Copper(I) O,O-dimethylphosphorodithioate | 23859-09-8

• 分子结构分类: 有机化合物 - 有机酸及其衍生物 - 有机二硫代磷酸及其衍生物
• 英文名称: Copper(I) O,O-dimethylphosphorodithioate
• 英文别名: (O,O-Dimethyl phosphorodithioato)copper；copper(1+);dimethoxy-sulfanylidene-sulfido-λ5-phosphane
• CAS: 23859-09-8
• 化学式: C₂H₆O₂PS₂*Cu
• 分子量: 220.72
• InChiKey: RKJBIVDGDKSIRT-UHFFFAOYSA-M

计算性质

• 辛醇/水分配系数(LogP)：
  1.05
• 重原子数：
  8
• 可旋转键数：
  2
• 环数：
  0.0
• sp3杂化的碳原子比例：
  1.0
• 拓扑面积：
  51.6
• 氢给体数：
  0
• 氢受体数：
  4

反应信息

• 作为反应物：
  描述：

  Copper(I) O,O-dimethylphosphorodithioate 、 potassium thiomolybdate 在 Et₄NBr 作用下， 以 N,N-二甲基甲酰胺 为溶剂， 以63%的产率得到
  参考文献：
  名称：

  Construction of two novel 2D layer Mo(W)/Cu/S polymers using bidentate thiolato ligands as linkers

  摘要：

  Reactions of thiomolybdate or thiotungstate [MOS3](2-) (M = Mo, W) with 3 equiv. of CuS2P(OMe)(2) led to the formation of two novel Mo(W)/Cu/S polymers [Et4N][MOS3Cu3} {S2P(OMe) (1, M = Mo; 2, M = W). Single-crystal X-ray diffraction studies reveal that 1 and 2 are the first examples that containing anionic 2D (6,3) net with nest-shaped [MOS3Cu3 (.) S2P(OMe)(2)] clusters as 3-connecting nodes and tridentate [S2P(OMe)(2)](-) ligands as linkers. Both 1 and 2 crystallize in a noncentrosymmetric space group and the former polymer shows good second-order NLO performance. (c) 2005 Elsevier B.V. All rights reserved.

  DOI：

  10.1016/j.inoche.2005.10.010
• 作为产物：
  描述：

  tetrakis(actonitrile)copper(I) hexafluorophosphate 、 二甲基二硫代磷酸酯 以 甲醇 、 乙腈 为溶剂， 生成 Copper(I) O,O-dimethylphosphorodithioate
  参考文献：
  名称：

  Construction of three novel luminescent polymers containing {CuS2P(OR)2} (R=Me, Et) building blocks linked by 4,4′-bipyridine ligands

  摘要：

  The self-assembly reactions of the polymers CuSP(OMe)(2) or CuS2P(OEt)(2) with 4,4'-bipyridine(4,4'-bipy) under mild conditions gave a novel two-dimensional network {[CuS2P(OMe)(2)](4,4'-bipy)(0.5)}(n) (1) and two novel polymeric chains {[CuS2P(OMe)(2)](4)(4,4'-bipy)}(n) (2) and {[CuS2P(OEt)(2)](4,4'-bipy)(0.5)}(n) (3). Complex 1 represents the first layered structure incorporating intriguing linear 1CuS(2)P(OMe)(2))(n) building blocks in the CuDDP (DDP = general dialkyl dithiophosphate) system. Complex 2 is the first one-dimensional polymer with {CuS2P(OMe)(2)}(4) fragments connected by 4,4'-bipy ligands while 3 is also the first hanging ladder-like chain with 4,4'-bipy ligands as cross rungs in this system. Complexes 1-3 exhibit strong photoluminescence with the peak maximum at 681, 578 and 644 nm respectively. (c) 2005 Elsevier B.V. All rights reserved.

  DOI：

  10.1016/j.molstruc.2005.09.002

文献信息

• MELNIK, YA. I.;MAKOTA, I. P., BECTH. LVOV YH-TA. CEP. XIM., 1985, N 26, 60-63
  作者：MELNIK, YA. I.、MAKOTA, I. P.

  DOI：——

  日期：——