C-1-naphthylresorcin[4]arene | 916134-80-0

• 分子结构分类: 有机化合物 - 苯类化合物 - 萘
• 英文名称: C-1-naphthylresorcin[4]arene
• 英文别名: 2,8,14,20-Tetranaphthalen-1-ylpentacyclo[19.3.1.13,7.19,13.115,19]octacosa-1(25),3(28),4,6,9(27),10,12,15,17,19(26),21,23-dodecaene-4,6,10,12,16,18,22,24-octol
• CAS: 916134-80-0
• 化学式: C₆₈H₄₈O₈
• 分子量: 993.124
• InChiKey: CDBKFJRTJGTVJU-UHFFFAOYSA-N

计算性质

• 辛醇/水分配系数(LogP)：
  15.7
• 重原子数：
  76
• 可旋转键数：
  4
• 环数：
  13.0
• sp3杂化的碳原子比例：
  0.06
• 拓扑面积：
  162
• 氢给体数：
  8
• 氢受体数：
  8

反应信息

• 作为反应物：
  描述：

  C-1-naphthylresorcin[4]arene 在 氨 作用下， 以 水 为溶剂， 反应 0.5h， 以45.7%的产率得到4,6,10,12,16,18,22,24-octaamino-2,8,14,20-tetra(1-naphthyl)pentacyclo[19.3.1.1(3.7).1(9.13).1(15.19)]octacosa-1⁽²⁵⁾,3,5,7⁽²⁸⁾,9,11,13⁽²⁷⁾,15,17,19⁽²⁶⁾,21,23-dodecane
  参考文献：
  名称：

  Amination of calix[4]resorcinarenes. First synthesis of calix[4]phenylenediamines

  摘要：

  DOI：

  10.1134/s1070363210030333
• 作为产物：
  描述：

  1-萘甲醛 、 间苯二酚 在 盐酸 作用下， 以 乙醇 、 水 为溶剂， 反应 8.0h， 生成 C-1-naphthylresorcin[4]arene
  参考文献：
  名称：

  Syntheses and characterization of aryl-substituted pyrogallol[4]arenes and resorcin[4]arenes

  摘要：

  合成并表征了十三种芳基取代的焦高酚[4]芳烃和间苯二酚[4]芳烃结构。系统地研究和讨论了不同芳基侧链对π-π距离、侧链-R基团的内倾角、侧链-R基团的扭曲角度以及侧链-R基团之间角度的影响。

  DOI：

  10.1039/c5ce01792k

文献信息

• Regioselective Synthesis and Structure of New Oligophosphorylated <i>rctt</i> Resorcinarenes
  作者：Vera I. Maslennikova、Olga S. Serkova、Tatiana V. Guzeeva、Konstantin A. Lyssenko、Irina I. Levina、Valentina V. Glushko、Eduard E. Nifantyev

  DOI：10.1080/10426507.2010.531489

  日期：2011.8.1
• Pre-organized oligomodified resorcinarene ligands. Preparation, structure, and complex formation
  作者：O. S. Serkova、A. V. Burikhina、L. K. Vasyanina、O. S. Kuprina、V. I. Maslennikova、E. E. Nifantiev

  DOI：10.1134/s1070363214040240

  日期：2014.4

  Interaction of various conformations of resorcinarenes with carbamoyl chloride, thiocarbamoyl chloride, and trifluoromethanesulfonic acid anhydride has resulted in a series of derivatives with certain pre-organization of the macrocyclic scaffold and the immobilized electron-donating groups. Complex formation of the selected prepared compounds towards Pd(II) derivatives has been studied.
• PROCESS FOR PRODUCING CARBON MATERIAL
  申请人：Suzuki Junji

  公开号：US20100298522A1

  公开（公告）日：2010-11-25

  A process for producing a carbon material comprising the following steps (A) and (B): Step (A): a step of reacting a compound represented by the formula (1): wherein R represents a hydrogen atom etc., R′ represents a hydrogen atom etc., and n represents 3, 5 or 7, with an aldehyde compound to obtain a polymer, Step (B): a step of heating the polymer obtained in Step (A) at 600 to 3000° C. under an inert gas atmosphere.
• [EN] PROCESS FOR PRODUCING CARBON MATERIAL<br/>[FR] PROCÉDÉ DE FABRICATION D'UNE MATIÈRE CARBONÉE
  申请人：SUMITOMO CHEMICAL CO

  公开号：WO2009101947A2

  公开（公告）日：2009-08-20

  A process for producing a carbon material comprising the following steps (A) and (B): Step (A): a step of reacting a compound represented by the formula (1): wherein R represents a hydrogen atom etc., R' represents a hydrogen atom etc., and n represents 3, 5 or 7, with an aldehyde compound to obtain a polymer, Step (B): a step of heating the polymer obtained in Step (A) at 600 to 3000oC under an inert gas atmosphere.
• Syntheses and characterization of aryl-substituted pyrogallol[4]arenes and resorcin[4]arenes
  作者：Constance R. Pfeiffer、Kyle A. Feaster、Scott J. Dalgarno、Jerry L. Atwood

  DOI：10.1039/c5ce01792k

  日期：——

  Thirteen aryl-substituted pyrogallol[4]arene and resorcin[4]arenes structures are synthesized and characterized. The effect of the varying aryl pendent groups on π–π distance, the inward tilt of the pendent –R groups, the twist angle of the pendent –R groups, and the angle between the pendent –R groups is methodically investigated and discussed.

  合成并表征了十三种芳基取代的焦高酚[4]芳烃和间苯二酚[4]芳烃结构。系统地研究和讨论了不同芳基侧链对π-π距离、侧链-R基团的内倾角、侧链-R基团的扭曲角度以及侧链-R基团之间角度的影响。