申请人:BASF SE
公开号:US20200407508A1
公开(公告)日:2020-12-31
A method for producing films, fibers, and moldings of a polybenzazole polymer (P) by reacting at temperatures of 0 to 120° C. a mixture including (a) aromatic dicarboxylic compound(s) (I):
wherein Ar
1
is optionally substituted phenylene, naphthalenediyl, anthracenediyl, biphenyldiyl, diphenylmethanediyl, diphenyl ether diyl, diphenyl thio ether diyl, diphenyl sulfone diyl, benzophenonediyl, pyridinediyl, pyrimidinediyl, furandiyl, or thiophenediyl, substituents being —F, —Cl, —Br, —OR
1
, and —C
1
-C
10
-alkyl, R
1
being —H or —C
1
-C
10
-alkyl; X
1
and X
2
are independently-OR
2
, —F, —Cl, or —Br, R
2
being —H, —C
1
-C
10
-alkyl, —C
1
-C
10
-alkenyl or a repeating unit (a):
wherein m is a natural number from 1 to 50, and R
3
is —H, C
1
-C
10
-alkyl, or C
1
-C
10
-alkenyl; (b) aromatic diamino compound(s) of formula (IIa), (IIb), (IIc) and/or (IId); (c) at least one ionic liquid (IL), to obtain a product, processing the product at temperatures 0 to 100° C. and heating of the articles obtained at temperatures of 250 to 500° C.