biphenyl-2,3-dicarboxylic acid anhydride | 954-06-3

• 分子结构分类: 有机化合物 - 有机杂环化合物 - 苯并呋喃
• 英文名称: biphenyl-2,3-dicarboxylic acid anhydride
• 英文别名: 3-phenyl-phthalic acid-anhydride；3-Phenyl-phthalsaeure-anhydrid；3-phenylphthalic anhydride；biphenyl dicarboxylic acid anhydride；4-Phenyl-2-benzofuran-1,3-dione
• CAS: 954-06-3
• 化学式: C₁₄H₈O₃
• 分子量: 224.216
• InChiKey: VETOZLDSVKEYKO-UHFFFAOYSA-N

计算性质

• 辛醇/水分配系数(LogP)：
  2.9
• 重原子数：
  17
• 可旋转键数：
  1
• 环数：
  3.0
• sp3杂化的碳原子比例：
  0.0
• 拓扑面积：
  43.4
• 氢给体数：
  0
• 氢受体数：
  3

反应信息

• 作为反应物：
  描述：

  biphenyl-2,3-dicarboxylic acid anhydride 在 三氯化铝 作用下， 以 苯 为溶剂， 生成 9-芴酮-1-羧酸
  参考文献：
  名称：

  Christiaens,L.; Renson,M., Bulletin des Societes Chimiques Belges, 1969, vol. 78, p. 359 - 393

  摘要：

  DOI：
• 作为产物：
  描述：

  4-苯基-1-茚满酮 在 sodium hydroxide 、 potassium permanganate 作用下， 生成 biphenyl-2,3-dicarboxylic acid anhydride
  参考文献：
  名称：

  Cook et al., Journal of the Chemical Society, 1950, p. 139,146

  摘要：

  DOI：

文献信息

• Formation of Cyclopent[a]indene and Acenaphthylene from Allyl Esters of Biphenyl Mono- and Di-carboxylic Acids and from Biphenyl Dicarboxylic Anhydrides on Flash Vacuum Pyrolysis at 1000 - 1100°C
  作者：Jayant B. Bapat,、Roger F. C. Brown、Glenn H. Bulmer,、Trevor Childs,、Karen J. Coulston、Frank W. Eastwood、Dennis K. Taylar

  DOI：10.1071/c97119

  日期：——

  Flash vacuum pyrolysis at 1000-1100°C of the allyl esters of the three isomeric biphenylcarboxylic acids, of the allyl esters of the 12 biphenyldicarboxylic acids and of the three biphenyldicarboxylic anhydrides gave pyrolysates which were examined by 1H n.m.r. spectroscopy at temperatures below -50°C. In all cases the spectra showed the presence of cyclopent[a]indene and acenaphthylene together with other products. Possible mechanisms for these ring contraction and cyclization processes are discussed and the results of pyrolyses of [2,3-13C2] biphenyl-2,3-dicarboxylic anhydride, and [3,4-13C2]- and (2-2 H1)-biphenyl-3,4-dicarboxylic anhydrides are reported.

  在 1000-1100°C 下闪速真空热解三种异构联苯羧酸的烯丙基酯 在 1000-1100°C 下闪速真空热解三种异构联苯羧酸的烯丙基酯、12 联苯二甲酸的烯丙基酯和三种联苯二甲酸酐的烯丙基酯 得到的热解产物通过 1H n.m.r. 光谱进行了检测。在所有情况下，光谱都显示 存在环戊并[a]茚和 苊烯和其他产物。这些 环收缩和环化过程的可能机制进行了讨论，并对 2,3-13C2]的热解结果。 联苯-2,3-二羧酸酐和 [3,4-13C2]和 (2-2 H1)-联苯-3,4-二羧酸酐的热解结果。 酐。
• Biaryl-type compounds, CD color fixing agent and method for determination of absolute configuration
  申请人：KANAZAWA UNIVERSITY

  公开号：US20030088104A1

  公开（公告）日：2003-05-08

  A novel achiral biaryl-type compound and a circular dichroism(CD) color fixing agent are provided. Furthermore, a method for determining an absolute configuration of a chiral compound is carried out by introducing the above achiral biaryl-type compound into the chiral compound.

  提供了一种新型的非手性双芳基化合物和一种环形二色性(CD)着色固定剂。此外，通过将上述非手性双芳基化合物引入手性化合物中，实施了一种确定手性化合物绝对构型的方法。
• Diarylindane-1,3-diones, their preparation and use
  申请人：Akzo N.V.

  公开号：US04569945A1

  公开（公告）日：1986-02-11

  The invention is dealing with arylindane-1,3-diones of the formula: ##STR1## which can be used in the treatment of inflammatories, psoriasis and asthma.

  该发明涉及式为：##STR1## 的芳基茚-1,3-二酮，可用于治疗炎症、牛皮癣和哮喘。
• Novel aromatic diamine and polyimide thereof
  申请人：Mitsui Chemicals, Inc.

  公开号：US20030092870A1

  公开（公告）日：2003-05-15

  The aromatic diamine compound of the present invention is represented by the following formula (1), and from the aromatic diamine compound a polyimide having a repeating unit represented by the following formula (4), which has low-temperature adherability, can be obtained. 1 In the formulas (1) and (4), n is an integer of 3 to 7, each R is independently an atom or a group selected from the group consisting of a hydrogen atom, a halogen atom and a hydrocarbon group, the same or different two hetero atoms selected from nitrogen atoms and oxygen atoms bonded to each benzene ring are at the ortho- or meta-positions to each other on at least one benzene ring, and when n is 3, the hetero atoms are at the ortho- or meta-positions to each other on all the benzene rings. In the formula (4), Y is a tetravalent organic group.

  本发明的芳香族二胺化合物由以下式(1)表示，从该芳香族二胺化合物可以得到具有低温粘附性的重复单元由以下式(4)表示的聚酰亚胺。 在式(1)和式(4)中，n是3到7的整数，每个R独立地是氢原子、卤素原子和烃基所选的原子或基团，所选的两个异原子从氮原子和氧原子中选择，它们与至少一个苯环上的另一个异原子连接在邻位或间位上，当n为3时，异原子在所有苯环上都在邻位或间位上。在式(4)中，Y是四价有机基团。
• Cyclopent[a]indene (benzopentalene): Generation by flash vacuum pyrolysis and subsequent dimerisation
  作者：Roger F.C. Brown、Neil Choi、Karen J. Coulston、Frank W. Eastwood、Ulfert E. Wiersum、Leonardus W. Jenneskens

  DOI：10.1016/s0040-4039(00)73368-5

  日期：1994.6

  Cyclopent[a]indene (benzopentalene, 7) is generated by flash vacuum pyrolysis of 3-phenylphthalic anhydride (6), biphenylene (3) or diphenic anhydride (4). It dimerises readily and adds cyclopentadiene above −70 °C, but it does not equilibrate at 900 °C with as-indacene (1).

  环戊二烯并[一个]茚（benzopentalene，7）由3 phenylphthalic酸酐（闪速真空热解产生的6），亚联苯基（3）或联苯酸酐（4）。它dimerises容易，并增加了以上-70℃环戊二烯，但它不会在900℃下用平衡为-indacene（1）。