1,3-bis<(trimethylsilyl)amino>propane | 63737-72-4

• 分子结构分类: 有机化合物 - 有机金属化合物 - 有机类金属化合物
• 英文名称: 1,3-bis<(trimethylsilyl)amino>propane
• 英文别名: N,N'-bis(trimethylsilyl)-1,3-propanediamine；1,3-C3H6(NHSiMe3)2；CH2(CH2NHSiMe3)2；N,N'-Bis-trimethylsilyl-trimethylendiamin；1,3-Propanediamine, N,N'-bis(trimethylsilyl)-；N,N'-bis(trimethylsilyl)propane-1,3-diamine
• CAS: 63737-72-4
• 化学式: C₉H₂₆N₂Si₂
• 分子量: 218.49
• InChiKey: DSUNTQBDAUKNQM-UHFFFAOYSA-N

计算性质

• 辛醇/水分配系数(LogP)：
  2.23
• 重原子数：
  13
• 可旋转键数：
  6
• 环数：
  0.0
• sp3杂化的碳原子比例：
  1.0
• 拓扑面积：
  24.1
• 氢给体数：
  2
• 氢受体数：
  2

反应信息

• 作为反应物：
  描述：

  1,3-bis<(trimethylsilyl)amino>propane 在 正丁基锂 作用下， 以 正己烷 为溶剂， 反应 1.0h， 以91%的产率得到
  参考文献：
  名称：

  Synthesis of mixed-metal Li/M, M/M′ and mixed valence MI/MIII chelate amido complexes of the heavy Group 13 metals (M=In, Tl)

  摘要：

  Reaction of the difunctional lithium amide [H2C{CH2N(Li)SiMe3}(2)](2), (2) or its ether adduct [H2C{CH2N(Li-THF)SiMe3}(2)] (3) with MCl3 (M = In, Ga, Tl) gave the mixed metal amides [{CH2(CH2NSiMe3)(2)}(2)M-Li(THF)(2)] (M = In: 4, Ga: 5, Tl: 6) which are highly fluctional in solution. Metal exchange of the thallium(I) amide with MCl3 yielded the mixed-metal/valent species [{CH2(CH2NSiMe3)(2)}(2)(MTlI)-Tl-III] (M = In: 7, Tl: 8) both of which were characterized by X-ray crystallography and found to have the trivalent metal at the centre of a distorted tetrahedral coordination sphere of the amide donors while the monovalent Tl atom bridges two such donor functions. (C) 1999 Elsevier Science S.A. All rights reserved.

  DOI：

  10.1016/s0022-328x(98)00652-4
• 作为产物：
  描述：

  三甲基氯硅烷 、 1,3-丙二胺 在 三乙胺 作用下， 以 四氢呋喃 为溶剂， 反应 2.0h， 以75%的产率得到1,3-bis<(trimethylsilyl)amino>propane
  参考文献：
  名称：

  单烷基氨基甲基化有机金属盐N-烷基N-三甲基甲硅烷基烷氧基甲基胺

  摘要：

  简单或功能性的N-烷基-N-三甲基甲硅烷基烷氧基甲基胺是非常方便的新试剂，用于从由α-不饱和卤化物，功能性末端炔烃或α-溴代酯制备的有机金属化合物（MAl，Mg，Zn）制得不对称的仲功能胺（或酰胺）。

  DOI：

  10.1016/0022-328x(88)80069-x

文献信息

• Zirconium(IV) Complexes Having a Rigid 1,8-Naphthalene Diamide versus a Flexible 1,3-Propylene Diamide for Olefin Polymerization
  作者：Choong Hoon Lee、Young-Hye La、Joon Won Park

  DOI：10.1021/om990360z

  日期：2000.2.1

  Structure and chemical properties of zirconium(IV) complexes containing a rigid naphthalene diamide ligand ([1,8-C10H6(NSiMe3)2]2-) or flexible propylene diamide ligands ([1,3-C3H6(NR)2]2-, R = SiMe3, Si(i-Pr)3) are described. The reaction of 1,8-C10H6(NHSiMe3)2 with Zr(NMe2)4 in refluxing toluene yields [1,8-C10H6(NSiMe3)2]Zr(NMe2)2 (1), and the product 1 is converted to [1,8-C10H6(NSiMe3)2]ZrCl2

