3,4,8-Trimethyl-[1,10]phenanthrolin | 3248-06-4

• 分子结构分类: 有机化合物 - 有机杂环化合物 - 菲咯啉
• 英文名称: 3,4,8-Trimethyl-[1,10]phenanthrolin
• 英文别名: 3,4,8-Trimethyl-1,10-phenanthroline
• CAS: 3248-06-4
• 化学式: C₁₅H₁₄N₂
• 分子量: 222.29
• InChiKey: QVRIPXJLPIZPSH-UHFFFAOYSA-N

物化性质

• 熔点：
  211-212 °C
• 沸点：
  414.8±40.0 °C(Predicted)
• 密度：
  1.152±0.06 g/cm3(Predicted)

计算性质

• 辛醇/水分配系数(LogP)：
  3.6
• 重原子数：
  17
• 可旋转键数：
  0
• 环数：
  3.0
• sp3杂化的碳原子比例：
  0.2
• 拓扑面积：
  25.8
• 氢给体数：
  0
• 氢受体数：
  2

反应信息

• 作为产物：
  描述：

  4-羟基-3-甲基-2-丁酮 在 arsenic(V) oxide 、 乙醇 、 硫酸 、 tin(ll) chloride 作用下， 反应 2.0h， 生成 3,4,8-Trimethyl-[1,10]phenanthrolin
  参考文献：
  名称：

  Substituted 1,10-Phenanthrolines. III.^1,2 Polymethyl Phenanthrolines Related to 3,4-Dimethyl-1,10-phenanthroline

  摘要：

  DOI：

  10.1021/ja01173a085

文献信息

• REACTIVE COMPOUND
  申请人：SUMITOMO CHEMICAL COMPANY, LIMITED

  公开号：US20150353583A1

  公开（公告）日：2015-12-10

  A reactive compound represented by the following formula (I): [In the formula (I), Z represents a divalent group. A plurality of Y may be the same or different, and represent a monovalent boronate residue having at least one hydroxyl group, Ar 1 and Ar 2 may be the same or different, and represent a trivalent aromatic hydrocarbon group or a trivalent heterocyclic group.].

  由以下公式（I）表示的一种反应性化合物： [在公式（I）中，Z代表二价基团。多个Y可以相同也可以不同，并表示至少有一个羟基的一价硼酸酯残基，Ar1和Ar2可以相同也可以不同，并表示三价芳香烃基团或三价杂环基团。]。
• Polymer complex compound and polymer light emitting device using the same
  申请人：Mikami Satoshi

  公开号：US20070040164A1

  公开（公告）日：2007-02-22

  A polymer complex compound comprising a repeating unit of the following formula (1) and a metal complex structure showing light emission from triplet excited state, having visible light emission in the solid state, and having a polystyrene reduced number-average molecular weight of 10 3 to 10 8 : (wherein, Ring P and Ring Q each independently represent an aromatic ring, but Ring P may be either existent or non-existent. When Ring P is existent, two connecting bonds respectively are on Ring P and/or Ring Q, and when Ring P is non-existent, two connecting bonds respectively are on 5 membered ring containing Y, and/or Ring Q. Y represents —O—, —S— and the like).
• Polymer light-emitting material and polymer light-emitting device
  申请人：Nakatani Tomoya

  公开号：US20070051922A1

  公开（公告）日：2007-03-08

  A polymer light emitting material which contains a polymer compound comprising a repeating unit of the following formula (1) or (2) and having a polystyrene-reduced number-average molecular weight of 10 3 to 10 8 , and which exhibits light emission from the triplet excited state. [wherein Ar 1 and Ar 2 each independently represent a trivalent aromatic hydrocarbon group or a trivalent heterocyclic group. X 1 and X 2 each independently represent O, S, C(═O), S(═O), SO 2 , C(R 1 )(R 2 ), Si(R 3 )(R 4 ), N(R 5 ), B(R 6 ), P(R 7 ) or P(═O)(R 8 ). X 1 and Ar 2 bond to adjacent carbon atoms in the aromatic ring of Ar 1 ; and X 2 and Ar 1 bond to adjacent carbon atoms in the aromatic ring of Ar 2 ]; [wherein Ar 3 and Ar 4 each independently represent a trivalent aromatic hydrocarbon group or a trivalent heterocyclic group. X 3 and X 4 each independently represent N, B, P, C(R 9 ) or Si(R 10 ). X 3 and Ar 4 bond to adjacent carbon atoms in the aromatic ring of Ar 3 ; and X 4 and Ar 3 bond to adjacent carbon atoms in the aromatic ring of Ar 4 ].
• Composition and polymer light-emitting device
  申请人：Tsubata Yoshiaki

  公开号：US20070103059A1

  公开（公告）日：2007-05-10

  A composition comprising a polymer compound having a polystyrene reduced number-average molecular weight of 10 3 -10 8 , and a compound showing light-emission from triplet excited state, and said polymer compound comprises a repeating unit of the following formula (1); and a polymer complex compound having visible light-emission in the solid state, and including a repeating unit of the above formula (1), a repeating unit selected from the above formulas (12) and (13), and a metal complex structure showing light-emission from triplet excited state: wherein, Ring P and Ring Q represent an aromatic ring, Y represents —O—, —S—, etc.; Ar 15 and Ar 16 represent a trivalent aromatic hydrocarbon group or a trivalent heterocyclic group; R 40 represents an alkyl group, etc.; X represents a single bond, etc.; Ar 6 , Ar 7 , Ar 8 , and Ar 9 represent an arylene group, etc.; Ar 10 , Ar 11 , and Ar 12 represent aryl group, etc.; and x and y each independently represent 0 or 1, and 0≦x+y≦1.
• Polymer Compound, Polymer Thin Film and Polymer Thin Film Device Using the Same
  申请人：Ueda Masato

  公开号：US20080003422A1

  公开（公告）日：2008-01-03

  A polymer compound comprising a repeating unit of the following formula (1) and a repeating unit of the following formula (2) and having a polystyrene-reduced number-average molecular weight of 10 3 to 10 8 : (wherein, Ar 1 and Ar 2 represent each independently a tri-valent aromatic hydrocarbon group or a tri-valent heterocyclic group, X 1 and X 2 represent each independently O, S, C(═O), S(═O), SO 2 or the like, and X 1 and X 2 are not identical. Y represents O, S, and R 9 represents a halogen atom, alkyl group, alkyloxy group or the like. m represents 0 or 1, and n represents an integer from 1 to 6. o represents an integer from 1 to 6, and p represents an integer from 0 to 2.).