divinyltetramethyldisiloxane | 30110-75-9

• 分子结构分类: 有机化合物 - 有机金属化合物 - 有机类金属化合物
• 英文名称: divinyltetramethyldisiloxane
• 英文别名: tetramethyldivinyldisiloxane；Divinyl tetramethyldisiloxane；bis(ethenyl)-methyl-trimethylsilyloxysilane
• CAS: 30110-75-9
• 化学式: C₈H₁₈OSi₂
• 分子量: 186.401
• InChiKey: FSIJKGMIQTVTNP-UHFFFAOYSA-N

计算性质

• 辛醇/水分配系数(LogP)：
  2.86
• 重原子数：
  11
• 可旋转键数：
  4
• 环数：
  0.0
• sp3杂化的碳原子比例：
  0.5
• 拓扑面积：
  9.2
• 氢给体数：
  0
• 氢受体数：
  1

反应信息

• 作为反应物：
  描述：

  间溴硝基苯 、 divinyltetramethyldisiloxane 在 C₂₅H₃₉P 、 四丁基氟化铵 、 palladium diacetate 作用下， 以 四氢呋喃 为溶剂， 反应 24.0h， 以90%的产率得到3-硝基苯乙烯
  参考文献：
  名称：

  轻度条件下Pd催化的芳基卤化物与廉价的有机硅试剂的乙烯基化

  摘要：

  在温和条件下开发了钯催化未活化的芳基氯和溴化物的Hiyama乙烯基化反应。有效的乙烯基供体和富含电子的位阻膦配体的使用对于反应成功至关重要。这种转化的产物可用于Am / Cm分离，这是核燃料后处理中的一项重要挑战。还获得了取代基对Am / Cm分离选择性的影响，这可能有助于开发用于分离Am和Cm的新型色谱材料。

  DOI：

  10.1002/chem.201802573
• 作为产物：
  描述：

  三甲基氯硅烷 、 2,4,6-三乙烯基-2,4,6-三甲基环三硅氧烷 、 乙烯基-锂 生成 divinyltetramethyldisiloxane
  参考文献：
  名称：

  A Facile Preparation and Polymerization of 1,1-Difunctionalized Disiloxanes

  摘要：

  通过使用几种烷基鎓对环状硅氧烷进行烷基化裂解，然后用氯硅烷淬火，合成了新型 1,1 二甲基二硅氧烷。制备的双官能化硅氧烷通过铂催化的氢硅烷化作用进行加成反应。

  DOI：

  10.1246/cl.1996.517
• 作为试剂：
  描述：

  1,1,5,5-四甲基-3,3-二苯基三硅氧烷 、 Vinylcyclohexene 1,2-monoepoxide 在 divinyltetramethyldisiloxane 作用下， 反应 0.5h， 以99%的产率得到1,5-bis(β-(3,4-epoxycyclohexyl)ethyl)-1,1,5,5-tetramethyl-3,3-diphenyltrisiloxane
  参考文献：
  名称：

  １，５−ビス（β−（３，４−エポキシシクロヘキシル）エチル）−１，１，５，５−テトラメチル−３，３−ジフェニル−トリシロキサン

  摘要：

  【问题】提供一种具有高反应性脂环式环氧基的高折射率新硅材料。【解决方案】提供一种具有脂环式环氧基的高折射率硅材料，即1,5-双(β-(3,4-环氧环己基)乙基)-1,1,5,5-四甲基-3,3-二苯基三环氧烷。【选项图】无。

  公开号：

  JP2020183365A

文献信息

• Polymeric dye for optical power limiting
  申请人：Sarkar Abhijit

  公开号：US08791222B2

  公开（公告）日：2014-07-29

  This invention concerns a polymer coating composition for use as non-focal optical power limiting dye containing polymeric materials. This composition contains: (1) one or more Modified Polymers comprising a Polymer, such as a hyperbranched polymer family, especially HB-PCS, HB-PU, HB-PUSOX or PC with one or more of: a) reverse saturable dye (RSA), b) multi-photon absorption dye (MPA), c) an azo dye, or d) absorption dye, which dye is chemically bonded to the pendant groups of the Polymer (along its chain and/or termini) or which forms a part of the backbone of the Polymer; (2) carbon nanotubes (CNT) as optical power limiters (OPL); and (3) a self-focusing component.

