3,3'-(1,4-diazepane-1,4-diyl)bis[1-(4-ethylpiperazine-1-yl)propan-2-ol] | 1430236-09-1

• 分子结构分类: 有机化合物 - 有机杂环化合物 - 二氮杂卓
• 英文名称: 3,3'-(1,4-diazepane-1,4-diyl)bis[1-(4-ethylpiperazine-1-yl)propan-2-ol]
• 英文别名: 1-(4-Ethylpiperazin-1-yl)-3-[4-[3-(4-ethylpiperazin-1-yl)-2-hydroxypropyl]-1,4-diazepan-1-yl]propan-2-ol；1-(4-ethylpiperazin-1-yl)-3-[4-[3-(4-ethylpiperazin-1-yl)-2-hydroxypropyl]-1,4-diazepan-1-yl]propan-2-ol
• CAS: 1430236-09-1
• 化学式: C₂₃H₄₈N₆O₂
• 分子量: 440.673
• InChiKey: NYFFLGBWAMLHTA-UHFFFAOYSA-N

计算性质

• 辛醇/水分配系数(LogP)：
  -0.4
• 重原子数：
  31
• 可旋转键数：
  10
• 环数：
  3.0
• sp3杂化的碳原子比例：
  1.0
• 拓扑面积：
  59.9
• 氢给体数：
  2
• 氢受体数：
  8

反应信息

• 作为反应物：
  描述：

  tetrakis(acetonitrile)copper(I) perchlorate 、 3,3'-(1,4-diazepane-1,4-diyl)bis[1-(4-ethylpiperazine-1-yl)propan-2-ol] 以 乙腈 为溶剂， 生成
  参考文献：
  名称：

  Krupadam, Reddithota J.; Nagababu, Penumaka; Paul, Perala Sudheer, Indian Journal of Chemistry - Section B Organic and Medicinal Chemistry, 2021, vol. 60, # 5, p. 742 - 745

  摘要：

  DOI：
• 作为产物：
  描述：

  高哌嗪 反应 114.0h， 生成 3,3'-(1,4-diazepane-1,4-diyl)bis[1-(4-ethylpiperazine-1-yl)propan-2-ol]
  参考文献：
  名称：

  Krupadam, Reddithota J.; Nagababu, Penumaka; Paul, Perala Sudheer, Indian Journal of Chemistry - Section B Organic and Medicinal Chemistry, 2021, vol. 60, # 5, p. 742 - 745

  摘要：

  DOI：

文献信息

• Efficient Oxidation of Methane to Methanol by Dioxygen Mediated by Tricopper Clusters
  作者：Sunney I. Chan、Yu-Jhang Lu、Penumaka Nagababu、Suman Maji、Mu-Cheng Hung、Marianne M. Lee、I-Jui Hsu、Pham Dinh Minh、Jeff C.-H. Lai、Kok Yoah Ng、Sridevi Ramalingam、Steve S.-F. Yu、Michael K. Chan

  DOI：10.1002/anie.201209846

  日期：2013.3.25

  developing catalysts to harness the abundant natural supply of methane for various industrial applications. Two tricopper complexes capable of mediating efficient oxidation of methane to methanol under ambient conditions were tested: a biomimetic tricopper complex (see figure) and a tricopper‐peptide species derived from the particulate methane monooxygenase (pMMO) protein.

  吨铜的乐趣：开发催化剂以利用丰富的自然甲烷供应用于各种工业应用，这引起了人们的极大兴趣。测试了两种能够在环境条件下将甲烷有效氧化为甲醇的三铜配合物：仿生的三铜配合物（见图）和衍生自颗粒甲烷单加氧酶（pMMO）蛋白的三铜肽物种。
• Molecular Catalysts Capable of Catalyzing Oxidation of Hydrocarbons and Method for Oxidizing Hydrocarbons
  申请人：Academia Sinica

  公开号：US20150099876A1

  公开（公告）日：2015-04-09

  This invention relates to molecular catalysts and chemical reactions utilizing the same, and particularly to molecular catalysts for efficient catalytic oxidation of hydrocarbons, such as hydrocarbons from natural gas. The molecular catalytic platform provided herein is capable of the facile oxidation of hydrocarbons, for example, under ambient conditions such as near room temperature and atmospheric pressure.

  本发明涉及分子催化剂和利用其进行化学反应，特别是用于高效催化氧化碳氢化合物的分子催化剂，例如来自天然气的碳氢化合物。本文提供的分子催化平台能够轻松氧化碳氢化合物，例如在常温和大气压等环境条件下。
• Molecular catalysts capable of catalyzing oxidation of hydrocarbons and method for oxidizing hydrocarbons
  申请人：Academia Sinica

  公开号：US10005746B2

  公开（公告）日：2018-06-26

  This invention relates to molecular catalysts and chemical reactions utilizing the same, and particularly to molecular catalysts for efficient catalytic oxidation of hydrocarbons, such as hydrocarbons from natural gas. The molecular catalytic platform provided herein is capable of the facile oxidation of hydrocarbons, for example, under ambient conditions such as near room temperature and atmospheric pressure.

  本发明涉及分子催化剂和利用分子催化剂进行的化学反应，特别是涉及高效催化氧化碳氢化合物（如天然气中的碳氢化合物）的分子催化剂。本发明提供的分子催化平台能够方便地氧化碳氢化合物，例如在接近室温和大气压的环境条件下。
• MOLECULAR CATALYSTS CAPABLE OF CATALYZING OXIDATION OF HYDROCARBONS AND METHOD FOR OXIDIZING HYDROCARBONS
  申请人：Academia Sinica

  公开号：EP3052436A1

  公开（公告）日：2016-08-10
• Krupadam, Reddithota J.; Nagababu, Penumaka; Paul, Perala Sudheer, Indian Journal of Chemistry - Section B Organic and Medicinal Chemistry, 2021, vol. 60, # 5, p. 742 - 745
  作者：Krupadam, Reddithota J.、Nagababu, Penumaka、Paul, Perala Sudheer、Reddy, Thatiparthi Byragi

  DOI：——

  日期：——