magnesium(VI) bis(2-oxidoethyl)amide | 263407-29-0

• 分子结构分类: 有机化合物 - 有机金属化合物
• 英文名称: magnesium(VI) bis(2-oxidoethyl)amide
• CAS: 263407-29-0
• 化学式: C₈H₂₀MgN₂O₄
• 分子量: 232.563
• InChiKey: NIPTVESWTAJSOO-UHFFFAOYSA-N

计算性质

• 辛醇/水分配系数(LogP)：
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• 重原子数：
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• 可旋转键数：
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• 环数：
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• sp3杂化的碳原子比例：
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• 拓扑面积：
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• 氢给体数：
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• 氢受体数：
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反应信息

• 作为反应物：
  描述：

  magnesium(VI) bis(2-oxidoethyl)amide 、 aluminum isopropoxide 以 苯 为溶剂， 以65%的产率得到
  参考文献：
  名称：

  Synthesis and characterization of homo- and heterobimetallic diethanolaminates of alkaline earth metals

  摘要：

  Heteroleptic heterobimetallic isopropoxide diethanolaminate derivatives of the type {Al(OPir)(2)}(2){M[ (OC2H4)(2)NH](2)} (M = Mg, Ca, Sr Ba) have been prepared by the reactions of homometallic precursor derivatives H2M{ (OC2H4)(2)NH}(2) (1a-1d) with Al(OPri)(3) in 1:2 molar ratio in benzene. The insoluble homometallic precursor derivatives (la-ld) have been synthesized by two alternative routes: (1) reactions of M(OPri)(2) with diethanolamine in 1:2 molar ratio; and (2) reactions of the metals Mg, Ca, Sr and Ba with diethanolamine in 1:2 molar ratio in refluxing toluene. The new homo- and heterobimetallic diethanolaminate derivatives have been characterized by elemental analysis, molecular weight measurements and spectroscopic [IR, NMR (H-1,C-13, Al-27)] studies. (C) 2000 Elsevier Science Ltd All rights reserved.

  DOI：

  10.1016/s0277-5387(99)00327-7