  本发明涉及一种用作非聚焦光学功率限制染料含聚合物材料的聚合物涂层组合物。该组合物包含：（1）一种或多种改性聚合物，包括聚合物，例如超支化聚合物系列，特别是HB-PCS，HB-PU，HB-PUSOX或PC，其中包括以下一种或多种：a）反饱和染料（RSA），b）多光子吸收染料（MPA），c）偶氮染料或d）吸收染料，该染料与聚合物的吊挂基团（沿其链和/或末端）化学键合，或者构成聚合物的骨架的一部分；（2）碳纳米管（CNT）作为光学功率限制器（OPL）；和（3）自聚焦组分。
• Proton conducting membrane, process for its production, and fuel cells made by using the same
  申请人：——

  公开号：US20040062970A1

  公开（公告）日：2004-04-01

  The present invention provides relates to a crosslinkable, proton-conducting membrane having a crosslinked structure, excellent in heat resistance, durability, dimensional stability and fuel barrier characteristics, and showing excellent proton conductivity at high temperature, characterized by comprising (a) an organic/inorganic hybrid structure (A) covalently bonded to 2 or more silicon-oxygen crosslinks and, at the same time, having a carbon atom, and (b) an acid containing structure (B) having an acid group, covalently bonded to a silicon-oxygen crosslink and having an acidic group; and provides a fuel cell using the same membrane. The present invention also provides a method for producing the proton-conducting membrane, comprising steps of preparing a mixture containing an organic/inorganic hybrid, crosslinkable compound (C) and compound (D), the former having 2 or more crosslinkable silyl groups and carbon atoms each being bonded to the silyl group via the covalent bond and the latter having a crosslinkable silyl group and acid group, as the first step; forming the above mixture into a film as the second step; and hydrolyzing/condensing or only condensing the hydrolyzable silyl group contained in the mixture formed into the film to form a crosslinked structure as the third step.

  本发明提供了一种交联的质子导电膜，具有交联结构，优异的耐热性、耐久性、尺寸稳定性和燃料屏障特性，在高温下表现出优异的质子导电性能，其特征在于包括（a）与2个或更多硅氧交联共价键结合，同时具有碳原子的有机/无机杂化结构（A），以及（b）具有酸基，与硅氧交联共价键结合并具有酸性基团的酸含有结构（B）；并提供使用该膜的燃料电池。本发明还提供了一种制备质子导电膜的方法，包括以下步骤：第一步，制备含有有机/无机杂化交联化合物（C）和化合物（D）的混合物，前者具有2个或更多可交联的硅基团，碳原子通过共价键与硅基团结合，后者具有可交联的硅基团和酸基团；第二步，将上述混合物形成成膜；第三步，水解/缩合或仅缩合形成成膜的可水解硅基团，形成交联结构。
• Proton conducting membrane, method for producing the same, and fuel cell using the same
  申请人：Nomura Shigeki

  公开号：US20070213495A1

  公开（公告）日：2007-09-13

  The present invention provides relates to a crosslinkable, proton-conducting membrane having a crosslinked structure, excellent in heat resistance, durability, dimensional stability and fuel barrier characteristics, and showing excellent proton conductivity at high temperature, characterized by comprising (a) an organic/inorganic hybrid structure (A) covalently bonded to 2 or more silicon-oxygen crosslinks and, at the same time, having a carbon atom, and (b) an acid containing structure (B) having an acid group, covalently bonded to a silicon-oxygen crosslink and having an acidic group; and provides a fuel cell using the same membrane. The present invention also provides a method for producing the proton-conducting membrane, comprising steps of preparing a mixture containing an organic/inorganic hybrid, crosslinkable compound (C) and compound (D), the former having 2 or more crosslinkable silyl groups and carbon atoms each being bonded to the silyl group via the covalent bond and the latter having a crosslinkable silyl group and acid group, as the first step; forming the above mixture into a film as the second step; and hydrolyzing/condensing or only condensing the hydrolyzable silyl group contained in the mixture formed into the film to form a crosslinked structure as the third step.

