decyldimethylsilylacetylene | 1135021-59-8

• 分子结构分类: 有机化合物 - 有机金属化合物 - 有机类金属化合物
• 英文名称: decyldimethylsilylacetylene
• 英文别名: decyldimethylethynylsilane；Decyldimethylethynylsilane；decyl-ethynyl-dimethylsilane
• CAS: 1135021-59-8
• 化学式: C₁₄H₂₈Si
• 分子量: 224.462
• InChiKey: SLMGXHDNFTYHCF-UHFFFAOYSA-N

计算性质

• 辛醇/水分配系数(LogP)：
  5.01
• 重原子数：
  15
• 可旋转键数：
  10
• 环数：
  0.0
• sp3杂化的碳原子比例：
  0.86
• 拓扑面积：
  0
• 氢给体数：
  0
• 氢受体数：
  0

反应信息

• 作为反应物：
  描述：

  decyldimethylsilylacetylene 、 还原黄G 在 正丁基锂 作用下， 以 四氢呋喃 、 正己烷 为溶剂， 反应 22.58h， 以15%的产率得到8,16-bis(decyldimethylsilylethvnyl)flavanthrene
  参考文献：
  名称：

  [EN] FLAVANTHRENE DERIVATIVES AND THEIR USE AS ORGANIC SEMICONDUCTORS
  [FR] DÉRIVÉS DE FLAVANTHRÈNE ET LEUR UTILISATION EN TANT QUE SEMI-CONDUCTEURS ORGANIQUES

  摘要：

  这项发明涉及公式（I）的黄蒽衍生物，其中各个基团的含义如申请中所定义，它们的制备方法，它们作为有机电子（OE）器件中的半导体的用途，以及包括它们的OE器件。

  公开号：

  WO2012100900A1
• 作为产物：
  描述：

  癸基溴 在 四氯化碳 、 magnesium 、 palladium dichloride 作用下， 以 四氢呋喃 为溶剂， 反应 3.25h， 生成 decyldimethylsilylacetylene
  参考文献：
  名称：

  Trialkylsilylethynyl-substituted triphenylenes and hexabenzocoronenes: highly soluble liquid crystalline materials and their hole transport abilities

  摘要：

  Four triphenylene (TP) and four hexa-peri-hexabenzocoronene (HBC) derivatives with trialkylsilylethynyl groups were prepared and characterized by differential scanning calorimetry, polarizing optical microscopy, and X-ray diffraction measurements. All compounds were highly soluble in less-polar organic solvents and exhibited a columnar phase, Col(h) or Col(r) for the TPs, and Col(h) for the HBCs. The hole transport ability in the HBCs' columnar phase, 0.4-1.5x10(-3) cm(2) V-1 s(-1) at 40-180 degrees C, and its temperature dependence were determined by the time-of-flight method using a solution technique. (C) 2015 Elsevier Ltd. All rights reserved.

  DOI：

  10.1016/j.tet.2015.05.071

文献信息

• FLAVANTHRENE DERIVATIVES AND THEIR USE AS ORGANIC SEMICONDUCTORS
  申请人：Wang Changsheng

  公开号：US20130306914A1

  公开（公告）日：2013-11-21

  The invention relates to benzo[h]benz[5,6]acridino[2,1,9,8-klmna]acridines, methods of their preparation, their use as semiconductors in organic electronic (OE) devices, and to OE devices comprising them.

  本发明涉及苯并[h]苯[5,6]螺[2,1,9,8-klmna]螺吩，它们的制备方法，它们作为有机电子(OE)器件中的半导体的用途，以及包含它们的OE器件。
• Flavanthrene derivatives and their use as organic semiconductors
  申请人：Wang Changsheng

  公开号：US09373801B2

  公开（公告）日：2016-06-21

  The invention relates to benzo[h]benz[5,6]acridino[2,1,9,8-klmna]acridines, methods of their preparation, their use as semiconductors in organic electronic (OE) devices, and to OE devices comprising them.

  本发明涉及苯并[h]苯[5,6]蒽[2,1,9,8-klmna]蒽衍生物、其制备方法、其在有机电子（OE）器件中作为半导体的应用，以及包含它们的OE器件。
• [EN] FLAVANTHRENE DERIVATIVES AND THEIR USE AS ORGANIC SEMICONDUCTORS<br/>[FR] DÉRIVÉS DE FLAVANTHRÈNE ET LEUR UTILISATION EN TANT QUE SEMI-CONDUCTEURS ORGANIQUES
  申请人：MERCK PATENT GMBH

  公开号：WO2012100900A1

  公开（公告）日：2012-08-02

  The invention relates to flavanthrene derivatives of formula (I) wherein the individual groups have the meanings as defined in the application, methods of their preparation, their use as semiconductors in organic electronic (OE) devices, and to OE devices comprising them.

  这项发明涉及公式（I）的黄蒽衍生物，其中各个基团的含义如申请中所定义，它们的制备方法，它们作为有机电子（OE）器件中的半导体的用途，以及包括它们的OE器件。
• Trialkylsilylethynyl-substituted triphenylenes and hexabenzocoronenes: highly soluble liquid crystalline materials and their hole transport abilities
  作者：Takuji Hirose、Yutaro Miyazaki、Mizuki Watabe、Sho Akimoto、Tatsuya Tachikawa、Koichi Kodama、Mikio Yasutake

  DOI：10.1016/j.tet.2015.05.071

  日期：2015.7

  Four triphenylene (TP) and four hexa-peri-hexabenzocoronene (HBC) derivatives with trialkylsilylethynyl groups were prepared and characterized by differential scanning calorimetry, polarizing optical microscopy, and X-ray diffraction measurements. All compounds were highly soluble in less-polar organic solvents and exhibited a columnar phase, Col(h) or Col(r) for the TPs, and Col(h) for the HBCs. The hole transport ability in the HBCs' columnar phase, 0.4-1.5x10(-3) cm(2) V-1 s(-1) at 40-180 degrees C, and its temperature dependence were determined by the time-of-flight method using a solution technique. (C) 2015 Elsevier Ltd. All rights reserved.