Diazene, bis(2,4,6-trinitrophenyl)-, (1E)- | 52253-67-5

• 分子结构分类: 有机化合物 - 有机杂环化合物 - 偶氮苯
• 英文名称: Diazene, bis(2,4,6-trinitrophenyl)-, (1E)-
• 英文别名: bis(2,4,6-trinitrophenyl)diazene；2,2',4,4',6,6'-hexanitroazobenzene；2.2'.4.4'.6.6'-Hexanitroazobenzol
• CAS: 52253-67-5
• 化学式: C₁₂H₄N₈O₁₂
• 分子量: 452.21
• InChiKey: PSDIVOYKWCKHLG-BUHFOSPRSA-N

计算性质

• 辛醇/水分配系数(LogP)：
  3.55
• 重原子数：
  32.0
• 可旋转键数：
  8.0
• 环数：
  2.0
• sp3杂化的碳原子比例：
  0.0
• 拓扑面积：
  283.56
• 氢给体数：
  0.0
• 氢受体数：
  14.0

反应信息

• 作为产物：
  描述：

  2,4,6-三硝基氯苯 在 potassium acetate 、 肼 、 盐酸 、 硝酸 作用下， 以 乙醇 为溶剂， 生成 Diazene, bis(2,4,6-trinitrophenyl)-, (1E)-
  参考文献：
  名称：

  Form III of 2,2′,4,4′,6,6′-hexanitroazobenzene (HNAB-III)

  摘要：

  The crystal structure of form III of the title compound, HNAB [systematic name: bis(2,4,6-trinitrophenyl)diazene], C12H4N8O12, has finally been solved as a pseudo-merohedral twin (monoclinic space group P2(1), rather than the orthorhombic space group C222(1) suggested by diffraction symmetry) using a dual space recycling method. The significant differences in the room-temperature densities of the three crystalline forms allow examination of molecular differences due to packing arrangements. An interesting relationship with the stilbene analog, HNS, is discussed. Interatomic separations are compared with other explosives and/or nitro-containing compounds.

  DOI：

  10.1107/s0108270105000569

文献信息

• Perforating systems with insensitive high explosive
  申请人：Halliburton Energy Services, Inc.

  公开号：US10746002B2

  公开（公告）日：2020-08-18

  The disclosure relates to perforating systems for perforating the casing of a wellbore. The perforating systems contain insensitive high explosives. The disclosure also relates to shaped charges containing insensitive high explosives for use in such perforating systems. The disclosure further relates to methods of using such perforating systems to perforate the casing of a wellbore.

  本公开涉及用于穿孔井筒套管的穿孔系统。穿孔系统含有不敏感的烈性炸药。本公开还涉及用于此类穿孔系统的含有不敏感烈性炸药的定型装药。本公开还涉及使用这种穿孔系统对井筒套管进行穿孔的方法。
• PERFORATING SYSTEMS WITH INSENSITIVE HIGH EXPLOSIVE
  申请人：Halliburton Energy Services, Inc.

  公开号：US20170241245A1

  公开（公告）日：2017-08-24

  The disclosure relates to perforating systems for perforating the casing of a wellbore. The perforating systems contain insensitive high explosives. The disclosure also relates to shaped charges containing insensitive high explosives for use in such perforating systems. The disclosure further relates to methods of using such perforating systems to perforate the casing of a wellbore.
• US4316412A
  申请人：——

  公开号：US4316412A

  公开（公告）日：1982-02-23
• US5370845A
  申请人：——

  公开号：US5370845A

  公开（公告）日：1994-12-06
• US5516970A
  申请人：——

  公开号：US5516970A

  公开（公告）日：1996-05-14