4-异丙氧基萘-1-醇 | 41426-37-3

• 分子结构分类: 有机化合物 - 苯类化合物 - 萘
• 中文名称: 4-异丙氧基萘-1-醇
• 英文名称: 4-isopropyloxynaphth-1-ol
• 英文别名: 4-isopropoxy-1-naphthol；4-isopropyl-1-naphthol；4-iso-propoxy-1-naphthol；4-Isopropoxy-[1]naphthol；Isopropyl-(4-hydroxy-naphthyl-(1))-aether；4-Hydroxy-1-isopropyloxy-naphthalin；1-Naphthalenol, 4-(1-methylethoxy)-；4-propan-2-yloxynaphthalen-1-ol
• CAS: 41426-37-3
• 化学式: C₁₃H₁₄O₂
• 分子量: 202.253
• InChiKey: WMVPFEQOLJSBDR-UHFFFAOYSA-N

物化性质

• 熔点：
  97 °C
• 沸点：
  363.0±15.0 °C(Predicted)
• 密度：
  1.127±0.06 g/cm3(Predicted)

计算性质

• 辛醇/水分配系数(LogP)：
  4.1
• 重原子数：
  15
• 可旋转键数：
  2
• 环数：
  2.0
• sp3杂化的碳原子比例：
  0.23
• 拓扑面积：
  29.5
• 氢给体数：
  1
• 氢受体数：
  2

安全信息

• 海关编码：
  2909499000

反应信息

• 作为反应物：
  描述：

  4-异丙氧基萘-1-醇 在 三氟化硼 、 异丙醇 作用下， 生成 2-isopropyl-naphthalene-1,4-diol
  参考文献：
  名称：

  Fieser et al., Journal of the American Chemical Society, 1948, vol. 70, p. 3177

  摘要：

  DOI：
• 作为产物：
  描述：

  1,4-二乙酰氧基萘 在 sodium hydroxide 、 乙醇 、 三氟化硼 作用下， 生成 4-异丙氧基萘-1-醇
  参考文献：
  名称：

  Fieser et al., Journal of the American Chemical Society, 1948, vol. 70, p. 3177

  摘要：

  DOI：

文献信息

• One step hair coloring compositions using salts
  申请人：Unilever Home & Personal Care USA, Division of Conopco, Inc.

  公开号：US20040019980A1

  公开（公告）日：2004-02-05

  A hair coloring composition comprising the following two compositions which are mixed just prior to application to the hair: (a) a composition comprising a water-soluble peroxygen oxidizing agent; and (b) a composition comprising one or more oxidative hair coloring agents selected from the group consisting of an aromatic diamine, an amino phenol, a naphthol, a polyhydric phenol, a catechol and mixtures thereof; wherein the composition comprising one or more oxidative hair coloring agents further comprises al least one water soluble carbonate releasing salts; and optionally a water soluble ammonium salt, is described.

  一种染发组合物，包括以下两种组分，这两种组分在涂抹到头发之前混合： (a) 包括水溶性过氧化氧化剂的组合物；和 (b) 包括从芳香二胺、氨基酚、萘酚、多羟基酚、邻苯二酚和它们的混合物中选择的一种或多种氧化染发剂的组合物；其中包括一种或多种氧化染发剂的组合物进一步包括至少一种水溶性碳酸盐释放盐；和可选地一种水溶性铵盐。
• Enhanced color deposition for hair with sequestering agents
  申请人：Unilever Home & Personal Care USA, Division of Conopco, Inc.

  公开号：US20030135935A1

  公开（公告）日：2003-07-24

  Hair coloring compositions which comprise: (A) non-nitrogenous chelating agents from the group consisting of polyphosphate; phosphonates; hydroxycarboxylates; polyacrylates; zeolite; and mixtures thereof; (B) an oxidative dye primary intermediate; and (C) an oxidative dye coupler; (D) and water are described. The present invention also relates to a method for coloring hair which comprises contacting said hair with a hair coloring composition as described above.

  描述了包括以下成分的染发配方：(A) 来自聚磷酸盐、膦酸盐、羟基羧酸盐、聚丙烯酸盐、沸石及其混合物等组成的非氮螯合剂；(B) 一种氧化染料的主要中间体；和(C) 一种氧化染料偶联剂；(D) 以及水。本发明还涉及一种染发方法，该方法包括将头发与上述描述的染发配方接触。
• Cosmetic composition comprising at least one ingredient chosen from compounds of formula (1) and salts thereof, use thereof as colouring agent, and novel compounds of formulae (IIa), (IIIa), (IVa), (Va), and (VIa), and salts thereof
  申请人：——

  公开号：US20020012683A1

  公开（公告）日：2002-01-31

  A cosmetic composition containing at least one ingredient chosen from compounds of formula (I) and salts thereof: 1 The invention also relates to the use of at least one ingredient chosen from compounds of formula (I) and salts thereof as defined above as a coloring agent, such as in a cosmetic composition, as well as to certain novel furan-naphthoquinone compounds and salts thereof.

  一种化妆品组合物，含有至少一种选自化合物式(I)及其盐的成分：本发明还涉及将至少一种选自化合物式(I)及其盐的成分作为上述定义的着色剂的用途，例如在化妆品组合物中，以及某些新颖的呋喃-萘醌化合物及其盐。
• Facile synthesis of chiral ε-sultams <i>via</i> an organocatalytic aza-Friedel–Crafts reaction
  作者：Zi-Biao Zhao、Lei Shi、Yaming Li、Fan-Jie Meng、Yong-Gui Zhou

  DOI：10.1039/c9ob01158g

  日期：——

  Chiral ε-sultams, with their unique strain cyclic structure, are a type of molecule with important biological activities. A facile enantioselective aza-Friedel-Crafts reaction of seven-membered cyclic N-sulfonylimines with naphthols was developed with a cinchona alkaloid-based bifunctional organocatalyst, giving chiral ε-sultams with an enantiomeric excess of up to 92%.

  具有独特的应变环状结构的手性ε-sultams是具有重要生物活性的一种分子。用金鸡纳生物碱基双功能有机催化剂开发了一种七元环状N-磺酰亚胺类药物与萘酚的简便对映选择性氮杂-弗里德尔-克拉夫茨反应，得到手性ε-杜鹃花，其对映体过量高达92％。
• Ambipolar transistor properties of 2,2′-binaphthosemiquinones
  作者：Toshiki Higashino、Shohei Kumeta、Sumika Tamura、Yoshio Ando、Ken Ohmori、Keisuke Suzuki、Takehiko Mori

  DOI：10.1039/c4tc02467b

  日期：——

  Binaphthosemiquinones having characteristic blue colors owing to the small energy gaps are proved to show ambipolar transistor properties.

  Binaphthosemiquinones由于能隙较小而具有特征性的蓝色，被证明具有双极晶体管特性。