is disclosed. The fluidic device may be configured for multiplexed analyses. Also disclosed are methods for sorbing and remediating PFAS in a sample. The sample may be groundwater containing, or suspected of containing, one or more PFAS.
• US5241071A
  申请人：——

  公开号：US5241071A

  公开（公告）日：1993-08-31
• 1,3,4-Oxadiazoles with SF5-containing substituents
  作者：M.E. Sitzmann

  DOI：10.1016/0022-1139(94)03095-h

  日期：1995.1

  1,3,4-Oxadiazoles containing a combination of SF5-perfluoroalkyl, SF5-alkyl, polynitroalkyl and perfluoroalkyl substituents have been synthesized by cyclization (dehydration) of the corresponding diacyl hydrazines. The properties of oxadiazoles with SF5-perfluoroalkyl substituents are compared with those of similar oxadiazoles containing the corresponding perfluoroalkyl substituent (CF3 in place of SF5).