  锆的结构和化学特性（IV）含有刚性萘二酰胺配位体（[1,8-C复合物10 ħ 6（NSiMe 3）2 ] 2 - ）或柔性的丙烯二酰胺配位体（[1,3-C 3 H ^ 6（NR）2 ] 2 -，R =森达3，硅（我-Pr）3）进行说明。1,8-C 10 H 6（NHSiMe 3）2与Zr（NMe 2）4在回流的甲苯中反应生成[1,8-C 10 H6（NSiMe 3）2 ] Zr（NMe 2）2（1），并且产物1通过适当的分离产率被转化为[1,8-C 10 H 6（NSiMe 3）2 ] ZrCl 2（2）。用过量的ClSiMe 3处理。X射线晶体学分析确定2形成通过固态的两个氯化物桥缔合的二聚体，并具有高度褶皱的六元环，且N-Zr-N咬合角较小（91.05°）。1,3-C 3 H 6（NHR）2的反应（R ＝ SiMe 3，Si（i- Pr）3）和Zr（NMe 2）4也提供[1，3-C 3
• Synthesis and structure of samarium benzyl complex supported by bridged bis(guanidinate) ligand and its reactivity toward nitriles and phenyl isocyanate
  作者：Xingmin Zhang、Chuanyong Wang、Mingqiang Xue、Yong Zhang、Yingming Yao、Qi Shen

  DOI：10.1016/j.jorganchem.2012.06.004

  日期：2012.10

  (L = iPr(Me3Si)NC(NiPr)N(CH2)3NC(NiPr)N(SiMe3)iPr) in THF afforded monochloride complex LSmCl(THF)2 (1) or LSmCl(DME) (2) upon crystallization from THF or DME. Treatment of 1 with KCH2C6H5 yielded monobenzyl complex LSm(η1-CH2C6H5)(DME) (3). The reactivity of 3 has been further studied with MeCN, 4-MeOC6H4CN and PhNCO. Complex 3 reacts with MeCN to produce [LSm(μ-(N,N′)-N(H)C(Me)C(H)CN)(THF)]2 (4) via

  SMCL的反应3与一个当量LLI的2（L = 我镨（ME 3 Si）的NC（N我PR）N（CH 2）3 NC（N我PR）N（森达3）我PR）在THF，得到一氯化从THF或DME中结晶后，生成复杂的LSmCl（THF）2（1）或LSmCl（DME）（2）。的治疗1与KCH 2 ç 6 ħ 5得到单苄复杂LSM（η 1 -CH 2 C ^ 6 ħ 5）（DME）（3）。3的反应性已与MeCN，4-MeOC 6 H 4 CN和PhNCO进行了进一步研究。配合物3与MeCN反应，通过MeCN甲基的金属化反应生成[LSm（μ-（N，N '）-N（H）C（Me）C（H）C N）（THF）] 2（4）然后将另一个MeCN插入新的Sm-C键和1,3-H移位。4-MeOC 6 H 4 CN插入3的Sm-苄基中形成二聚体复合物[LSm μ- NH（C 6 H 5（p -OMe））CCC 6 H ^ 5 }
• Homogeneous catalytic formation of carbon-nitrogen bonds. 2. Catalytic activation of the silicon-nitrogen bond
  作者：M. T. Zoeckler、R. M. Laine

  DOI：10.1021/jo00163a023

  日期：1983.7
• Kurochkin, V. V.; Zavalishina, A. I.; Orzhekovskaya, E. I., Journal of general chemistry of the USSR, 1987, vol. 57, p. 265 - 274
  作者：Kurochkin, V. V.、Zavalishina, A. I.、Orzhekovskaya, E. I.、Bekker, A. R.、Agranovich, A. G.、Nifant'ev, E. E.

  DOI：——

  日期：——
• Using Zirconium Half-Sandwich Complexes as Building Blocks in a New Class of Zr-M Heterobimetallics Containing Unsupported Zr-M Bonds (M = Fe, Ru, Co)
  作者：Stefan Friedrich、Lutz H. Gade、Ian J. Scowen、Mary McPartlin

  DOI：10.1021/om00011a060

  日期：1995.11

  A new class of Zr-M heterobimetallic complexes (M = Fe, Ru, Co) containing the CH2(CH(2)NSiMe(3))(2)(Cp)Zr} fragment as a building block has been synthesized by salt metathesis of CH2(CH(2)NSiMe(3))(2)(Cp)ZrCl (5) with K[CpM'(CO)(2)] (M' = Fe, Ru) and Na[Co(CO)(3)(PR(3))] (R = Ph, Tol). The zirconium half-sandwich complex 5 was obtained in four reaction steps from ZrCl4 via the spirocyclic complex [CH2(CH(2)NSiMe(3))(2)]Zr-2 (1), the (diamido)dichlorozirconium complex CH2(CH(2)NSiMe(3))(2)ZrCl2 (2), and its soluble THF-adduct CH2(CH(2)NSiMe(3))(2)ZrCl2(THF)(2) (3). The latter was converted to 5 in good yield by reaction with LiCp. The Zr-Fe heterodinuclear complex CH2(CH(2)NSiMe(3))(2)(Cp)Zr-Fe(CO)(2)Cp (6) has been characterized by X-ray crystal structure analysis which has established the presence of an unsupported Zr-Fe bond. The nu(CO) infrared bands of the CpM'(CO)(2) moieties in the Zr-M' complexes (M' = Fe, Ru) indicate a significant ionic contribution to the Zr-M' bonding.