1-chloroacenaphthylene | 65726-91-2

• 分子结构分类: 有机化合物 - 苯类化合物 - 吖萘类
• 英文名称: 1-chloroacenaphthylene
• 英文别名: 1-chloro-acenaphthylene；1-Chlor-acenaphthylen
• CAS: 65726-91-2
• 化学式: C₁₂H₇Cl
• 分子量: 186.641
• InChiKey: IUOZUYUGGOKLEA-UHFFFAOYSA-N

计算性质

• 辛醇/水分配系数(LogP)：
  4
• 重原子数：
  13
• 可旋转键数：
  0
• 环数：
  3.0
• sp3杂化的碳原子比例：
  0.0
• 拓扑面积：
  0
• 氢给体数：
  0
• 氢受体数：
  0

反应信息

• 作为反应物：
  描述：

  1-chloroacenaphthylene 在 sodium dichromate 、 氯 作用下， 以 四氯化碳 、 溶剂黄146 为溶剂， 生成 1,8-萘二甲酸
  参考文献：
  名称：

  Petrenko,G.P.; Usachenko,V.G., Journal of Organic Chemistry USSR (English Translation), 1968, vol. 4, p. 335 - 338

  摘要：

  DOI：
• 作为产物：
  描述：

  1-苊酮 在 五氯化磷 作用下， 生成 1-chloroacenaphthylene
  参考文献：
  名称：

  Banerjee,P.K.; Bhattacharya,A.J., Indian Journal of Chemistry - Section B Organic and Medicinal Chemistry, 1977, vol. 15B, p. 953 - 955

  摘要：

  DOI：

文献信息

• Irreversible E1cb mechanism in the syn eliminations from 1,2-dihalogenoacenaphthenes promoted by potassium t-butoxide in t-butyl alcohol
  作者：Enrico Baciocchi、Renzo Ruzziconi、Giovanni V. Sebastiani

  DOI：10.1039/c39800000807

  日期：——

  The lack of a significant leaving group effect and the preferential departure of the ‘poorer’ leaving group suggest an irreversible E1cb mechanism for the title reactions.

  缺乏显着的离去基团效应和“较贫穷”离去基团的优先离开表明标题反应具有不可逆的E 1 cb机制。
• SOME ACENAPHTHENE COMPOUNDS
  作者：E. H. Charlesworth、H. Campbell、J. J. Conn、C. T. Elston、D. L. Stachiw

  DOI：10.1139/v57-052

  日期：1957.4.1

  A new geometric isomer of 1,2-dichloroacenaphthene has been isolated among the reaction products of acenaphthylene and hypochlorous acid. Some new derivatives of acenaphthenone and acenaphthenol are reported.

  1,2-二氯蒽并[cd]蒽的一种新的几何异构体已经在蒽烯和次氯酸反应产物中被分离出来。报道了一些蒽酮和蒽醇的新衍生物。
• Curable resin composition
  申请人：Kawabe Masanao

  公开号：US20070129502A1

  公开（公告）日：2007-06-07

  Provided is curable resin composition which gives a cured article excellent in chemical resistance, dielectric properties, low water-absorption, heat resistance, flame retardance, and mechanical properties and which is usable in applications such as dielectric materials, insulating materials, heat-resistant materials, and structural materials. The curable resin composition includes a component (A) which is a polyphenylene ether oligomer having a number-average molecular weight of 700 to 4,000 and having a vinyl group at both end and a component (B) which is a solvent-soluble polyfunctional vinylaromatic copolymer which has structural units derived from monomers including a divinylaromatic compound (a) and an ethylvinylaromatic compound (b) and in which the content of repeating units derived from the divinylaromatic compound (a) is 20 mol % or higher, the ratio of the amount (wt. %) of the component (A) to that (wt. %) of the component (B) being (20 to 98):(2 to 80). The composition can further contain a layered silicate, a halogenated flame retardant, etc.

  提供了一种可治愈的树脂组合物，其使得固化后的制品具有出色的化学耐性、介电性能、低吸水性、耐热性、阻燃性和机械性能，并可用于介电材料、绝缘材料、耐热材料和结构材料等应用。该可治愈的树脂组合物包括以下组分：(A)是一种聚苯醚寡聚体，其具有700至4,000的数量平均分子量，并在两端具有乙烯基；(B)是一种可溶于溶剂的多功能乙烯基芳香族共聚物，其具有从单体中衍生出的结构单元，包括一种二乙烯基芳香族化合物(a)和一种乙基乙烯基芳香族化合物(b)，其中重复单元中来自二乙烯基芳香族化合物(a)的含量为20摩尔%或更高，组分(A)与组分(B)的重量比为(20至98)∶(2至80)。该组合物还可以进一步包含层状硅酸盐、卤素阻燃剂等。
• Resin composition, prepreg, resin-added film, resin-added metal foil, metal-clad layered plate, and wiring plate
  申请人：PANASONIC INTELLECTUAL PROPERTY MANAGEMENT CO., LTD.

  公开号：US11242425B2

  公开（公告）日：2022-02-08

  A resin composition is provided and contains a compound (A) having at least one group represented by the following Formula (1) in a molecule, a crosslinking type curing agent (B), and an azo compound (C) that has an azo group in a molecule and has no heteroatom other than a nitrogen atom constituting the azo group. In Formula (1), n represents 0 to 10, Z represents an arylene group, and R1 to R3 each independently represent a hydrogen atom or an alkyl group.

  本发明提供了一种树脂组合物，其中包含分子中至少含有一个下式 (1) 所代表基团的化合物 (A)、交联型固化剂 (B) 以及分子中含有偶氮基团且除构成偶氮基团的氮原子外没有杂原子的偶氮化合物 (C)。 式（1）中，n 代表 0 至 10，Z 代表芳烯基，R1 至 R3 各自独立地代表氢原子或烷基。
• Anti-reflection coating forming composition
  申请人：——

  公开号：US20020086934A1

  公开（公告）日：2002-07-04

  An anti-reflection coating-forming composition is provided. This composition includes a polymer and a solvent. The polymer has a structural unit represented by the formula (1): 1 wherein R 1 is a monovalent atom other than a hydrogen atom or a monovalent group, and n is an integer of 0-4, provided that when n is an integer of 2-4, a plural number of R 1 's are the same or different; R 2 and R 3 are each a monovalent atom or group; and X is a bivalent group. The anti-reflection coating formed from this composition has a high antireflective effect, does not generate intermixing with a resist film, and enables a good resist pattern profile excellent in resolution and precision in cooperation with a positive or negative resist.

  提供了一种抗反射涂层形成组合物。这种组合物包括一种聚合物和一种溶剂。聚合物具有由式（1）表示的结构单元： 1 其中 R 1 是氢原子或一价基团以外的一价原子，n 是 0-4 的整数，但当 n 是 2-4 的整数时，R 1 的复数相同或不同；R 2 和 R 3 均为一价原子或基团；X 为二价基团。由这种组合物形成的抗反射涂层具有很高的抗反射效果，不会与抗蚀剂薄膜产生混杂，并且在与正极或负极抗蚀剂配合使用时，可以形成分辨率和精度极佳的抗蚀图案轮廓。