Methyl-di-[1]naphthyl-arsin | 53720-35-7

• 分子结构分类: 有机化合物 - 苯类化合物 - 萘
• 英文名称: Methyl-di-[1]naphthyl-arsin
• 英文别名: di(1-naphthyl)methylarsine；methyl-di-[1]naphthyl-arsine；Methyl-di-α-naphthyl-arsin；Methyl(dinaphthalen-1-yl)arsane
• CAS: 53720-35-7
• 化学式: C₂₁H₁₇As
• 分子量: 344.288
• InChiKey: KWVAQMKPPAQJNZ-UHFFFAOYSA-N

计算性质

• 辛醇/水分配系数(LogP)：
  4.23
• 重原子数：
  22
• 可旋转键数：
  2
• 环数：
  4.0
• sp3杂化的碳原子比例：
  0.05
• 拓扑面积：
  0
• 氢给体数：
  0
• 氢受体数：
  0

反应信息

• 作为反应物：
  描述：

  Methyl-di-[1]naphthyl-arsin 以 乙醇 、 乙腈 为溶剂， 生成
  参考文献：
  名称：

  Naikar, S. B.; Gowda, N. M. Nanje; Reddy, G. K. N., Indian Journal of Chemistry, Section A: Inorganic, Physical, Theoretical and Analytical

  摘要：

  DOI：
• 作为产物：
  描述：

  甲基碘化镁 、 tetra-[1]naphthyl-diarsoxane 在 乙醚 作用下， 生成 Methyl-di-[1]naphthyl-arsin
  参考文献：
  名称：

  Matsumiya; Nakai, Memoirs of the College of Science, Kyoto Imperial University, vol. 8, p. 314

  摘要：

  DOI：

文献信息

• Naikar, S. B.; Nanje Gowda, N. M.; Reddy, G. K. N., Indian Journal of Chemistry, Section A: Inorganic, Physical, Theoretical and Analytical, 1984, vol. 23, # 2, p. 133 - 136
  作者：Naikar, S. B.、Nanje Gowda, N. M.、Reddy, G. K. N.

  DOI：——

  日期：——
• Nagasundara, K. R.; Nanje Gowda, N. M.; Reddy, G. K. N., Indian Journal of Chemistry, Section A: Inorganic, Physical, Theoretical and Analytical, 1989, vol. 28, # 11, p. 1001 - 1003
  作者：Nagasundara, K. R.、Nanje Gowda, N. M.、Reddy, G. K. N.

  DOI：——

  日期：——
• Synthesis, spectroscopy, structure and photophysical properties of dinaphthylmethylarsine complexes of palladium(II) and platinum(II)
  作者：Prasad P. Phadnis、Vimal K. Jain、Thilo Schurr、Axel Klein、Falk Lissner、Thomas Schleid、Wolfgang Kaim

  DOI：10.1016/j.ica.2005.03.026

  日期：2005.6

  Dinaphthylmethylarsine complexes of palladium(II) and platinum(II) with the formulae [MX2L2] (M = Pd, Pt; L = di(I-naphthyl)methylarsine = NaP2AsMe and X = Cl, Br, I), [M2Cl2(mu-Cl)(2)L-2], [PdCl(S2CNEt2)L], [Pd2Cl2(mu-OAc)(2)L-2] and [MCl2(PR3)L] (PR3 = PEt3, PPr3, PBu3, PMePh2) have been prepared. These complexes have been characterized by elemental analyses, IR, Raman, NMR (H-1, C-13, P-31) and UV-vis spectroscopy. The stereochemistry of the complexes has been deduced from the spectroscopic data. The crystal structures of trans-[PdCl2(PEt3)(NaP2AsMe)] and of [Pd(S2CNEt2)(2)], a follow-up product, were determined. The UV-vis spectra of [MX2L2] complexes show a red shift on going from X = Cl to X = L The complexes [PdX2L2] and [PtX2L2] are strongly luminescent in fluid solution and in the solid at ambient temperature. (c) 2005 Elsevier B.V. All rights reserved.
• Matsumiya; Nakai, vol. 8, p. 315
  作者：Matsumiya、Nakai

  DOI：——

  日期：——