  本发明提供了一种交联的、质子导电膜，具有交联结构，优异的耐热性、耐久性、尺寸稳定性和燃料屏障特性，并在高温下表现出优异的质子导电性能。该膜的特征在于包含(a)有机/无机混合结构(A)，其与2个或更多硅氧交联键共价结合，并且同时具有碳原子；以及(b)含有酸基的酸性结构(B)，其与硅氧交联键共价结合，并具有酸性基团。本发明还提供了使用该膜的燃料电池。本发明还提供了一种制备质子导电膜的方法，包括以下步骤：第一步，制备一个混合物，其中包含一个有机/无机混合、可交联化合物(C)和化合物(D)，前者具有2个或更多可交联的硅基团，碳原子通过共价键与硅基团结合，后者具有可交联的硅基团和酸基团；第二步，将上述混合物形成成薄膜；第三步，水解/缩合或仅缩合形成薄膜中含有的可水解硅基团，形成交联结构。
• Proton conductive film, process for producing the same, and fuel cell employing the proton-conductive film
  申请人：Miyama Toshihito

  公开号：US20060219981A1

  公开（公告）日：2006-10-05

  It is intended to provide a proton conducting membrane which is excellent in heat resistance, dimensional stability, fuel barrier properties, flexibility, etc. and exhibits an excellent protonic conductivity even at high temperatures, a method of producing same and a fuel cell which can operate stably at high temperatures, the proton conducting membrane of the present invention comprises a support filled with a proton conducting structure (β) comprising an acid-containing structure containing an acid group, which support being made of an organic-inorganic composite structure (α) having a crosslinked structure formed by a metal-oxygen bond and an open-cell structure having internally-formed pores connected continuously to each other by the crosslinked structure, and the use of this proton conducting membrane makes it possible to obtain a fuel cell having an excellent performance.

  本发明旨在提供一种质子导体膜，该膜在耐热性、尺寸稳定性、燃料屏障性、柔韧性等方面表现出色，并且即使在高温下也表现出优异的质子导电性能，以及制备该膜的方法和可以在高温下稳定运行的燃料电池。本发明的质子导体膜包括一个支撑体，该支撑体填充有一个质子导体结构（β），该结构包含一个含酸基的酸性结构，该支撑体由具有金属氧键交联结构和内部形成连续连接的开孔结构的有机-无机复合结构（α）制成。使用这种质子导体膜可以获得性能优异的燃料电池。
• Selective hydrosilylation method using hydrido (hydrocarbonoxy) silane
  申请人：Dow Corning Asia, Ltd.

  公开号：US06048994A1

  公开（公告）日：2000-04-11

  A method for hydrosilylating a vinyl-substituted aromatic compound comprising reacting a hydrido (hydrocarbonoxy)silane compound with the vinyl-substituted aromatic compound in the presence of a platinum or platinum compound catalyst and a carboxylic acid. The presence of the carboxylic acid increases the positional selectivity of addition in the hydrosilylation reaction and reduces the polymerization of vinyl groups even in the case of a high-temperature or long-term hydrosilylation reaction.

  一种水硅烷化vinyl取代芳香化合物的方法，包括在铂或铂化合物催化剂和羧酸存在下，将氢基（碳氧基）硅烷化合物与vinyl取代芳香化合物反应。羧酸的存在增加了水硅烷化反应中加成的位置选择性，并且即使在高温或长时间的水硅烷化反应中，也减少了vinyl基团的聚合。