丁烯基二氯甲基硅烷 | 15983-86-5

• 物质功能分类: 化学试剂 - 硅烷试剂
• 分子结构分类: 有机化合物 - 有机金属化合物 - 有机类金属化合物
• 中文名称: 丁烯基二氯甲基硅烷
• 中文别名: 3-丁烯基甲基二氯硅烷
• 英文名称: butenylmethyldichlorosilane
• 英文别名: 3-Butenylmethyldichlorosilane；but-3-enyl-dichloro-methylsilane
• CAS: 15983-86-5
• 化学式: C₅H₁₀Cl₂Si
• mdl: MFCD00054914
• 分子量: 169.126
• InChiKey: QYDLCVNCOWIUET-UHFFFAOYSA-N

物化性质

• 沸点：
  144 °C
• 密度：
  1.05
• 闪点：
  >25°C

计算性质

• 辛醇/水分配系数(LogP)：
  2.25
• 重原子数：
  8
• 可旋转键数：
  3
• 环数：
  0.0
• sp3杂化的碳原子比例：
  0.6
• 拓扑面积：
  0
• 氢给体数：
  0
• 氢受体数：
  0

安全信息

• TSCA：
  No
• 危险类别码：
  R10,R36/37/38
• 危险品运输编号：
  UN 2986
• 海关编码：
  2931900090
• 安全说明：
  S16,S26,S36/37/39,S45
• 储存条件：
  存储条件：2-8°C，密封保存，并保持干燥。

反应信息

• 作为反应物：
  描述：

  丁烯基二氯甲基硅烷 、 (butane-1,4-diyl)dimagnesium dibromide 以 乙醚 为溶剂， 反应 24.0h， 以5.7 g的产率得到4-(1-methyl-1-silacyclopentyl)but-1-ene
  参考文献：
  名称：

  Enzymatic synthesis of enantiomerically enriched d- and l-3-silylated alanines by deracemization of dl-5-silylmethylated hydantoins

  摘要：

  The hydantoinase process was shown to be extendable to the production of highly lipophilic, silicon-containing amino acids. Two hydantoinases of different origin and stereoselectivities and one L-N-carbamoylase were used for the highly stereoselective bioconversion of (dimethyl)phenylsilyl- and 1-methyl-1-silacyclopentyl substituted alanine derivatives. The enantiomeric purities and absolute configuration of the products were determined with reference compounds that were synthesized with the aid of the Evans oxazolidinone auxiliary. (C) 2001 Elsevier Science Ltd. All rights reserved.

  DOI：

  10.1016/s0957-4166(01)00028-3
• 作为产物：
  描述：

  4-溴-1-丁烯 、 甲基三氯硅烷 在 magnesium 作用下， 以 乙醚 为溶剂， 反应 15.5h， 生成 丁烯基二氯甲基硅烷
  参考文献：
  名称：

  Enzymatic synthesis of enantiomerically enriched d- and l-3-silylated alanines by deracemization of dl-5-silylmethylated hydantoins

  摘要：

  The hydantoinase process was shown to be extendable to the production of highly lipophilic, silicon-containing amino acids. Two hydantoinases of different origin and stereoselectivities and one L-N-carbamoylase were used for the highly stereoselective bioconversion of (dimethyl)phenylsilyl- and 1-methyl-1-silacyclopentyl substituted alanine derivatives. The enantiomeric purities and absolute configuration of the products were determined with reference compounds that were synthesized with the aid of the Evans oxazolidinone auxiliary. (C) 2001 Elsevier Science Ltd. All rights reserved.

  DOI：

  10.1016/s0957-4166(01)00028-3

文献信息

• Hydrosilylation of methylenecyclopropane and methylenecyclobutane on an immobilized platinum catalyst
  作者：E. Sh. Finkel'shtein、V. E. Fedorov、M. P. Filatova

  DOI：10.1007/bf00958591

  日期：1991.4

  The hydrosilylation of methylenecyclopropane on an immobilized platinum catalyst, in contrast to methylenecyclobutane, leads to the formation of linear 3-butenylsilane.
• Lopatnikova, E., Doklady Chemistry, 1983, vol. 268, p. 6 - 9
  作者：Lopatnikova, E.

  DOI：——

  日期：——
• Enzymatic synthesis of enantiomerically enriched d- and l-3-silylated alanines by deracemization of dl-5-silylmethylated hydantoins
  作者：Richard J. Smith、Markus Pietzsch、Thomas Waniek、Christoph Syldatk、Stefan Bienz

  DOI：10.1016/s0957-4166(01)00028-3

  日期：2001.2

  The hydantoinase process was shown to be extendable to the production of highly lipophilic, silicon-containing amino acids. Two hydantoinases of different origin and stereoselectivities and one L-N-carbamoylase were used for the highly stereoselective bioconversion of (dimethyl)phenylsilyl- and 1-methyl-1-silacyclopentyl substituted alanine derivatives. The enantiomeric purities and absolute configuration of the products were determined with reference compounds that were synthesized with the aid of the Evans oxazolidinone auxiliary. (C) 2001 Elsevier Science Ltd. All rights reserved.